Five-membered heterocyclic derivative-bridged perylene diimide dipolymer and its preparation method and use in organic photovoltaic device

A perylene diimide dimer and dimer technology, which is applied in the field of asymmetric perylene diimide dimers, can solve the problems of poor solubility and film-forming properties, and limit the application of photovoltaic materials.
CN104045657AActive Publication Date: 2014-09-17INST OF CHEM CHINESE ACAD OF SCI
11 Cites 19 Cited by

Patent Information

Authority / Receiving Office
CN · China
Current Assignee / Owner
INST OF CHEM CHINESE ACAD OF SCI
Publication Date
2014-09-17

Smart Images

  • Figure 1
    Figure 1
  • Figure 2
    Figure 2
  • Figure 3
    Figure 3
Patent Text Reader

Abstract

The invention provides a 1,1'-dialkoxy-substituted asymmetrical perylene diimide dipolymer having a novel structure, and the perylene diimide dipolymer is an electron acceptor-type organic micromolecule having solution processibility. The invention also provides a method for synthesis of the asymmetrical substituted perylene diimide dipolymer. The asymmetrical substituted perylene diimide dipolymer as a receptor and P3HT isoelectronic donor-type polymer are combined to form an organic solar cell so that high photoelectric conversion efficiency is obtained. The asymmetrical substituted perylene diimide dipolymer provides a novel direction for photovoltaic field research.
Need to check novelty before this filing date? Find Prior Art

Description

technical field

[0001] The invention belongs to the field of organic photovoltaic materials, and relates to a 1,1'-dialkoxy substituted asymmetric perylene diimide dimer, its preparation method and its application in the field of organic photovoltaic materials. Background technique

[0002] Solar energy is a green and environmentally friendly renewable energy, and its transformation and application is one of the important strategic ways to solve the energy crisis. Compared with the high photoelectric conversion efficiency (20-30%) of silicon-based and inorganic semiconductor photovoltaic materials, the conversion efficiency of polymer photovoltaic materials is still low, only about 6-8%.

[0003] Traditional polymer photovoltaic materials use poly(3-hexyl-thiophene) (referred to as P3HT, formula a) as the electron donor material, fullerene derivatives ([6,6]-phenyl-C61-butyric acid methyl ester, referred to as PC61BM or PC60BM and [6,6]-phenyl-C71-butyric acid methyl ester,...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More