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Stable-state titanium dioxide colloid and preparation method thereof

A titanium dioxide, stable state technology, applied in the field of titanium dioxide, can solve the problems such as the inability to achieve the dispersion effect of the ball mill, the inability to store the titanium dioxide solution for a long time, and the influence of the product use effect, etc., to improve economic efficiency and product quality, eliminate Brownian motion, Avoid the effect of dispersion inhomogeneity

Inactive Publication Date: 2014-01-01
TIANJIN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Since the titanium dioxide solution is agglomerated due to precipitation at the bottom of the container, it needs to be fully stirred again before use, which will cause the following problems: 1. However, after adding such substances to the latex, in order to fully disperse, the stirring process is time-consuming and laborious , and when the stirring time is long, it is easy to generate bubbles in the latex liquid, and stirring for too long will cause the latex to heat up and cause the latex to polymerize; 2. Due to the agglomeration of titanium dioxide particles, it is difficult to form a single particle even if it is stirred The particles are dispersed and cannot achieve the dispersion effect of ball mill grinding. Although the agglomerated particles are small, they will seriously affect the product use effect
For example, when used in the production of condoms, the agglomerated particles are in the gelled film, which is unsightly, and the agglomerated particles will directly cause rupture, water leakage and air leakage, seriously affecting product quality
If these titanium dioxides are used as toners for pigments, the color of the pigments will be seriously affected due to poor dispersion; 3. Due to serious sedimentation, the titanium dioxide solution will not be able to be stored for a long time, to a large extent, Whether it is a pigment or a paint, it will often remain at the bottom of the container due to the precipitation of titanium dioxide during use.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0022] The preparation method of the titanium dioxide colloid of above-mentioned stable state, the steps are as follows:

[0023] ⑴.Pour the titanium dioxide, water and thickener directly into the ball mill according to the proportion for grinding, and the grinding time is 24-30 hours;

[0024] ⑵. Take out the colloid after grinding and it will be the finished product.

Embodiment 1

[0026] A stable titanium dioxide colloid, its composition and weight are as follows:

[0027] Titanium dioxide: 5kg;

[0028] Water: 4.5kg;

[0029] Polyacrylate copolymer emulsion: 0.55kg.

[0030] The preparation method of the titanium dioxide colloid of above-mentioned stable state, the steps are as follows:

[0031] (1) Pour 5kg of titanium dioxide, 4.5kg of water and 0.55kg of polyacrylate copolymer emulsion directly into a ball mill for grinding for 24 hours;

[0032] ⑵. Take out the colloid after grinding and it will be the finished product.

Embodiment 2

[0034] A stable titanium dioxide colloid, its composition and weight are as follows:

[0035] Titanium dioxide: 6kg;

[0036] Water: 5kg;

[0037] Sodium polyacrylate with a mass percentage of 20%: 0.6kg.

[0038] The preparation method of the titanium dioxide colloid of above-mentioned stable state, the steps are as follows:

[0039] ⑴. Put 6kg of titanium dioxide, 5kg of water and 0.6kg of sodium polyacrylate with a mass percentage of 20% directly into a ball mill for grinding, and the grinding time is 27 hours;

[0040] ⑵. Take out the colloid after grinding and it will be the finished product.

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PUM

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Abstract

The invention relates to a stable-state titanium dioxide colloid. The stable-state titanium dioxide colloid comprises the following components in parts by weight: 5-10 parts of titanium dioxide, 4.5-5.5 parts of water and 0.55-0.7 part of thickener. The preparation method of the stable-state titanium dioxide colloid comprises the following steps of: (1) directly pouring titanium dioxide, water and the thickener into a ball mill for grinding proportionally; (2) taking out the ground colloid to obtain a finished product. The stable-state titanium dioxide colloid and the preparation method provided by the invention have the advantages that precipitation and aggregation of titanium dioxide can be avoided and good quality of the product can be ensured; the titanium dioxide colloid is free of precipitation and aggregation, convenient to use and suitable for storage for a long time; the product quality problems of the present pigments and coatings using the titanium dioxide due to precipitation and aggregation are changed; the stable-state titanium dioxide colloid can be blended instantly according to the amount needed by the pigment and the coating; the stable-state titanium dioxide colloid is good in dispersity without particles; as long as the stable-state titanium dioxide colloid is used, the blending efficiency and the blending effect can be improved; moreover, the purposes of no waste, energy saving and emission reduction, and high economic benefit are achieved.

Description

technical field [0001] The invention relates to titanium dioxide in the field of chemical products, in particular to a stable titanium dioxide colloid and a preparation method thereof. Background technique [0002] Titanium dioxide (chemical formula TiO 2 , commonly known as titanium dioxide) is an important white pigment and porcelain glaze, which is widely used in latex industry and paint industry. Titanium dioxide has many functions, not only as a white pigment, but also as an essential pigment toner, as a hiding agent for latex products, and as a photocatalyst in modern coatings (available Widely used in the decomposition of formaldehyde, benzene-containing organic matter, etc.). [0003] At present, during the use of titanium dioxide in the above fields, titanium dioxide is usually mixed with water and various pigments, and then mixed in a ball mill to form a good dispersion of titanium dioxide in the mixed solution. However, the ground product needs to be used as so...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D17/00C09C1/36C09C3/10C09C3/04
Inventor 王昶
Owner TIANJIN UNIV OF SCI & TECH
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