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A kind of preparation method of titanium oxide-sepiolite-activated carbon composite carrier

A composite carrier, sepiolite technology, applied in catalyst carriers, chemical instruments and methods, chemical/physical processes, etc., to achieve the effect of high specific surface area

Active Publication Date: 2016-03-02
唐群
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the prior art, activated carbon, sepiolite or titanium dioxide are mostly used alone as catalyst supports, and there is no report on a support that combines the three materials together and has a specific pore structure and specific surface area.

Method used

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  • A kind of preparation method of titanium oxide-sepiolite-activated carbon composite carrier

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Get the wheat straw of 100 weight parts, through crushing, after pulverizing with superfine pulverizer and refinement with superfine pulverizer, obtain particle size and be the powder particle of 325 meshes;

[0018] Take 80 parts by weight of sepiolite, pulverize it with a pulverizer, and sieve it. Put the sieved powder particles in a muffle furnace, raise the temperature to 250° C. at a heating rate of 5° C. / min, keep it warm for 1 hour, and cool it down. After reaching room temperature, fully soak the calcined powder with HCl solution for 2 hours, then filter and wash to obtain activated modified sepiolite;

[0019] Take 50ml of butyl titanate, add 150ml of ethanol to it while stirring, and then add 10ml of HNO 3 and 10ml of distilled water, mixed and stirred for 2 hours to obtain a titanium dioxide sol, and the activated modified sepiolite obtained in the previous steps was added to the sol, stirred thoroughly for 1 hour, and then the mixture was baked in a muffle f...

Embodiment 2

[0021] Get 100 parts by weight of wheat straw, after crushing, pulverizing with a superfine pulverizer and refining with a superfine pulverizer, to obtain a particle size of 500 mesh powder particles;

[0022] Take 80 parts by weight of sepiolite, pulverize it with a pulverizer, and sieve it. Put the sieved powder particles in a muffle furnace, raise the temperature to 250° C. at a heating rate of 5° C. / min, keep it warm for 1 hour, and cool it down. After reaching room temperature, fully soak the calcined powder with HCl solution for 2 hours, then filter and wash to obtain activated modified sepiolite;

[0023] Take 50ml of butyl titanate, add 150ml of ethanol to it while stirring, and then add 10ml of HNO 3 and 10ml of distilled water, mixed and stirred for 2 hours to obtain a titanium dioxide sol, and the activated modified sepiolite obtained in the previous steps was added to the sol, stirred thoroughly for 1 hour, and then the mixture was baked in a muffle furnace at 500°...

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Abstract

The invention discloses a composite carrier comprising three components of activated carbon, sepiolite and titanium oxide. PEG-2000 is used as a pore-enlarging agent for the composite catalyst. Pore ​​structure and high specific surface area support material.

Description

technical field [0001] The invention relates to a preparation method of titanium oxide-sepiolite-activated carbon composite carrier. Background technique [0002] Supported catalyst is a conventional catalyst structure type in the prior art. Activated carbon is used as a catalyst carrier material because of its high specific surface area. The catalytically active components are supported on the surface of activated carbon by impregnation and other loading methods to form a supported catalyst. . Due to its special structure, sepiolite exhibits excellent adsorption, rheological and catalytic properties, and has received increasing attention from researchers in many fields, especially in the field of catalysis. Titanium dioxide has been developed as a catalyst carrier in recent years, and commonly used titanium dioxide carrier types such as P-25. [0003] In the prior art, activated carbon, sepiolite or titanium dioxide are mostly used alone as catalyst supports. So far, ther...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J32/00B01J21/18B01J35/10
Inventor 李程伟
Owner 唐群
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