Modified sulfur/carbon doped lithium cobalt oxide cathode material and preparation method thereof
A positive electrode material, lithium cobaltate technology, applied in the field of modified sulfur/carbon doped lithium cobaltate positive electrode material and its preparation, can solve problems such as restricting development prospects, lack of cobalt resources, toxicity, etc., and achieve extended storage time , Improve self-discharge, the effect of simple method
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[0013] The modified sulfur / carbon doped lithium cobaltate positive electrode material is prepared by the following components according to the ratio shown in parts by weight, sulfur / carbon composite material 25, active material 70, functional material 3, conductive material 10 10. Adhesive material 10. The functional material is 60% lithium iron nitrate solution. The positive electrode material is lithium cobalt oxide. The conductive agent is flake graphite
[0014] The preparation method of the modified sulfur / carbon doped lithium cobaltate cathode material comprises the following steps:
[0015] (1) Put the carbon material and sublimed sulfur or sulfur powder into a zirconia or agate ball mill jar according to the above weight ratio, inject the ball mill jar with high-purity inert gas in the glove box, and place it on a planetary ball mill for 5 hours. The ball milling speed is 500 r / min, the mass ratio of elemental sulfur and carbon is 1:2~3:2; the sulfur / carbon composit...
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