Production process of polyisophthaloyl metaphenylene diamine polymer
A polym-phenylene isophthalamide, production process technology, applied in the production process field of poly-m-phenylene isophthalamide polymer, can solve difficult to grasp and control, inaccurate control, increasing colloid Difficulty of filtering etc.
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Embodiment 1
[0023] A kind of production technique of polym-phenylene isophthalamide polymer, comprises the following steps,
[0024] In the diamine dissolving step, m-phenylenediamine is added to a temperature of 20-60 degrees in an amide polar organic solvent, and m-phenylenediamine is dissolved in an amide polar organic solvent; in a preferred embodiment, m-phenylene The diamine is selected from polymer grade m-phenylenediamine, and the amide polar organic solvent is selected from dimethylacetamide solution, and the dimethylacetamide solution made from 6 to 8 parts of weight of dry dimethylacetamide is mixed with 1 Part weight of polymeric grade m-phenylenediamine is added to the dimethylacetamide solution, and the temperature of the solution is controlled at 20-30 degrees;
[0025] In the normal temperature polymerization step, the temperature of the solution obtained in the diamine dissolving step is controlled at 20-40 degrees, and isophthaloyl dichloride is added under the reaction ...
Embodiment 2
[0032] A kind of specific production technique of polym-phenylene isophthalamide polymer, comprises the following steps,
[0033] In the diamine dissolving step, m-phenylenediamine is selected from polymer grade m-phenylenediamine, amide polar organic solvent is selected from dimethylacetamide solution, and dimethylacetamide made from 7.8 parts by weight of dry dimethylacetamide Acetamide solution, 1 part by weight of polymeric grade m-phenylenediamine is added to the dimethylacetamide solution, and the temperature of the solution is controlled at 20-30 degrees;
[0034] In the normal temperature polymerization step, continuously and slowly the polymerization grade isophthaloyl dichloride of 1.88 parts by weight;
[0035]In the rough control neutralization reaction step, corresponding to 1 part by weight of m-phenylenediamine in the diamine dissolution step, 0.65 parts by weight of alkaline earth metal oxide or hydroxide is added, and in a preferred embodiment, corresponding t...
Embodiment 3
[0039] A kind of specific production technique of polym-phenylene isophthalamide polymer, comprises the following steps,
[0040] In a tank reactor with stirring and jacket, add 1 part by weight of polymer-grade m-phenylenediamine to 7.8 parts by weight of dry dimethylacetamide, control the temperature at 20-30 degrees, and continuously Slowly add 1.88 parts by weight of polymeric isophthaloyl chloride for polymerization, and the hydrogen chloride generated is continuously neutralized with 0.65 parts by weight of calcium hydroxide dimethylacetamide solution, wherein calcium hydroxide and dimethyl The weight ratio of acetamide is 1:2, the temperature is controlled below 70 degrees, and then 0.07 parts by weight of diethylamine-dimethylacetamide solution is used for continuous neutralization reaction. The weight ratio of diethylamine and dimethylacetamide The ratio is 1:2, and the resulting colloidal polymer of polyisophthaloyl dichloride m-phenylenediamine has a polymer concent...
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