Method for manufacturing array substrate of liquid crystal display
A liquid crystal display and array substrate technology, which is applied in the field of manufacturing array substrates for liquid crystal displays, and can solve the problems of poor etching performance of three-layer copper-based metal films, poor heat release stability and poor storage stability, etc.
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Embodiment 1-1 to 1-4 and comparative example 1-1 to 1-4
[0039] Examples 1-1 to 1-4 and Comparative Examples 1-1 to 1-4: Preparation of etchant compositions
[0040] As given in Table 1 below, 180 kg of the etchant compositions of Examples 1-1 to 1-4 and Comparative Examples 1-1 to 1-4 were prepared.
[0041] [Table 1]
[0042] (Unit: wt%)
[0043]
[0044] ※Fluorinated compounds: ammonium bifluoride (NH 4 F·HF)
[0045] ※Azole compound: 3-amino-1,2,4-triazole
[0046] ※IDA: Iminodiacetic acid
[0047] ※NTA: Nitrilotriacetic acid
Embodiment 2-1 to 2-4 and comparative example 2-1 to 2-3
[0074] Examples 2-1 to 2-4 and Comparative Examples 2-1 to 2-3: Preparation of etchant compositions
[0075] As given in Table 3 below, 180 kg of the etchant compositions of Examples 2-1 to 2-4 and Comparative Examples 2-1 to 2-3 were prepared.
[0076] [table 3]
[0077] (Unit: wt%)
[0078]
[0079] ※Fluorinated compounds: ammonium bifluoride (NH 4 F·HF)
[0080] ※Azole compound: 3-amino-1,2,4-triazole
[0081] ※TEG: Triethylene glycol
[0082] ※IDA: Iminodiacetic acid
[0083] Test Example: Performance Evaluation of Etchant Composition
[0084]
[0085] MoTi was deposited on a glass substrate (100mm×100mm), a copper film was deposited on the MoTi, and then a photoresist with a predetermined pattern was formed on the glass substrate through a photolithography process. Thereafter, an etching process of Cu / MoTi was performed using the respective etchant compositions of Examples 2-1 to 2-4 and Comparative Examples 2-1 to 2-3.
[0086] The etching process was pe...
Embodiment 3-1 to 3-5 and comparative example 3-1 to 3-3
[0117] Examples 3-1 to 3-5 and Comparative Examples 3-1 to 3-3: Preparation of etchant compositions
[0118] As given in Table 5 below, 180 kg of the etchant compositions of Examples 3-1 to 3-5 and Comparative Examples 3-1 to 3-3 were prepared.
[0119] [table 5]
[0120] (Unit: wt%)
[0121]
[0122] ※Fluorinated compounds: ammonium bifluoride (NH 4 F·HF)
[0123] ※Azole compound: 3-amino-1,2,4-triazole
[0124] ※Polyol type surfactant: triethylene glycol
[0125] ※IDA: Iminodiacetic acid
[0126] ※Phosphate: sodium dihydrogen phosphate
[0127] Test Example: Evaluation of Etchant Composition Performance
[0128]
[0129] MoTi was deposited on a glass substrate (100mm×100mm), a copper film was deposited on the MoTi, and then a photoresist with a predetermined pattern was formed on the glass substrate through a photolithography process. Thereafter, an etching process of a three-layer film (MoTi / Cu / MoTi) was performed using the respective etchant compositions o...
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