Preparation method of heat-resisting PVC (polyvinyl chloride)/ABS (acrylonitrile butadiene styrene)/PMMA (polymethyl methacrylate) alloy material

A technology of alloy material and high temperature resistance, which is applied in the field of polymer materials, can solve the problems of wear resistance decline and achieve good wear resistance

Active Publication Date: 2014-12-17
NINGBO YOSUN AUTO PARTS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0010] The technical problem to be solved by the present invention: After th

Method used

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  • Preparation method of heat-resisting PVC (polyvinyl chloride)/ABS (acrylonitrile butadiene styrene)/PMMA (polymethyl methacrylate) alloy material
  • Preparation method of heat-resisting PVC (polyvinyl chloride)/ABS (acrylonitrile butadiene styrene)/PMMA (polymethyl methacrylate) alloy material

Examples

Experimental program
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Embodiment 1

[0032] A preparation method of a high temperature resistant PVC / ABS / PMMA alloy material, comprising the following methods:

[0033] Step 1: Mix PVC140Kg, ABS10Kg, PMMA15Kg, fluorine rubber 4Kg, white carbon black 15Kg, dioctyl phthalate 5Kg, aluminum stearate 4Kg, layered silica thin rock powder 6Kg, clay 8Kg, silicon micropowder (400 Add 3Kg (mesh to 600 mesh) and 6Kg zinc oxide into the mixer, heat up, the temperature is 70°C, stir evenly, the stirring speed is 500rpm, the stirring time is 20min, and the material is cooled;

[0034] Step 2: Extrude the cooling material obtained in the first step with a twin-screw extrusion granulator, and the extrusion temperature is 190°C to obtain granules A;

[0035] The 3rd step: the particle A obtained in the 2nd step, 5Kg of chlorinated polyethylene elastomer and 4Kg of triallyl isocyanate are stirred and mixed uniformly, and the stirring speed is 700rpm;

[0036] Step 4: Add the mixture obtained in Step 3 into a single-screw extruder...

Embodiment 2

[0039] A preparation method of a high temperature resistant PVC / ABS / PMMA alloy material, comprising the following methods:

[0040] Step 1: Mix PVC180Kg, ABS12Kg, PMMA20Kg, fluororubber 6Kg, white carbon black 20Kg, dioctyl phthalate 10Kg, aluminum stearate 6Kg, layered silica thin rock powder 12Kg, pottery clay 14Kg, silicon micropowder (400 Add 6Kg of mesh to 600 mesh) and 10Kg of zinc oxide into the mixer, heat up, the temperature is 90°C, stir evenly, the stirring speed is 700rpm, the stirring time is 30min, and the material is discharged and cooled;

[0041] Step 2: Extrude the cooling material obtained in the first step with a twin-screw extrusion granulator at a temperature of 200°C to obtain granules A;

[0042] The 3rd step: the particle A obtained in the 2nd step is mixed with chlorinated polyethylene elastomer 10Kg and triallyl isocyanate 6Kg in stirring, and the stirring speed is 800rpm;

[0043] Step 4: Add the mixture obtained in Step 3 into a single-screw extru...

Embodiment 3

[0046] A preparation method of a high temperature resistant PVC / ABS / PMMA alloy material, comprising the following methods:

[0047] Step 1: Mix PVC160Kg, ABS11Kg, PMMA17Kg, fluororubber 5Kg, white carbon black 17Kg, dioctyl phthalate 7Kg, aluminum stearate 5Kg, layered silica thin rock powder 8Kg, clay 12Kg, silicon micropowder (400 Add 5Kg (mesh to 600 mesh) and 7Kg zinc oxide into the mixer, heat up, the temperature is 80°C, stir evenly, the stirring speed is 600rpm, the stirring time is 25min, and the material is cooled;

[0048] Step 2: Extrude the cooling material obtained in Step 1 with a twin-screw extrusion granulator, and the extrusion temperature is 195°C to obtain granules A;

[0049] The 3rd step: the particle A obtained in the 2nd step, 7Kg of chlorinated polyethylene elastomer and 5Kg of triallyl isocyanate are stirred and mixed evenly, and the stirring speed is 750rpm;

[0050] Step 4: Add the mixture obtained in Step 3 into a single-screw extruder, and perform...

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Abstract

The invention relates to a preparation method of a heat-resisting PVC/ABS/PMMA alloy material and belongs to the technical field of high polymer materials. The method comprises the following steps of adding PVC, ABS, PMMA, fluororubber, white carbon black, dioctyl phthalate, aluminum stearate, stratiform silicon flagstone powder, argil, silica powder and zinc oxide into a mixer, increasing the temperature and performing temperature increasing, uniform mixing, discharging and cooling; extruding the obtained cooled materials through a double-screw extrusion granulator to obtain granules A; uniformly mixing and stirring the granules A, chlorinated polyethylene elastomer and trimerical isocyanate triene propyl ester; adding the mixture above into a single-screw extruder, and performing hot-melt extrusion to obtain the heat-resisting PVC/ABS/PMMA alloy material. The hot-melt extrusion to obtain the heat-resisting PVC/ABS/PMMA alloy material still obtains good wear-resisting performance under high-temperature testing.

Description

[0001] technical field [0002] The invention relates to a preparation method of a high temperature-resistant PVC / ABS / PMMA alloy material, belonging to the technical field of polymer materials. [0003] Background technique [0004] Polyvinyl chloride (PVC) is a thermoplastic resin polymerized by vinyl chloride under the action of an initiator. It is a homopolymer of vinyl chloride. Vinyl chloride homopolymers and vinyl chloride copolymers are collectively referred to as vinyl chloride resins. PVC is a white powder with an amorphous structure and a small degree of branching. The molecular weight of industrially produced PVC is generally in the range of 50,000 to 120,000, with a large polydispersity, and the molecular weight increases with the decrease of the polymerization temperature; there is no fixed melting point, it starts to soften at 80-85°C, and becomes viscoelastic at 130°C , 160 ~ 180 ℃ began to change into a viscous flow state; good mechanical properties, ten...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L55/02C08L33/12C08L27/12C08L23/28C08K13/06C08K9/02C08K9/04C08K3/22C08K3/36C08K5/12C08K5/098C08K3/34
Inventor 陈凌王琰任琪程晓
Owner NINGBO YOSUN AUTO PARTS
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