Compound microorganism oil-displacing agent for oil production and compounding method thereof

A technology of composite microorganisms and oil displacement agents, applied in the direction of drilling compositions, chemical instruments and methods, etc., can solve the problems of large formation damage, high microbial inactivation rate, and large environmental pollution in the reservoir, and achieve composite The effect of strong performance, wide application range and strong operability

Inactive Publication Date: 2015-01-07
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] (2) Commonly used oil displacement surfactants are easy to improve the efficiency of water flooding, but they cause great damage to the formation, great environmental pollution in the reservoir, and high microbial inactivation rate
However, this oil displacement agent is only suitable for oil displacement and demulsification and demulsification using exogenous microbial technology in oil fields, and after compounding with the mentioned chemical surfactants, there is a certain degree of biological toxicity in the reservoir

Method used

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  • Compound microorganism oil-displacing agent for oil production and compounding method thereof
  • Compound microorganism oil-displacing agent for oil production and compounding method thereof
  • Compound microorganism oil-displacing agent for oil production and compounding method thereof

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Experimental program
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Effect test

Embodiment 1

[0034] Embodiment 1 Composite microbial oil displacement agent A and its composite method for oil recovery

[0035] (1) Composite microbial oil displacement agent A component and its ratio

[0036] Composite microbial oil displacement agent A component and its proportion are as follows:

[0037]

[0038] The molecular weight of the alkyl polyoxyethylene ether polymer is 6000-8000.

[0039] After laboratory evaluation, the critical micelle concentration of compound microbial oil displacement agent A is 9.5 mg / L; when the mass concentration of alkyl polyoxyethylene ether polymer is greater than 0.05%, the oil washing efficiency of A is greater than 96.0%, and the interfacial tension is lower than 0.06mN / m, see Table 1; A suitable reservoir conditions are temperature 25 ℃ ~ 71 ℃, salinity less than 72000mg / L; indoor physical simulation experiment compound microbial oil displacement agent A injection volume 0.5PV, enhanced oil recovery The rate is greater than 16%, see Table ...

Embodiment 2

[0050] Embodiment 2 Composite microbial oil displacement agent B for oil recovery and its composite method

[0051] (1) Composite microbial oil displacement agent B component and its proportion

[0052] Composite microbial oil displacement agent B component and its proportion are as follows:

[0053]

[0054] The molecular weight of the alkyl polyoxyethylene ether polymer is 7000-8500.

[0055] After laboratory evaluation, the critical micelle concentration of compound microbial oil displacement agent B is 9.2 mg / L; when the mass concentration of alkyl polyoxyethylene ether polymer is greater than 0.05%, the oil washing efficiency of B is greater than 97.0%, and the interfacial tension is lower than 0.05mN / m, see Table 3; B is suitable for reservoir conditions with a temperature of 40°C to 85°C and a salinity of less than 70,000mg / L; the injection volume of composite microbial oil displacement agent B is 0.5PV in indoor physical simulation experiments to improve oil recove...

Embodiment 3

[0065] Embodiment 3 Composite microbial oil displacement agent C and its composite method for oil recovery

[0066] (1) Composite microbial oil displacement agent C component and its ratio

[0067] Composite microbial oil displacement agent C component and its ratio are as follows: 0

[0068]

[0069] The molecular weight of the alkyl polyoxyethylene ether polymer is 9000-10000.

[0070] After laboratory evaluation, the critical micelle concentration of compound microbial oil displacement agent C is 9.0mg / L; when the mass concentration of alkyl polyoxyethylene ether polymer is greater than 0.05%, the oil washing efficiency of C is greater than 98.0%, and the interfacial tension is lower than 0.06mN / m, as shown in Table 5; C is suitable for reservoir conditions with a temperature of 40°C to 75°C and a salinity of less than 65,000mg / L; the injection volume of compound microbial oil displacement agent C is 0.5PV in indoor physical simulation experiments, and the oil recovery ...

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Abstract

The invention discloses a compound microorganism oil-displacing agent for oil production and a compounding method thereof. The oil-displacing agent is prepared from the following components in percentage by weight: 2-5 percent of an oligomeric surfactant, 5-9 percent of an activator and the balance of water, wherein the oligomeric surfactant is alkyl polyoxyethylene ether polymer, and the activator is prepared from a carbon source, a nitrogen source and a phosphorus source. The compounding method of the oil-displacing agent comprises the following steps: sampling oil-reservoir formation water, separating oil and water, and filtering the formation water; adding the activator into a closed reaction kettle according to the components and proportion, and stirring for 0.5-1.0 hour; adding the filtered formation water into the uniformly stirred activator, heating to 30-40 DEG C, and stirring for 2-3 hours to form an activator solution; and adding the oligomeric surfactant into the activator solution according to the component and proportion, heating to 40-50 DEG C, stirring for 4-6 hours, and standing for 0.5-2 hours. The oil-displacing agent has the characteristics of high displacement efficiency, low interfacial tension, wide oil reservoir application range, large scope of enhanced oil recovery, strong compounding performance, simple compounding method and strong operability, thus the oil-displacing agent can be widely applied to field testing of enhanced oil recovery.

Description

technical field [0001] The invention relates to the field of microbial oil recovery, in particular to a composite microbial oil displacement agent for oil recovery and a compounding method thereof. Background technique [0002] Endogenous microbial oil recovery technology directly utilizes the existing microbial community in the oil reservoir to enhance oil recovery. Due to the simplicity of its injection process and the avoidance of strain screening and fermentation processes, the cost is lower and its adaptability to the reservoir environment is strong, so it has been widely used. [0003] The disadvantages of current endogenous microbial oil recovery methods are: [0004] (1) Most of the endogenous nutrients used are pure nutrients. Such an activator has good water solubility, so the activator itself has good fluidity and low viscosity. It is difficult to ensure the residence time in the reservoir during the injection process. , to reduce the swept volume of the activat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/584
CPCC09K8/584C09K8/582
Inventor 曹嫣镔宋欣孙刚正曹功泽王静徐鹏王刚杜春安刘涛徐登霆宋永亭
Owner CHINA PETROLEUM & CHEM CORP
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