High temperature supercapacitor
A technology for supercapacitors and current collectors, which is applied in the direction of hybrid capacitor electrodes, hybrid capacitor electrolytes, hybrid capacitor collectors, etc., and can solve problems such as high-intensity vibrations
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example 1
[0042] Build the supercapacitor unit as described above. The two working electrode layers are formed from activated carbon. Each conductive layer is formed of metallic silver. An electrolyte impermeable smooth carbon layer separates each working electrode from its corresponding conductive layer. The inert matrix used is glass. Glass fibers are used as electrode separator material. The electrolyte used is an ionic liquid electrolyte composed of hexyltriethylammonium cation and bis(trifluoromethylsulfonyl)imide anion. Its voltammetric response was measured.
[0043] image 3 A graph showing the voltammetric response of the supercapacitor in the range of 4V at 220°C. As can be seen from this graph, the supercapacitor is stable at high temperature for many cycles and can operate reliably over a wide voltage range (4V). The test was arbitrarily terminated after 100 cycles.
example 2
[0045] The ionic liquid gel was formed by adding fumed silica gel (Sigma-Aldrich, product number S5130) to each ionic liquid. The ionic liquid used can be triethylsulfonium bis(trifluoromethylsulfonyl)imide, hexyltriethylammonium bis(trifluoromethylsulfonyl)imide (hexyltriethylammoniumbis(trifluoromethylsulfonyl)imide), or butyl Trimethylammonium bis(trifluoromethylsulfonyl)imide (butyltrimethylammonium bis(trifluoromethylsulfonyl)imide). The amount of fumed silica mechanically diffused into the ionic liquid was 7.5 weight percent of the total weight of the electrolyte phase. In some cases, the amount of fumed silica can be doubled and ferrocene (10 mM) can be added as a redox activity detection reagent.
[0046] Figure 4 It is shown that when silicon is not included, the amount of hydrophilic silicon nanoparticles (S5130) is 7.5 weight percent of the total weight of the electrolyte phase, and the amount of hydrophilic silicon nanoparticles (S5130) is 15% of the total weigh...
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