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A kind of glyphosate ammonium salt soluble granule and preparation method thereof

A glyphosate ammonium salt, soluble technology, applied in botanical equipment and methods, herbicides, algicides, biocides, etc., can solve problems such as toxicity, skin and eye irritation, etc. The effect of refined processing and low storage and transportation costs

Active Publication Date: 2016-02-10
长兴德源环保助剂有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Ethoxylated fatty amines (such as tallow amine polyoxyethylene ether) are widely used as special additives for glyphosate. Although they have good synergistic performance, they still have relatively serious shortcomings, especially their harmful effects on skin and eyes. It is highly irritating and highly toxic to fish and other aquatic organisms. Therefore, developing its substitutes or reducing its irritating effect on skin and eyes through compounding has become a research hotspot at home and abroad.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Preparation of additives:

[0033] The auxiliary agent is calculated in parts by weight and consists of the following components:

[0034] Ethylene oxide: 25, KOH: 0.3, acetic acid: 0.4,

[0035] Dodecylamine: 16, octadecylamine: 15, tallow amine: 5,

[0036] Polypropylene: 16, fatty acid methyl ester: 25.

[0037] The preparation method of the auxiliary agent is: put dodecylamine, stearylamine, tallow amine, fatty acid methyl ester and KOH into a 1L reactor equipped with a thermometer, agitator and a jacket, at 120°C, -0.97Mpa Dehydrate under vacuum for 1.5 hours; then use N 2 Replace 3 times. After the water content is qualified, pass polypropylene into the reaction kettle at 115℃; when the temperature in the kettle rises and the pressure drops, continuously pass ethylene oxide; after the passage is completed, keep it warm at 120°C for aging After 1.5 hours to atmospheric pressure, vacuum, discharge, and neutralize with acetic acid to obtain the finished product.

Embodiment 2

[0039] A glyphosate ammonium salt soluble granule, in parts by weight, consists of the following components:

[0040] Glyphosate ammonium salt: 793, ammonium sulfate: 97, adjuvant: 100, water: 8.

[0041] According to the ratio, add glyphosate ammonium salt and ammonium sulfate to the mixer and mix; the mixed materials are crushed by the pulverizer, and slowly add the additives to the mixed materials, and then add water, continue Kneading into a moist material without obvious lumps; moving the above-mentioned kneaded material to a granulator for granulation. The obtained soluble granules are dried (2h) at no higher than 50°C, and the finished glyphosate soluble granules are obtained by selecting a screen with a suitable diameter and sieving.

[0042] Table 1: Technical indicators of glyphosate ammonium salt soluble granules

[0043] Test items

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PUM

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Abstract

The invention discloses an ammonium glyphosate soluble granule auxiliary, which consists of the following components in parts by weight: 700 to 800 parts of ammonium glyphosate, 50 to 100 parts of ammonium sulfate, 100 to 120 parts of auxiliaries and 6 to 15 parts of water. A preparation method comprises the following technical steps: (1) adding the ammonium glyphosate and the ammonium sulfate into a mixer for mixing in the ratio; (2) crushing the uniformly mixed materials by a crusher, slowly and uniformly adding the auxiliaries into the mixed materials, adding water, and kneading the mixture to form a humid material without obvious blocks; (3) transferring the kneaded material to a granulator for granulation; (4) drying obtained soluble granules at the temperature of not more than 50 DEG C for 2 hours, and sieving the soluble granules by a sieve to obtain glyphosate soluble granule finished products.

Description

Technical field [0001] The invention belongs to the technical field of pesticide additives, and more particularly relates to a glyphosate ammonium salt soluble granule and a preparation method thereof. Background technique [0002] In 1971, Monsanto Company developed Glyphosate, a broad-spectrum herbicide with epoch-making significance in world agriculture. In the mid and late 1970s, it introduced isopropylamine, amine and sodium salts of glyphosate; ICI launched trimethyl in 1989 Matte salt. At present, glyphosate has become the world's most widely used pesticide variety with the largest output, and its annual sales have always ranked first among pesticides. [0003] Glyphosate is a highly effective, low-toxic, broad-spectrum herbicide. It can not only control annual weeds, but also control perennial deep-rooted weeds. It is often used as a biocidal herbicide and is mainly used in orchards, mulberry gardens, and tea gardens. , Rubber plantations and sugar cane plantations. In a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A01N25/14A01N57/20A01P13/00C08G65/26
Inventor 王德新
Owner 长兴德源环保助剂有限公司
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