51results about How to "Alleviate thermal expansion coefficient differences" patented technology

The invention discloses a high chrome steel centrifugation roll collar and a manufacturing method thereof, and belongs to the technical field of machining and casting. The high chrome steel centrifugation roll collar comprises an outer layer and a core part, and the proportion of the outer layer to the core part is 1:2; and the outer layer comprises alloy compositions including, by weight, 0.80%-1.40% of C, 0.40%-1.00% of Si, 0.60%-1.20% of Mn, not larger than 0.03% of P, not larger than 0.03% of S, 8.00%-14.0% of Cr, 1.00%-3.00% of Mo, 0.50%-1.50% of Ni+V and the balance Fe and inevitable impurities. The high chrome steel centrifugation roll collar solves the technical problems that a composite casting roll collar is not enough in abrasive resistance, poor in rolled metal surface quality, poor in outer layer and core part interface combination, low in bonding intensity and the like in the using process, and the economic and feasible manufacturing method is provided for producing roll collars of large and small vertical rolls of a hot strip mill.

The invention relates to the technical field of sintering boat coatings, in particular to an anti-sticking coating on the surface of a cemented carbide sintering boat and a preparation method thereof.The anti-sticking coating on the surface of the cemented carbide sintering boat comprises an intermediate transition coating and a working surface layer; the intermediate transition coating is an aluminum oxide coating or a silicon carbide coating; the working surface layer is a zirconium oxide layer; and the zirconium oxide layer is doped with a rare earth oxide. With the anti-sticking coating,the sintering boat can be repeatedly used 40 times or more.

The invention discloses a multilayer antioxidant high-temperature-resistant SiC/Ta/C/Ta/SiC coating and a preparation method thereof. The multilayer antioxidant high-temperature-resistant SiC/Ta/C/Ta/SiC coating is formed by laminating SiC layers, Ta layers and C layers, and is characterized in that the laminating sequence is the SiC layer, the Ta layer, the C layer, the Ta layer and the SiC layer, or SiC layer, the Ta layer, the C layer, the Ta layer, the SiC layer, SiC layer, the Ta layer, the C layer, the Ta layer, and the SiC layer, or SiC layer, the Ta layer, the C layer, the Ta layer, the SiC layer, SiC layer, the Ta layer, the C layer, the Ta layer, the SiC layer, SiC layer, the Ta layer, the C layer, the Ta layer and the SiC layer; both sides of the C layer are Ta layers; the innermost layer and the outermost layer are SiC layers; and the Ta layer, the C layer, the Ta layer and the SiC layer are sequentially deposited on the prepared SiC layer with a chemical vapor deposition method so as to obtain the multilayer antioxidant high-temperature-resistant SiC/Ta/C/Ta/SiC coating. According to the coating and the preparation method thereof, the outer SiC layer forms a layer of SiO2 film in a high-temperature aerobic environment, so that diffusion of oxygen atoms can be prevented effectively, and meanwhile, a TaC layer can be formed on a contact surface of the Ta layer and the C layer to further improve the antioxidation performance. Alternate deposition of coatings can effectively relieve differences of coefficients of thermal expansion of the coatings and improve the thermal shock performance of the coatings remarkably, the thickness and lay number of a matrix can be controlled by controlling deposition time and deposition times, and the microstructure of the composite coating can be controlled.

The invention discloses a rust-proof pigment. The rust-proof pigment comprises the following raw materials in parts by weight: 30-50 parts of scale-shaped zinc powder, 2-10 parts of modified aluminum tripolyphosphate, 15-20 parts of titanium dioxide powder, 30-35 parts of zinc phosphate, 1-2 parts of calcium phosphate, 8-10 parts of calcium carbonate, 2-7 parts of a pigment dispersing agent, 2-5 parts of a silicane coupling agent, 3-7 parts of ammonium molybdate, 1-2 parts of coconut fatty acid diethanol amide, 10-15 parts of a dinonylnaphthalene sulfonic acid, 5-10 parts of ethyl orthosilicate, 0.5-0.9 part of a polyaspartic acid and 0.5-0.7 part of petroleum sodium sulfonate, and further comprises 1.5-3.2 parts of sepiolite powder. The rust-proof pigment disclosed by the invention is low in production cost; environmental pollution is avoided, that is, an environmental protection function is achieved; the rust-proof pigment is high in storage stability and cost performance, and has a certain of rust-proof and comprehensive performance.

