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A method for preparing neodymium-iron-boron by regeneration of waste materials containing neodymium-iron-boron

A technology of NdFeB and waste materials, which is applied in the direction of magnetic materials, process efficiency improvement, magnetic objects, etc., can solve the problems of NdFeB magnetic properties, low recycling rate, limited practical value, etc., and achieve improved resistance Oxidation performance, accurate analysis results, and high recycling rate

Active Publication Date: 2017-01-04
CHINALCO JINYUAN RARE EARTH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the prior art, as reported in the literature, Liu Mingqing and others roasted and dissolved the NdFeB waste materials by the hydrochloric acid excellent solution method, and then re-separated them into rare earth oxides, and then prepared the metals required for magnet production through metal smelting. The process is cumbersome, the process is long, and the manufacturing cost is high
Chinese patent 95101204.5 introduces a method of producing NdFeB by remelting waste materials. This method produces a large amount of slag, the process is complicated, the yield is low, and the practical value is poor.
This method still has many problems in the implementation process of the waste pretreatment process, such as oily materials, small-sized materials, etc., which are difficult to clean; after the treatment, it is necessary to increase the process of remelting and homogenization, and only a small amount can be added to the new waste. Among the materials, the recycling rate is not high, the magnetic properties of NdFeB are not good, and the practical value is limited.

Method used

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Experimental program
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Effect test

Embodiment 1

[0019] Produce N45 products from N45 waste.

[0020] Take N45 waste, put it in an ultrasonic cleaner, and ultrasonically clean it in an aqueous solution of trisodium phosphate for 10 minutes. After the surface is free of oil stains, take out the waste and clean the surface with water until there is no adhesion on the surface, then put it in an oven Bake at 300°C for 2 hours. Then polish it in a shot blasting machine for 5 minutes until the surface of the material is silver-white in the color of the metal matrix.

[0021] Under the protection of inert gas, the previously treated waste is crushed into 10mm-sized particles in the crusher, and then mixed in the mixer for 50 minutes, and the samples are taken and its chemical composition is accurately analyzed:

[0022] Its mass percentage is PrNd 30.5 Al 0.45 Cu 0.14 Nb 0.24 B 1.01 Fe 67.66

[0023] Design product composition PrNd 31.5 Al 0.45 Cu 0.14 Nb 0.24 B 1.01 Fe 66.66

[0024] Composition design is carried ou...

Embodiment 2

[0029] 40SH products are produced from 38SH waste.

[0030] Take 38SH waste, put it in an ultrasonic cleaner, and ultrasonically clean it in an aqueous solution with detergent for 15 minutes. After the surface is free of oil stains, take out the waste and clean the surface with clean water until there is no adhesion on the surface, then put it in an oven Bake at 300°C for 1.5 hours. Then polish it in a shot blasting machine for 6 minutes until the surface of the material is silver-white in the color of the metal matrix.

[0031] Under the protection of inert gas, the previously treated waste is crushed into 8mm-sized particles in the crusher, and then mixed in the mixer for 60 minutes. Samples are taken and its chemical composition is accurately analyzed:

[0032] Its mass percentage is PrNd 29.5 Dy 2.3 Al 0.7 Cu 0.20 Nb 0.3 Ga 0.1 B 1.0 Fe 65.9

[0033] Design product composition PrNd 29 Dy 2.5 Al 0.85 Cu 0.20 Nb 0.4 Ga 0.15 B 1.0 Fe 65.9

[0034] Compositi...

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Abstract

The invention provides a method for preparing neodymium iron boron through regenerating a waste material containing neodymium, iron and boron. The method comprises steps of (1) preprocessing the waste material; (2) correcting the components of the waste material; (3) crushing by hydrogen; (4) preparing into powder; (5) molding under a magnetic field; and (6) vacuum sintering. The method fully uses the waste material recycled in a production process, has high recovery rate of the waste material, can produce high performance product, has a simple and controllable flow, has high operability, uses no strong acid and strong base polluting the environment, is environment-friendly and energy-saving, and has high social and economic benefits.

Description

technical field [0001] The invention relates to the field of metallurgy, in particular to a method for reproducing neodymium-iron-boron waste materials containing neodymium-iron-boron. Background technique [0002] NdFeB has the title of "a generation of permanent magnet king". It has excellent comprehensive magnetic properties and is widely used in electronics, automobiles, medical care, environmental protection and energy saving, aerospace and other industrial fields. According to incomplete statistics, the global output of NdFeB permanent magnets reached 110,000 tons in 2011, and has maintained a high growth rate of more than 20% in the last ten years. [0003] With the upgrading and scrapping of electronic devices, automobiles and other instruments and equipment, a large amount of NdFeB waste will inevitably be produced. The proportion of waste materials can be as high as 15-30%. If they cannot be effectively treated, these materials and the rare earths in them can only...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B7/00H01F1/057
CPCY02P10/20
Inventor 黄伟超汤盛龙律方忠甘家毅
Owner CHINALCO JINYUAN RARE EARTH
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