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Method for reducing GaN epitaxial defects through wet etching

A technology of epitaxial defect and wet etching, which is applied in the direction of electrical components, circuits, semiconductor devices, etc., can solve problems such as screw dislocations that cannot be alleviated, achieve good control of corrosion effects, reduce material prices, and improve crystal quality.

Inactive Publication Date: 2014-06-25
西安利科光电科技有限公司
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Alkaline solution corrosion can resolve edge dislocations and mixed dislocations, but cannot alleviate screw dislocations

Method used

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  • Method for reducing GaN epitaxial defects through wet etching
  • Method for reducing GaN epitaxial defects through wet etching
  • Method for reducing GaN epitaxial defects through wet etching

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Embodiment Construction

[0031] see figure 1 — Figure 5 , the invention provides a method for reducing GaN epitaxial defects by wet etching, comprising the following steps:

[0032] 1) Growing non-doped gallium nitride on a sapphire wafer; the specific steps are:

[0033] 1.1) Put the sapphire wafer into MOCVD;

[0034] 1.2) Adjust the temperature in MOCVD to 500-600°C and the pressure to 600 Torr, so that GaN can grow 30nm on the sapphire wafer;

[0035] 1.3) Raise the temperature in MOCVD to 1000-1100°C and pressure 400 Torr to grow non-doped gallium nitride 1.2um.

[0036] 2) Put the sapphire wafer into the acidic solution, then take it out and wash it with ionized water and dry it; the time for the sapphire wafer to be placed in the acidic solution is 10-60 minutes, and the temperature of the acidic solution is 100-300°C. Acidic solution is H 3 PO 4 . Sapphire wafer into H 3 PO 4 Solution time is 15 min, H 3 PO 4 The temperature of the solution was 200°C.

[0037] 3) The sapphire wafe...

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Abstract

The invention provides a method for reducing GaN epitaxial defects through wet etching. The method comprises the following steps that (1) non-doped gallium nitride is grown on a sapphire wafer; (2) the sapphire wafer is placed into an acid solution and then taken out to be cleaned through ionized water and spin-dried; (3) the sapphire wafer cleaned and spin-dried in the step (2) is made to grow again; (4) a GaN base is bonded on a silicon substrate and the sapphire wafer is peeled off by using high-temperature lattice mismatching stress. According to the method for reducing the GaN epitaxial defects through wet etching, the acid solution is used, and screw dislocation and mixed dislocation can be avoided.

Description

technical field [0001] The invention relates to the technical field of LED epitaxial growth, in particular to a method for reducing GaN epitaxial defects by wet etching. Background technique [0002] GaN is usually grown on a sapphire substrate with a relatively high defect density of 1x10 8-9 / cm 2 , due to the large lattice mismatch between GaN and sapphire. Material defects are an important limiting factor in LED device characteristics; this problem becomes more serious when the emission wavelength is extended from blue to ultraviolet or green. From the reported technology, the method to solve this problem is epitaxial lateral overgrowth (ELOG, Epitaxial Lateral Over Growth), defect blocking layer (DBL, Defect Blocking La x er) and sapphire patterned substrate (PSS, Pattern Sapphire Substrate). [0003] The ELOG approach uses an oxide-patterned GaN template, which reduces defect density by 1-2 orders of magnitude. However, defect reduction occurs only in oxide-covere...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L33/00
CPCH01L33/0066
Inventor 胡丹缪炳有张汝京黄宏嘉
Owner 西安利科光电科技有限公司
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