Methanol gasoline stabilizer

A technology of methanol gasoline and stabilizer is applied in the field of additives for methanol gasoline and additives for improving the stability of methanol gasoline, which can solve the problems of unfavorable environmental protection and health, increase the emission of toxic substances in tail gas, etc., and improve the resistance to phase separation when encountering water. , the effect of excellent pollutant discharge and improved water capacity

Active Publication Date: 2014-03-26
CRPC INNOVATION ENERGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Wherein partial saponification ammonium soap has no commercially available product, is the incomplete saponification product fatty acid ammonium that is produced by partial saponification reaction of animal and vegetable oil, waste oil or organic acid and organic amine or inorganic ammonium; 200810069817.9 discloses a kind of water-containing methanol gasoline and its The preparation method, the water content of industrial methanol used is 2-5%, the addition amount is 14.5%-48%, and the methanol must be modified before adding; 201010260367.9 discloses a polyetheramine and its production method and its application in methanol gasoline, Using polyetheramine prepared by addition of hexylamine and ethylene oxide as a methanol gasoline additive, combined with butanol or octanol, the resulting methanol gasoline has a water resistance of 1% to 2%; 201010242644.3 discloses a A certain amount of xylene is added to the methanol gasoline additive. The addition of xylene will significantly increase the emission of toxic substances in the tail gas, which is not conducive to environmental protection and human health. The test conditions for anti-phase separation performance are -20°C, 4h, and 0.15% water, 4h. These conditions are relatively mild and are different from the actual storage conditions of methanol gasoline.

Method used

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  • Methanol gasoline stabilizer
  • Methanol gasoline stabilizer
  • Methanol gasoline stabilizer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] According to mass percentage 2-octylamine 18.0%, N-tert-butylpiperazine 19.0%, 4-N-butoxybenzonitrile 19.0%, allyl phenoxyacetate 16.0%, 1,3-acetone dicarboxylic acid Add 14.5% diethyl ester and 13.5% 3-dimethylaminoanisole into a stirring tank, and stir evenly at room temperature to obtain a transparent and clear methanol-gasoline stabilizer product.

[0019] Add 0.4% stabilizer to methanol, mix evenly, and use BMT-180 ultrasonic instrument of BRANSON in the United States for 20 minutes at room temperature, then add other additives and gasoline to obtain methanol gasoline.

[0020] Five commercially available national standard gasolines were selected as base oils, and 5 methanol gasoline samples were prepared as blank groups. According to the method of this embodiment, 5 experimental samples of methanol gasoline containing stabilizer were prepared, and the water resistance test was carried out.

[0021] The test method refers to the local standards of Shanxi Province ...

Embodiment 2

[0025] According to mass percentage 2-octylamine 18.0%, N-tert-butylpiperazine 15.0%, 4-N-butoxybenzonitrile 20.0%, allyl phenoxyacetate 17.5%, 1,3-acetone dicarboxylic acid Add 15.0% diethyl ester and 14.5% 3-dimethylaminoanisole into a stirring tank, and stir evenly at room temperature to obtain a transparent and clear methanol-gasoline stabilizer product.

[0026] Test method is the same as embodiment 1. The experimental results are shown in Table 2.

[0027] Table 2 Maximum water capacity test results.

[0028]

Embodiment 3

[0030] According to mass percentage 2-octylamine 25.0%, N-tert-butylpiperazine 16.0%, 4-N-butoxybenzonitrile 15.0%, allyl phenoxyacetate 16.0%, 1,3-acetone dicarboxylic acid Add 12.0% diethyl ester and 16.0% 3-dimethylaminoanisole into a stirring tank, and stir evenly at room temperature to obtain a transparent and clear methanol-gasoline stabilizer product.

[0031] Test method is the same as embodiment 1. The experimental results are shown in Table 3.

[0032] Table 3 Maximum water capacity test results.

[0033]

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Abstract

The invention discloses a methanol gasoline stabilizer. The methanol gasoline stabilizer is formed by mixing the following components in percentage by mass: 18.0 to 31.0 percent of 2-octylame, 15.0 to 29.5 percent of N-tert-butyl-piperazine, 15.0 to 24.5 percent of 4-N-butoxy-benzonitrile, 13.0 to 24.0 percent of allyl phenoxyacetate, 10.0 to 20.5 percent of 1,3-acetone dicarboxylate, and 9.0 to 19.5 percent of 3-dimethyl aminoanisole. Before methanol gasoline is prepared, first, 0.4 to 0.8 mass percent of the stabilizer disclosed by the invention is added to the methanol, and the methanol and the stabilizer are mixed uniformly, and then, performing subsequent processes of preparing the methanol gasoline after ultrasonic treatment is performed at a normal temperature. The improvement effect of the storage stability of the methanol gasoline using the methanol gasoline stabilizer disclosed by the invention is remarkable; the anti-water separation performance is improved obviously; through engine stand and actual road driving tests, the gasoline consumption, the output power, the tail gas emission and the like of the methanol gasoline are equivalent to those of the methanol gasoline with the same grade.

Description

technical field [0001] The invention belongs to the technical field of methanol replacing vehicle fuel, and relates to an additive for methanol gasoline, in particular to an additive for improving the stability of methanol gasoline. Background technique [0002] With the increasing shortage of world oil resources and the increasing air pollution, the energy crisis has become the bottleneck of economic development, and new alternative fuels have attracted the attention of all parties. my country's dependence on foreign oil has exceeded 53%, and energy and environmental issues restrict the rapid development of my country's economy. my country is a country that is poor in oil and gas but relatively rich in coal. It is completely feasible to use coal to produce methanol to replace part of the oil. Using methanol as an alternative fuel for internal combustion engines is an effective way to protect the environment and use energy rationally. According to the National Development a...

Claims

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Application Information

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IPC IPC(8): C10L1/222C10L1/232C10L1/228C10L1/19C10L1/185
Inventor 郭四虎常永龙吴跃曲李永浩边建红石卫红
Owner CRPC INNOVATION ENERGY
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