A charcoal/charcoal composite material ablation-resisting coating and a preparing process thereof are disclosed. The coating comprises a SiC transition coating and a tungsten spraying coating. The surface layer of a substrate is covered with the SiC transition coating. The SiC transition coating is coated with the tungsten spraying coating. The SiC transition coating comprises 70-80% by mass of Si powder, 10-20% by mass of C powder and 5-15% by mass of Al2O3 powder. The preparing process includes subjecting the substrate to surface treatment, preparing the SiC transition coating, screening a tungsten powder material, preparing a tungsten coating/SiC/charcoal/charcoal composite material, relieving stress of a tungsten coating/SiC/charcoal/charcoal composite material coating, and subjecting the coating to ablation performance testing by adopting an oxyacetylene flame ablating device. According to the charcoal/charcoal composite material ablation-resisting coating and the preparing process, oxyacetylene flame ablation resisting time of a charcoal/charcoal composite material at about 2800 DEG C is prolonged from 10 s to 120 s and the coating does not shed.

The invention discloses a composite metal ceramic coating for high-temperature alloy protection and a preparing method of the composite metal ceramic coating. The coating comprises a face layer and abottom layer with a nano columnar crystal structure. The face layer comprises at least two metal ceramic sub layers, and a metal parent phase and a dispersed distribution nitride ceramic phase are specifically included. In the direction from the surface of the composite metal ceramic coating to an alloy matrix, the doping amount of the nitride ceramic phase is gradually reduced, and the distribution interval of the volume fraction of the nitride ceramic phase is 0.1-60%. According to the preparing method of the coating, magnetic control sputtering is adopted for preparing a bottom layer coating, and then, non-balance reaction magnetic control sputtering is utilized for preparing the face layer of the doped ceramic phase. Through the structure, the heat expansion coefficient of the coatingis gradually increased from top to bottom, jumping changes of the heat expansion coefficient on the coating/oxide film interface are reduced, accordingly, the heat stress in an oxide film in the heatcirculation process is relieved, and the capability of oxide film peeling resisting of the coating in the heat circulation is enhanced.

The invention discloses a composite coating for a titanium alloy gasket and a preparation method thereof. The composite coating is composed of a nickel-based metal transition layer with the thickness of 0.06mm and a ceramic surface layer with the thickness of 0.3-0.4 mm. The nickel-based metal transition layer comprises, by mass, 60-85% of Ni, 10-30% of Cr, 3-6% of B, 3-6% of Si, 2-5% of Fe and 2-5% of Mo. The ceramic surface layer comprises, by mass, 70-90% of Al2O3, 15-30% of TiO2 and 3-10% of ZrO2. The preparation method of the composite coating comprises the steps that firstly, oil stains, impurities and the like on the surface of the titanium alloy gasket are removed in a surface cleaning and compressed air sand blasting roughening mode; and then a uniform and compact insulating, wear-resistant and corrosion-resistant composite coating is prepared through a supersonic flame spraying technology and a high-speed plasma spraying technology, so that the insulating, wear-resistant and corrosion-resistant characteristics of the titanium alloy gasket are improved, contact potential is isolated, galvanic corrosion is avoided, and accordingly the sealing reliability of pipeline system equipment and accessories is improved.

The invention discloses a heater and a preparation method thereof. The heater comprises a pyrolytic boron nitride substrate (1), a conducting layer (2) and an insulating layer (3), wherein the conducting layer (2) and the insulating layer (3) are sequentially arranged on the surface of the substrate (1) in a stacked mode; and the conducting layer (2) comprises pyrolytic graphite doped with boron carbide; the mass of the boron carbide is 0.1%-50% of that of the new conducting layer. According to the embodiments of the invention, the new conducting layer is arranged in the heater; the differencebetween the expansion coefficient of the new conducting layer and the expansion coefficients of the insulating layer and the substrate is small, so that a layering phenomenon is not liable to occur.Moreover, the resistance of the new conducting layer does not fluctuate greatly along with the rise of temperature, so that a heating effect is good. With the heater and the preparation method thereofof the invention adopted, the problem of the resistivity negative temperature characteristic of the pyrolytic graphite conductive coating is solved; the thermal expansion coefficient difference of aconducting coating and a boron nitride substrate in the prior art is reduced; the temperature control procedure of the heater can be simplified; and the layering problem of the conducting coating canbe solved.

