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Multilayer antioxidant high-temperature-resistant SiC/Ta/C/Ta/SiC coating and preparation method thereof

A technology with high temperature resistance and anti-oxidation, applied in the direction of layered products, etc., can solve the problems of weak bonding strength of the coating, easy peeling off, mismatch of thermal expansion coefficient between the coating and the substrate, etc., to alleviate the difference in thermal expansion coefficient and improve oxidation resistance performance, the effect of improving thermal shock performance

Active Publication Date: 2014-04-16
TAICANG PAIOU TECH CONSULTING SERVICE
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  • Abstract
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AI Technical Summary

Problems solved by technology

However, a serious defect of the anti-oxidation coating provided in the literature is that the thermal expansion coefficient of the coating and the substrate does not match, and the bonding strength of the coating is weak. protection, resulting in a serious decline in the performance of C / SiC composites

Method used

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Effect test

Embodiment

[0015] A SiC / Ta / C / Ta / SiC multilayer anti-oxidation and high-temperature resistant coating, which is composed of SiC layer, Ta layer and C layer, is characterized in that the order of lamination is SiC layer, Ta layer, C layer, Ta layer Layer, SiC layer, cycle 2 times, both sides of the C layer are Ta layers, and the innermost and outermost layers are SiC layers. The thickness of the SiC layer is 20 μm, the thickness of the Ta layer is 10 μm, and the thickness of the C layer is 20 μm.

[0016] The preparation method of above-mentioned anti-oxidation coating is characterized in that comprising the steps of following sequence:

[0017] (1) A layer of SiC is deposited on the surface of the substrate by chemical vapor deposition. The deposition conditions of the SiC layer are as follows: trichloromethylsilane is the precursor, argon is the dilution gas, hydrogen is the carrier gas, and the deposition temperature is 1000°C. Deposition time 10h;

[0018] (2) Deposit Ta layer by che...

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Abstract

The invention discloses a multilayer antioxidant high-temperature-resistant SiC / Ta / C / Ta / SiC coating and a preparation method thereof. The multilayer antioxidant high-temperature-resistant SiC / Ta / C / Ta / SiC coating is formed by laminating SiC layers, Ta layers and C layers, and is characterized in that the laminating sequence is the SiC layer, the Ta layer, the C layer, the Ta layer and the SiC layer, or SiC layer, the Ta layer, the C layer, the Ta layer, the SiC layer, SiC layer, the Ta layer, the C layer, the Ta layer, and the SiC layer, or SiC layer, the Ta layer, the C layer, the Ta layer, the SiC layer, SiC layer, the Ta layer, the C layer, the Ta layer, the SiC layer, SiC layer, the Ta layer, the C layer, the Ta layer and the SiC layer; both sides of the C layer are Ta layers; the innermost layer and the outermost layer are SiC layers; and the Ta layer, the C layer, the Ta layer and the SiC layer are sequentially deposited on the prepared SiC layer with a chemical vapor deposition method so as to obtain the multilayer antioxidant high-temperature-resistant SiC / Ta / C / Ta / SiC coating. According to the coating and the preparation method thereof, the outer SiC layer forms a layer of SiO2 film in a high-temperature aerobic environment, so that diffusion of oxygen atoms can be prevented effectively, and meanwhile, a TaC layer can be formed on a contact surface of the Ta layer and the C layer to further improve the antioxidation performance. Alternate deposition of coatings can effectively relieve differences of coefficients of thermal expansion of the coatings and improve the thermal shock performance of the coatings remarkably, the thickness and lay number of a matrix can be controlled by controlling deposition time and deposition times, and the microstructure of the composite coating can be controlled.

Description

technical field [0001] The invention relates to an anti-oxidation and high-temperature resistant coating and a preparation method thereof, in particular to a SiC / Ta / C / Ta / SiC multilayer anti-oxidation and high-temperature resistance coating and a preparation method thereof. technical background [0002] Structural materials such as aero-engines, turbine blades, industrial turbines, aerospace engines, and thermal generators operate at high temperatures and are subject to high-temperature oxidation and corrosion. In order to protect these hot-end parts from oxidation corrosion at high temperature and prolong their life, a lot of research has been done on high-temperature structural materials and high-temperature coatings. In recent years, high-temperature structural materials have made great progress, but it is not enough to improve the high-temperature oxidation resistance of materials only from the material itself. Practice has proved that it is very difficult for high-tempe...

Claims

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Application Information

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IPC IPC(8): B32B33/00
Inventor 陈照峰汪洋
Owner TAICANG PAIOU TECH CONSULTING SERVICE
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