V2O5 nanoparticle/graphene lithium ion battery positive pole material and preparation method thereof
A technology for lithium-ion batteries and positive electrode materials, which is applied in the field of lithium-ion battery positive electrode materials and their preparation, and can solve problems such as limited electrochemical performance
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[0024] According to the literature (J.Am.Chem.Soc., 2008, 130, 5856-5857), the modified Hummer method was used to synthesize graphite oxide from natural graphite.
[0025] Disperse 40 mg of graphite oxide powder in N,N-dimethylformamide (DMF) and sonicate for 30 min to form a stable graphene oxide (GO) dispersion (1 mg / mL). Weigh 1g vanadium (IV) acetylacetonate (C 5 h 8 o 2 V) Disperse in the above GO dispersion and stir for 1 hour. A homogeneous and stable solution is formed. It was transferred to a 50ml hydrothermal kettle and reacted at 200°C for 20 hours. After the solution was cooled to room temperature, the obtained black precipitate was collected by centrifugation, washed several times with alcohol and deionized water, and dried at 80°C for 6 hours. The dried precipitate was calcined at 400°C for 2 hours with a heating rate of 10°C / min to obtain V 2 o 5 -GE lithium ion battery cathode material.
[0026] The specific steps of button battery assembly are as follo...
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