The invention discloses a binding-phase TiC/WC composite hard alloy and a preparation method thereof. The binding-phase TiC/WC composite hard alloy is prepared from the following raw materials in percentage by mass: 84-94% of hard-phase TiC and WC mixed powder, 5-15% of ternary intermetallic compound Co2AlTi powder and 0.5-1% of stearic acid additive, wherein the hard-phase TiC and WC mixed powder serves as a hard phase and has uniform granularity, and the ternary intermetallic compound Co2AlTi powder serves as a binding phase. The method comprises the steps of firstly, mixing and grinding the raw materials in a ball mill; carrying out vacuum drying, then, screening to remove aggregates, then, granulating, and then, pressing at the pressure of 800-1,200kg/cm<2>; putting a prepared pressed shape in a vacuum sintering furnace with the degree of vacuum of 3*10<-4> to 5*10<-4>MPa, heating to the temperature of 1,200-1,350 DEG C, carrying out vacuum sintering for 1-2 hours, then, carrying out hot isostatic pressing treatment for 1-5 hours at the temperature of 1,200-1,350 DEG C and the pressure of 80-100MPa, cooling, and then, taking out, thereby obtaining the hard alloy.

The invention discloses a low-stress multilayer film optical filter and a preparation method thereof, a substrate is 3.3 borosilicate glass, and the multilayer film optical filter is a double-half-wave narrow-band interference optical filter. 3.3 borosilicate glass has a linear expansion coefficient of 3.3 * 10 <-6 >/degree; in order to reduce the junction stress of the optical filter, two technologies of substrate heating and ion assistance are adopted. When the temperature of the substrate is 250 DEG C, the aggregation density of the TiO2 film is close to 1, the aggregation density of the SiO2 film is close to 0.92, and the accumulated tensile stress of the optical filter is 10.8 MPa; if the ion energy is selected to be 350 eV, the ratio JI/JM of the number of the auxiliary ions reachingthe substrate to the number of the deposited integrators is 0.15 and 0.05 respectively, so that the aggregation densities of TiO2 and SiO2 are close to 1 and 0.96 respectively, and the junction cumulative pressure stress of the optical filter is-7MPa. The low-stress film optical filter can be widely applied to various photoelectric instruments.

The invention relates to a workpiece wear-resistant coating and a spraying method for the same and belongs to the field of superficial technologies. According to the invention, on one side, the problems that wear-resistant coatings of single-layer structures in the prior art are poor in wear resistance, short in service life, long in replacement duration after halt and low in yield and productionefficiency of slabs can be solved; and on the other side, the problems that offline crystallizers cannot be partially repaired with the prior art, narrow-edged copper plates of the damaged crystallizers can only be used for other purposes and thus production materials are wasted can be solved. The workpiece wear-resistant coating comprises a bottom layer and a face layer, wherein the bottom layerserves as a transition layer and only covers a worn and damaged part of a clad layer; and the face layer covers an entire coating of a workpiece. The spraying method provided by the invention comprises the steps that areas outside a to-be-sprayed area are protected; the bottom layer is sprayed at first; and then protection is removed and the face layer is sprayed. According to the invention, bonding strength between the face layer and a copper base body can be improved; thermal shock resistance of the coating can be enhanced; and the service life of the surface coating of the copper plate of the crystallizer can be prolonged.

