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Sodium sulfate and sodium chloride production process

A production process, sodium sulfate technology, applied in the direction of alkali metal chloride, alkali metal sulfite/sulfite, inorganic chemistry, etc., can solve the difficult to adapt to the national policy requirements of energy saving and emission reduction scientific development, shorten the service life of mines , affecting the quality of brine and other issues, to achieve the effect of extending the service life of the mine, strong adaptability of raw materials, and low production cost

Inactive Publication Date: 2015-02-04
CHINA LIGHT IND INT ENG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the disadvantage of the multi-effect evaporation mother liquor recovery method is that it needs to configure a large-capacity boiler and produce a large amount of pollutants such as carbon dioxide and sulfur dioxide. The disadvantage of the multi-effect evaporation mother liquor discharge method is that it requires a large-capacity boiler and produces A large amount of pollutants such as carbon dioxide and sulfur dioxide, and the consumption of raw brine is high, and the high-salt mother liquor is discharged into the mine. After the mother liquor is discharged into the mine, the amount of salt enriched will affect the quality of the brine and shorten the service life of the mine.
Therefore, the above two processes are difficult to adapt to the national policy requirements of scientific development of energy saving and emission reduction

Method used

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  • Sodium sulfate and sodium chloride production process

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Effect test

Embodiment 1

[0019] 1. Take 200m 3 Sodium sulfate and sodium chloride solution are raw material liquid (sodium sulfate 310g / l, sodium chloride 50g / l), above-mentioned raw material liquid and low temperature salt making mother liquor 176.17m 3 (sodium chloride 287g / l, sodium sulfate 68g / l) respectively after heat exchange with the condensed water obtained by high-temperature nitrate production and the mother liquor of high-temperature nitrate production, separate and obtain 62 tons of sodium sulfate after high-temperature mechanical compression evaporation at 130 ° C. High temperature nitric acid mother liquor 32.26m 3 (sodium chloride 310g / l, sodium sulfate 60g / l); wherein the raw material solution containing sodium sulfate and sodium chloride solution passes through the condensed water obtained by high-temperature nitrate production and the high-temperature nitrate production mother liquor after heat exchange, and the temperature is raised by 25°C To 130°C, the temperature of the condens...

Embodiment 2

[0023] 1. Take 200m 3 Sodium sulfate and sodium chloride solution are raw material liquid (sodium sulfate 260g / l, sodium chloride 100g / l), above-mentioned raw material liquid and low temperature salt making mother liquor 352.36m 3 (sodium chloride 287g / l, sodium sulfate 68g / l) respectively after heat exchange with the condensed water obtained by high-temperature nitrate production and the mother liquor of high-temperature nitrate production, separate and obtain 52 tons of sodium sulfate after high-temperature mechanical compression evaporation at 130 ° C. High temperature nitric acid mother liquor 64.52m 3 (sodium chloride 310g / l, sodium sulfate 60g / l); wherein the raw material solution containing sodium sulfate and sodium chloride solution passes through the condensed water obtained by high-temperature nitrate production and the high-temperature nitrate production mother liquor after heat exchange, and the temperature is raised by 25°C To 130°C, the temperature of the conden...

Embodiment 3

[0027] 1. Take 200m 3 Sodium sulfate and sodium chloride solution are raw material liquid (sodium sulfate 210g / l, sodium chloride 150g / l), above-mentioned raw material liquid and low temperature salt making mother liquor 528.54m 3 (sodium chloride 287g / l, sodium sulfate 68g / l) respectively after heat exchange with the condensed water obtained by high-temperature nitrate production and the mother liquor of high-temperature nitrate production, separate and obtain 52 tons of sodium sulfate after high-temperature mechanical compression evaporation at 130 ° C. High temperature nitric acid mother liquor 96.77m 3 (sodium chloride 310g / l, sodium sulfate 60g / l); wherein the raw material solution containing sodium sulfate and sodium chloride solution passes through the condensed water obtained by high-temperature nitrate production and the high-temperature nitrate production mother liquor after heat exchange, and the temperature is raised by 25°C To 130°C, the temperature of the conden...

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Abstract

A sodium sulfate and sodium chloride production process is as follows: a sodium sulfate and sodium chloride solution is taken as a raw material liquid, after heat transfer heating of condensation water and high temperature nitrate making mother liquor in high temperature nitrate making process, the high temperature nitrate making is performed by high temperature mechanical compression evaporation at 80-150 DEG C, solid sodium sulfate and the high temperature nitrate making mother liquor are obtained by separation; after heat transfer of the high temperature nitrate making mother liquor and the raw material liquid, low temperature mechanical compression evaporation is performed at 40-60 DEG C, then solid sodium chloride and low temperature salt making mother liquor are obtained by separation; and after heat transfer heating of the low temperature salt making mother liquor and the condensation water and the high temperature nitrate making mother liquor in the high temperature nitrate making process, the high temperature mechanical compression evaporation is performed circularly. The process has no discharge of waste liquid, and has the characteristics of strong adaptability of raw materials, low production cost, high product quality, and no three waste discharge, the normal production needs no boiler to supply steam, the comprehensive energy consumption is reduced, the service life of mines is prolonged, the pollution discharge is reduced, and the sodium sulfate and sodium chloride production process is more environmentally-friendly.

Description

technical field [0001] The invention belongs to the technical field of inorganic salt preparation, in particular to a production process of sodium sulfate and sodium chloride. Background technique [0002] Sodium sulfate and sodium chloride are generally used chemical raw materials. At present, there are two methods for producing solid sodium sulfate and sodium chloride from a solution containing sodium sulfate and sodium chloride, namely, the multiple-effect evaporation nitric acid mother liquor recovery method and Multi-effect evaporation nitric acid mother liquor discharge method. However, the disadvantage of the multi-effect evaporation mother liquor recovery method is that it needs to configure a large-capacity boiler and produce a large amount of pollutants such as carbon dioxide and sulfur dioxide. The disadvantage of the multi-effect evaporation mother liquor discharge method is that it requires a large-capacity boiler and produces A large amount of pollutants such ...

Claims

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Application Information

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IPC IPC(8): C01D3/04C01D5/00
Inventor 彭赛军
Owner CHINA LIGHT IND INT ENG CO LTD
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