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Etching solution composition and etching method

A technology of etching solution and composition, which is applied in the manufacture of electrical components, circuits, semiconductors/solid-state devices, etc., and can solve problems such as the inability to obtain thin lines and the inability to control the etching speed

Active Publication Date: 2018-02-13
ADEKA CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] However, for example, when the etchant disclosed above is used in order to form a thin line including a titanium-based film and a copper-based film by etching a laminated film including a titanium-based film and a copper-based film together, there is a problem that sometimes it cannot be controlled. Etching speed, thin lines with the desired width, or sometimes thin lines with the desired cross-sectional shape cannot be obtained

Method used

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  • Etching solution composition and etching method
  • Etching solution composition and etching method
  • Etching solution composition and etching method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] Etching solution compositions were prepared in the proportions shown in Table 1 to obtain product Nos. 1 to 22 of the present invention. In addition, the balance of content is water.

[0054] Table 1

[0055] Invention Product No.

Embodiment 2

[0061] Form a resist pattern with a line width of 10 μm and an opening of 100 μm on a glass substrate laminated in the order of titanium (30 nm) and copper (500 nm) using a positive liquid resist, and cut the obtained substrate into 10 mm×10 mm , as a test piece, this test piece was subjected to pattern etching by a spraying method using product Nos. 1 to 22 of the present invention at 35° C. and a spray pressure of 0.05 MPa. As for the etching treatment time, only the time required to eliminate the residue between wirings was performed in each etchant, and this time was defined as "optimum etching time".

Embodiment 3

[0071] Form a resist pattern with a line width of 10 μm and an opening of 100 μm on a glass substrate laminated in the order of titanium (30 nm) and copper (500 nm) using a positive liquid resist, and cut the obtained substrate into 10 mm×10 mm , as a test piece, this test piece was subjected to pattern etching by a spray method using product Nos. 2, 4, 5, and 16 of the present invention at 35° C. and a spray pressure of 0.05 MPa. It should be noted that the etching treatment time was 30 seconds longer than the optimum etching time.

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Abstract

The present invention relates to etching liquid composition and etching method. [Problem] The object of the present invention is to provide an etchant composition and an etching method using the same, which can obtain a thin line of a desired width in the simultaneous etching of a laminated film including a titanium-based film and a copper-based film, and can also obtain Thin wire with preferred cross-sectional shape. [Solution] The present invention relates to an etchant composition for co-etching a laminated film including a titanium-based film and a copper-based film, characterized by comprising an aqueous solution containing: (A) hydrogen peroxide (B) fluoride ion supply source: 0.02 to 2 mass %; (C) organic carboxylic acid: 5 to 60 mass %; and (D) selected from azole compounds and having 1 in the structure At least one compound of a 6-membered heterocyclic compound containing three or more nitrogen atoms and three double bonds: 0.01 to 5% by mass.

Description

technical field [0001] The present invention relates to an etchant composition and an etching method using the etchant composition, and more specifically, to an etchant composition for etching a laminated film including a titanium-based film and a copper-based film together and its use The etching method of this etchant composition. Background technique [0002] It is known that the wiring material of a display represented by a flat panel display uses copper or a wiring mainly composed of copper, and titanium or titanium nitride is used as a wiring material in order to meet the requirements for a larger size and a higher resolution of the display. Titanium-based metals are represented as barrier films. Various wet etching techniques for copper and titanium-based multilayer films are known. [0003] For example, Patent Document 1 discloses an etchant for a multilayer thin film comprising a copper layer and a titanium layer, which contains hydrogen peroxide, nitric acid, a f...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23F1/18C23F1/26C23F1/44H01L21/3213
CPCC23F1/18C23F1/26C23F1/44
Inventor 石崎隼郎大宫大辅
Owner ADEKA CORP