The invention relates to the technical field of thin-film materials, and provides a DLC/CNx/MeN/CNx nano-multilayer film for solving the problems that the bonding strength of a traditional DLC thin film and a matrix material is poor, and the wear-resisting performance can also be reduced due to the fact that stress is reduced, and the bonding strength is improved. The DLC/CNx/MeN/CNx nano-multilayer film includes a matrix (1), and further includes a metal transition layer (2) and a nano-multilayer film which are successively deposited on the surface of the matrix, the nano-multilayer film is composed of a plurality of nano-composite units (3), and each nano-composite unit is provided with a DLC layer (4), a first gradient CNx layer (5), a metal nitride layer (6) and a second gradient CNx layer (7) which are successively arranged from bottom to top. The nano-multilayer film can effectively solve the problem of low film-matrix bonding strength of a traditional deposition method, meanwhile internal stress is reduced, and excellent wear resistance is achieved; and the steps of a preparation method are simple, process conditions are easy to control, the preparation process is safe and pollution-free, the cost is low, and industrialization is easy to realize.

The invention discloses a ceramic-based composite material system on the surface of an unmanned aerial vehicle and a preparation method of the ceramic-based composite material system. The ceramic-based composite material system comprises a ceramic-based composite material matrix which covers the surface of a fuselage of the unmanned aerial vehicle; a bonding layer, an oxygen barrier layer, an oxygen barrier propagation layer, a thermal expansion coefficient buffer layer and a heat insulation cooling layer are sequentially deposited on the ceramic-based composite material matrix; wherein the thickness of the bonding layer is 100-200 [mu] m, the thickness of the oxygen propagation prevention layer is 30-50 [mu] m, the thickness of the thermal expansion coefficient buffer layer is 30-50 [mu] m, and the thickness of the heat insulation cooling layer is 100-1000 [mu] m. The ceramic-based composite material system prepared by the invention has a coating with remarkable high-temperature resistance, high heat insulation, oxidation resistance and high oxygen resistance, so that the ceramic-based composite material system can be used for a long time in high-temperature fire rescue, the service temperature exceeds 1000 DEG C, and the temperature of internal parts of a fire scene rescue unmanned aerial vehicle is ensured to be below the limit working temperature; and meanwhile, the surface-layer ceramic-based composite ceramic material has extremely high oxidation resistance.

The invention relates to a preparation method of a TD3 alloy surface oxidation-resistant coating, and belongs to the technical field of high-temperature-resistant coating preparation. According to thepreparation method, a transition layer selects NiO sol as raw materials, a composite ceramic layer selects Al2O3-SiO2 sol as the raw materials, and preparation is carried out by combining sol-gel, low-temperature sintering and electron beam cladding. The method is simple in process and easy to realize, and the prepared oxidation-resistant coating and the substrate have good bonding force, and also have good high-temperature oxidation corrosion resistance and washing-out resistance.

The invention discloses a preparation method of a corrosion-resistant baffle surface coating for a TFT (Thin Film Transistor) process, which comprises the following steps: (1) powder preparation: (1) taking a composite ceramic powder raw material, and mixing to form slurry; (2) adding a binder into the slurry formed in the step (1), and mixing to form granulation slurry; (3) carrying out spray granulation on the granulation slurry formed in the step (2) in a spray granulator to form basically spherical composite ceramic spray particles; (2) pretreatment: carrying out pretreatment on the baffle element base body; and (3) plasma spraying: performing plasma spraying on the composite ceramic spray particles to form a composite ceramic layer. According to the invention, the defects of black spots, short circuit and the like of the TFT film are reduced, and the display quality of LED and OLED displays is improved.

The invention discloses a pantograph wear-resistant metal bow angle with an isolation buffer layer, which is mounted on a pantograph of a rail transit vehicle and comprises a metal bow angle pipe, theisolation buffer layer is arranged on the upper surface of the metal bow angle pipe, and a wear-resistant coating is arranged on the isolation buffer layer. The isolation buffer layer is made of a nichrome material with self-adhesion performance, and the thickness of the isolation buffer layer is 30-60 microns. The pantograph wear-resistant metal bow angle is simple in structure, low in cost andhigh in reliability, and can solve the problems that in the prior art, cracks and chippings occur after a wear-resistant coating is sprayed, micro-cracks are generated after wear-resistant coating fragments can penetrate into a bow angle pipe base body, and multi-point fatigue failure of a bow angle is caused by subsequent expansion of the micro-cracks at the same time. The pantograph angle application reliability of the pantograph is improved, and safe and efficient operation of the high-speed motor train unit is guaranteed.