Acid pickling regenerating liquid for denitration catalyst and regenerating method

A denitrification catalyst and regeneration solution technology, applied in the direction of catalyst regeneration/reactivation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems of great harm, increased conversion rate, and decreased activity of denitrification catalysts, and achieve denitrification efficiency High, good regeneration effect

Inactive Publication Date: 2015-01-21
TIANHE BAODING ENVIRONMENTAL ENG
View PDF4 Cites 20 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the prior art, the deactivated catalyst is generally cleaned with water or acid solution to remove the alkali metal and alkaline earth metal on the surface of the denitrification catalyst, so as to realize the regeneration of the deactivated denitrification catalyst. However, in actual coal-fired power plants, the chemical Poisoning is not only alkali metal and alkaline earth metal poisoning, but also more complex conditions, such as aluminum poisoning, iron poisoning, etc.
Among them, iron poisoning is more harmful to the denitrification catalyst. The i

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0070] In the present invention, the preparation method of the active replenishing liquid preferably includes the following steps:

[0071] a) Mix JFC-1 type fatty alcohol polyoxyethylene ether, TX-10 type alkylphenol polyoxyethylene ether, AEO type fatty alcohol polyoxyethylene ether with deionized water to obtain solution A;

[0072] b) mixing ammonium metavanadate, ammonium paratungstate, ammonium heptamolybdate, and acetamide with the solution A to obtain a solution B;

[0073] c) The solution B is mixed with nitric acid and aged to obtain an active replenishing solution.

[0074] The present invention mixes JFC-1 type fatty alcohol polyoxyethylene ether, TX-10 type alkylphenol polyoxyethylene ether, AEO type fatty alcohol polyoxyethylene ether with deionized water to obtain solution A. The present invention has no special limitation on the source of the JFC-1 type fatty alcohol polyoxyethylene ether, and the commercially available JFC-1 type fatty alcohol polyoxyethylene...

Embodiment 1

[0096] Add 5wt‰ of JFC-1 fatty alcohol polyoxyethylene ether into 0.5mol / L sulfuric acid solution, stir for 5min until uniform, and obtain pickling regeneration solution.

Embodiment 2

[0098] Add 3wt‰ of JFC-1 fatty alcohol polyoxyethylene ether into 0.3mol / L sulfuric acid solution, stir for 5min until uniform, and obtain pickling regeneration solution.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Concentrationaaaaaaaaaa
Login to view more

Abstract

The invention provides an acid pickling regenerating liquid for a denitration catalyst and a regenerating method. The acid pickling regenerating liquid comprises 0.1-1.0% of a surfactant and the balance being an acid solution, wherein the surfactant comprises one or more of JFC type fatty alcohol-polyoxyethylene ether, JFC-1 type fatty alcohol-polyoxyethylene ether, and JFC-2 type fatty alcohol-polyoxyethylene ether. Compared with the prior art, the acid pickling regenerating liquid has good effect of regenerating the toxic denitration catalyst in metallic elements, and the regenerated denitration catalyst has high denitration efficiency. Experiment results prove that in the regenerated denitration catalyst, the content of the metallic elements causing the denitration catalyst to be toxic is effectively controlled, and the denitration efficiency of the denitration catalyst is above 90%.

Description

technical field [0001] The invention relates to the technical field of catalyst regeneration, and more specifically relates to a pickling regeneration solution and a regeneration method for a denitration catalyst. Background technique [0002] my country is a country with coal as the main energy source, and nitrogen oxides emitted after coal combustion is one of the main pollutants in the atmosphere, which is extremely harmful to the environment. Therefore, my country has strictly controlled the emission of nitrogen oxides. [0003] Selective Catalytic Reduction (hereinafter referred to as SCR) denitrification technology has a remarkable effect on the removal of nitrogen oxides, and is currently the most widely used flue gas denitrification technology. In the entire SCR denitrification system, the denitrification catalyst is the core component and accounts for a relatively large proportion of equipment investment. However, the denitrification performance of the denitrificat...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): B01J38/60B01J38/62B01J23/78B01J23/94B01D53/90B01D53/56
Inventor 於承志
Owner TIANHE BAODING ENVIRONMENTAL ENG
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products