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Polyether modified organic silicon defoamer and preparation method thereof

A technology of silicone defoamer and polyether modified silicone oil, which is applied in textiles, papermaking, fiber processing, etc., can solve the problems of high price, short foam suppression time, low surface energy, etc., and achieves simple manufacturing method and foam suppression. Long time, increased dispersion effect

Active Publication Date: 2014-05-28
TIANJIN POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the traditional silicon-containing defoamers have low surface energy, strong hydrophobicity, and poor miscibility with other organic substances. Therefore, in the aqueous application system of chemical fiber oils, there are poor defoaming effects and short foam suppression time. shortcoming
However, most domestic defoamers that can meet the requirements of spinning production are monopolized by foreign products, which are expensive and increase the production cost of enterprises.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] The weight percentage composition of the compounded raw materials of the polyether modified silicone defoamer is: 10% polyether modified silicone oil, 15% white carbon black, 25% dimethyl silicone oil, 9% emulsifier, 4% regulator, Water 37%. Emulsifier is Span60, regulator is C 4 Fatty alcohol polyoxyethylene ether. The preparation process is:

[0024] (a) Put polyether modified silicone oil, white carbon black and dimethyl silicone oil into the reaction kettle by weight percentage, stir and heat up to 200°C to prepare silicone paste;

[0025] (b) Add the emulsifier Span60 into the silicone paste, heat it to 50°C, and then add the modifier C 4 Fatty alcohol polyoxyethylene ether, add water drop by drop, stir for 8 hours, cool, discharge, and pack.

Embodiment 2

[0027] The weight percentage composition of the compounded raw materials of the polyether modified silicone defoamer is: 10% polyether modified silicone oil, 10% white carbon black, 40% dimethyl silicone oil, 9% emulsifier, 3% regulator, Water 28%. The emulsifier is Span60 and Tween60, the regulator is C 4 Fatty alcohol polyoxyethylene ether. The preparation process is:

[0028] (a) Put polyether modified silicone oil, white carbon black and dimethyl silicone oil into the reaction kettle by weight percentage, stir and heat up to 200°C to prepare silicone paste;

[0029] (b) Add the emulsifier (the weight ratio of Span60 and Tween60 is 1:1) into the silicone paste, heat it to 50°C, and then add the modifier C 4 Fatty alcohol polyoxyethylene ether, add water drop by drop, stir for 8 hours, cool, discharge, and pack.

Embodiment 3

[0031] The weight percentage composition of the compounded raw materials of the polyether modified silicone defoamer: 5% polyether modified silicone oil, 15% white carbon black, 30% dimethyl silicone oil, 10% emulsifier, 1.75% regulator, Water 38.25%. The emulsifier is Span40, Span60 and Tween60, and the regulator is C 4 Fatty alcohol polyoxyethylene ether. The preparation process is:

[0032] (a) Put polyether modified silicone oil, white carbon black and dimethyl silicone oil into the reaction kettle by weight percentage, stir and heat up to 200°C to prepare silicone paste;

[0033] (b) Dissolve the emulsifier (the weight ratio of Span40, Span60 and Tween60 is 1:2:2) at 70°C and add it to the silicone paste, heat it to 75°C, and then add the modifier C 4 Fatty acid polyoxyethylene ether, add water drop by drop, stir for 7 hours, cool, discharge, and pack.

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Abstract

The invention discloses a polyether modified organic silicon defoamer and a preparation method thereof. The defoamer comprises compounding raw materials in percentage by weight as follows: 5%-40% of polyether modified silicone oil, 10%-40% of dimethyl silicone oil, 5%-30% of white carbon black, 2%-30% of an emulsifying agent, 0.01%-8% of a regulator and 10%-80% of water, and the sum of components is 100%. According to the preparation method of the polyether modified organic silicon defoamer, the polyether modified organic silicon defoamer is prepared by the compounding raw materials in percentage by weight, the technological method is as follows: (a), the polyether modified silicone oil, the white carbon black and the dimethyl silicone oil in different weight ratios are put in a reaction kettle, stirred and heated to the temperature of about 200 DEG C, and a silicon paste is prepared; and (b), the emulsifying agent is added into the silicon paste and heated to the temperature of about 50 DEG C-75 DEG C, the regulator is added, water is dropwise added, the mixture is stirred for 5-10 hours, cooled, discharged and packaged, and the polyether modified organic silicon defoamer is obtained.

Description

technical field [0001] The invention relates to the field of auxiliary agent manufacturing in synthetic fiber processing technology, in particular to a polyether modified silicone defoamer and a preparation method thereof. Background technique [0002] In the production process of polyester and other chemical fibers, the use of chemical fiber oils usually has foam problems. Since the oil agent components are mostly ionic surfactants, which have certain foaming properties, a large amount of foam will be generated when the oil agent is compounded and used, resulting in an increase in the volume of the entire oil agent system, and the oil agent device cannot be produced at full capacity. When the agent emulsion is transported, it is more likely to foam in the oil immersion tank after polyester processing. The foam overflow not only causes waste of resources, but also pollutes the working environment; the foam enters the sewage treatment system, causing adverse effects on microb...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M15/647D06M15/643D06M11/79D06M15/53D06M13/144
Inventor 郑帼孙玉周存徐进云刘燕军孙波泉张朝
Owner TIANJIN POLYTECHNIC UNIV
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