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Preparation method of water-repellent and oil-repellent antistatic finishing agent

An antistatic finishing agent, water and oil repellent technology, applied in fiber treatment, textiles and papermaking, etc., can solve the problems of increasing processing procedures, reducing antistatic finishing effect, reducing antistatic and water and oil repellency

Active Publication Date: 2014-02-19
上海天伟质量检测技术服务有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This brings some problems to endow the fabric with water-repellent, oil-repellent and antistatic functions at the same time. At present, there are mainly step-by-step finishing method and same-bath method to deal with, but the step-by-step finishing method increases the processing procedures, and two kinds of finishing should be considered at the same time. The viscosity and influence between the agents will greatly reduce the antistatic and water and oil repellency; there are compatibility problems between different functional agents, so in the same bath method, due to the compatibility and mutual influence of functional agents, it is also It will greatly reduce the effect of antistatic finishing and water and oil repellent finishing, so it is very necessary to invent a water and oil repellent antistatic finishing agent
For example, CN102108638B invented a durable waterproof, oil-proof, antistatic and antibacterial functional coating glue, which has the effect of water-repellent, oil-repellent and anti-static, but because of its anti-static part and its water-repellent and oil-repellent part At the same time, it acts as a side group, and they have a great influence on each other, so the water-repellent, oil-repellent and antistatic effect is not ideal. It is necessary to seek a better water-repellent, oil-repellent and antistatic finishing agent.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] By weight:

[0016] 1) Emulsification: 18 parts of methyl methacrylate, 40 parts of n-butyl acrylate, 33 parts of perfluorobutyl ethyl methacrylate, 4.5 parts of sodium dodecylbenzenesulfonate, 5.2 parts of fatty alcohol polyoxygen Add vinyl ether AEO-9 and 200 parts of deionized water into the container, stir and emulsify for 1.5 hours, and control the temperature at 70°C to obtain an emulsion;

[0017] 2) Initiate polymerization: add dropwise a blend of 0.3 parts of n-butyllithium and 30 parts of water to the emulsion, control the dropping time for 1.5 hours, and continue stirring for 1 hour to obtain a copolymer emulsion;

[0018] 3) Re-reaction: lower the temperature of the copolymer emulsion to 45°C, add a blend of 8.2 parts of 3-prop-2-acryloyloxypropane-1-sodium sulfonate and 50 parts of water, and then dropwise add 0.1 1 part of n-butyllithium and 20 parts of water, the dropwise addition time is controlled for 1.5 hours, and the stirring reaction is continued f...

Embodiment 2

[0023] By weight:

[0024] 1) Emulsification: 23 parts of methyl methacrylate, 35 parts of n-butyl acrylate, 25 parts of perfluorobutyl ethyl methacrylate, 3.4 parts of sodium dodecylbenzenesulfonate, 4.0 parts of fatty alcohol polyoxygen Add vinyl ether AEO-9 and 150 parts of deionized water into the container, stir and emulsify for 1 hour, and control the temperature at 60°C to obtain an emulsion;

[0025] 2) Initiate polymerization: add dropwise a blend of 0.4 parts of n-butyllithium and 30 parts of water to the emulsion, control the dropping time for 2 hours, and continue stirring for 1.5 hours to obtain a copolymer emulsion;

[0026] 3) Re-reaction: lower the temperature of the copolymer emulsion to 50°C, add a blend of 6.3 parts of 3-prop-2-acryloyloxypropane-1-sodium sulfonate and 50 parts of water, and then dropwise add 0.2 1 part of n-butyllithium and 20 parts of water, the dropwise addition time is controlled for 1 hour, and the stirring reaction is continued for 3 ...

Embodiment 3

[0031] By weight:

[0032] 1) Emulsification: 20 parts of methyl methacrylate, 42 parts of n-butyl acrylate, 28 parts of perfluorobutyl ethyl methacrylate, 4.0 parts of sodium dodecylbenzenesulfonate, 4.7 parts of fatty alcohol polyoxygen Vinyl ether AEO-9 and 180 parts of deionized water were added to the container, stirred and emulsified for 1.5 hours, and the temperature was controlled at 70°C to obtain an emulsion;

[0033] 2) Initiate polymerization: add dropwise a blend of 0.35 parts of n-butyllithium and 30 parts of water to the emulsion, control the dropping time for 2 hours, and continue to stir and react for 1.5 hours to obtain a copolymer emulsion;

[0034] 3) Re-reaction: lower the temperature of the copolymer emulsion to 50°C, add a blend of 7.5 parts of 3-prop-2-acryloyloxypropane-1-sodium sulfonate and 50 parts of water, and then dropwise add 0.1 1 part of n-butyllithium and 20 parts of water, the dropwise addition time is controlled for 1.5 hours, and the stir...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention relates to a preparation method of a water-repellent and oil-repellent antistatic finishing agent. The water-repellent and oil-repellent antistatic finishing agent is prepared from methyl methacrylate, n-butyl acrylate, perfluoro-n-butyl ethyl methacrylate, 3-propyl-2-enoyl acyloxy propane-1- sodium sulfonate, sodium dodecyl benzene sulfonate, fatty alcohol-poly-oxyethylene ether AEO-9, and n-butyllithium. A polymer with a fluorocarbon group on the side group and an antistatic group on the end group or close to the end group can be obtained by controlling the reaction sequence, time and equivalent ratios of reaction monomers to directionally influence the structure of the polymer to a certain extent. The finishing agent containing the polymer as main component has excellent water-repellent, oil-repellent and antistatic properties.

Description

technical field [0001] The invention relates to a preparation method of a finishing agent, in particular to a preparation method of a finishing agent with water-repelling, oil-repelling and antistatic properties. Background technique [0002] With the development of society, people's demand for fibers and textiles is increasing, and their performance requirements are getting higher and higher, which requires multifunctional composite finishing. At present, the effects of various functional finishing agents are relatively single, and there are compatibility problems among single-functional finishing agents. [0003] Water- and oil-repellent finishing and anti-static finishing are inherently contradictory. Anti-static finishing agents eliminate static electricity by absorbing moisture in the air and improving the electrical conductivity of fabrics, while water- and oil-repellent finishing agents reduce fiber surface tension. Make it lower than the surface tension of water and...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M15/356C08F220/16C08F220/14C08F220/24C08F220/38C08F2/26C08F2/30
Inventor 王济强李文刚朱桂秀张振娟
Owner 上海天伟质量检测技术服务有限公司
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