Method for preparing lignin polyether polyols

A technology of lignin polyether and polyol, which is applied in the field of preparation of lignin polyether polyol, can solve problems such as difficult problems, inability to use, and unreasonable use of by-products, and achieve the effect of simple process, simple steps, and non-deformation

Active Publication Date: 2014-05-07
单成敏
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Problems solved by technology

[0002] At present, alcohols such as ethylene glycol, propylene glycol, and butanol are mainly prepared from corn, and the by-products produced during the preparation process cannot be rationally utilized, such as the corn sugar residue and corn alcohol residue produced, whether it is Liq

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Example Embodiment

[0009] The specific implementation of the present invention will be described in further detail below in conjunction with the examples. The following examples are used to illustrate the present invention, but not to limit the scope of the present invention.

[0010] A preparation method of lignin polyether polyol includes the following steps:

[0011] 1) Put the following parts by weight of raw materials into the reactor: alkali lignin 30-120, water 20-150, cellulase 0.5-10, sodium hydroxide 0.5-3, furfuryl alcohol 0.1-50, furfural 1-15; The reactor is heated to 30-65°C and stirred for 2-6 hours to cause the alkali lignin to undergo an enzymatic hydrolysis reaction to obtain an enzymatically hydrolyzed modified alkali lignin;

[0012] 2) Put the enzymatically hydrolyzed modified alkali lignin and liquid polyol, bimetallic catalyst, diethylene glycol, and glycerin obtained in step 1) into the reactor in the following parts by weight: Enzymatically hydrolyzed modified alkali lignin 60...

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Abstract

The invention relates to a method for preparing lignin polyether polyols. The method comprises the following steps: (1) adding the following raw materials into a reactor in parts by weight: 30-120 parts of alkali lignin, 20-150 parts of water, 0.5-10 parts of cellulase, 0.5-3 parts of sodium hydroxide, 0.1-50 parts of furfuryl alcohol and 1-15 parts of furfural; raising the temperature of the reactor to be 30-65 DEG C, stirring for 2-6 hours, and preparing enzymatic hydrolysis modified alkali lignin; (2) adding the enzymatic hydrolysis modified alkali lignin prepared in the step (1), liquid-state polyhydric alcohols, a bimetallic catalyst, diethylene glycol and glycerol into the reactor in parts by weight, stirring and raising the temperature to be 80-120 DEG C, introducing a small amount of nitrogen into the bottom of the reactor for carrying out bubbling reaction, vacuumizing, adding 0.01-12 parts of epoxypropane into the reactor, reacting in a closed mode for 1-6 hours under normal pressure, and preparing the lignin polyether polyols. The method for preparing the lignin polyether polyols is simple in steps, byproducts can be reasonably and deeply processed by utilizing corn, and the prepared lignin polyether polyols are stable in physical properties, can serve as novel foam materials and are difficult to deform.

Description

technical field [0001] The invention relates to a preparation method of lignin polyether polyol. Background technique [0002] At present, alcohols such as ethylene glycol, propylene glycol, and butanol are mainly prepared from corn, and the by-products produced during the preparation process cannot be rationally utilized, such as the corn sugar residue and corn alcohol residue produced, whether it is Liquid or solid, in the past, belonged to industrial waste and could not be used, and how to dispose of these waste safely and harmlessly is also an industry problem; therefore, there is an urgent need for a preparation method of using corn deep processing by-products to prepare lignin polyether polyols. Contents of the invention [0003] In order to solve the above technical problems, the present invention provides a method for preparing lignin polyether polyol, the preparation process is simple, and the prepared lignin polyether polyol has good physical properties. [0004...

Claims

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Application Information

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IPC IPC(8): C08G65/28C08H7/00
Inventor 单成敏
Owner 单成敏
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