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High temperature and high pressure resistant organic compound oil layer protection fluid and preparation method thereof

A kind of oil layer protection fluid and composite technology, which is applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve problems such as construction resistance, surface corrosion, pitting corrosion, corrosion, etc., and achieve the effect of reducing backflow

Active Publication Date: 2018-05-01
陈国伟
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In recent years, during the construction and operation of ordinary oil-water wells and gas wells, a large number of protective fluids with chlorides as weighting agents have been used in large quantities. Reduce the permeability of the bottom layer; second, it is easy to interact with formation water to form precipitated insoluble matter and reduce porosity; third, it is easy to corrode the relevant downhole casings and equipment, causing a large amount of surface corrosion and pitting corrosion on the surface, which affects the service life. Especially in some gas wells and gas testing operations, the protection fluid has seriously corroded the oil casing, and the protection fluid poured back into the formation during the well killing process.
In addition, protective fluids with conventional densities are likely to cause construction resistance during construction, especially for low-permeability, low-pressure, and low-abundance "three-low" oil and gas reservoirs. Protective fluids that do not match the formation will cause permanent damage to the formation. harm

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The high temperature and high pressure resistant organic composite oil layer protection fluid of the present invention is of the type: QZ-Ⅲ type, which is composed of polyacrylamide, oxidative crosslinking agent, inorganic coagulant accelerator, water and 98% ethanol; each group The parts by mass are: 3 parts of polyacrylamide, 2 parts of oxidative crosslinking agent, 2 parts of inorganic coagulant, 88 parts of water and 5 parts of 98% ethanol.

[0025] Its preparation method, the steps are as follows:

[0026] a. Dissolve 2 parts of oxidized cross-linking agent with 5 parts of 98% ethanol to make solution A;

[0027] b. Dissolve 3 parts of polyacrylamide in 88 parts of water at a temperature of 35°C and stir evenly;

[0028] c. Add solution A to the mixed solution prepared in step b, and stir at a constant temperature of 35°C for 1 hour;

[0029] d. Cool the mixed solution prepared in step c to 20°C, add 2 parts of inorganic coagulant, and stir for 30 minutes to obta...

Embodiment 2

[0031] The high temperature and high pressure resistant organic composite oil layer protection fluid of the present invention is composed of polyacrylamide, dicumyl peroxide, sodium nitrite, water and 98% ethanol; the mass parts of each component are: 6 parts of polyacrylamide , 5 parts of dicumyl peroxide, 8 parts of sodium nitrite, 63 parts of water and 18 parts of 98% ethanol.

[0032] The preparation method of the high-temperature and high-pressure resistant organic composite oil reservoir protection fluid of the present invention, the steps are as follows:

[0033] a, 5 parts of dicumyl peroxide are dissolved with 18 parts of 98% ethanol to make solution A;

[0034] b. Dissolve 6 parts of polyacrylamide in 63 parts of water at a temperature of 60°C and stir evenly;

[0035] c. Add solution A to the mixed solution prepared in step b, and stir at a constant temperature of 60°C for 5 hours;

[0036] d. Cool the mixed solution prepared in step c to 30°C, add 8 parts of sodi...

Embodiment 3

[0038] The high temperature and high pressure resistant organic composite oil reservoir protection fluid of the present invention is composed of polyacrylamide, hydrogen peroxide, sodium nitrite, water and 98% ethanol; the mass parts of each component are: 3 parts of polyacrylamide, 3 parts of hydrogen peroxide, 3 parts of sodium nitrite, 83 parts of water and 8 parts of 98% ethanol.

[0039] The preparation method of the high-temperature and high-pressure resistant organic composite oil reservoir protection fluid of the present invention, the steps are as follows:

[0040] a. Dissolve 3 parts of hydrogen peroxide with 8 parts of 98% ethanol to make solution A;

[0041] b. Dissolve 3 parts of polyacrylamide in 83 parts of water at a temperature of 35°C and stir evenly;

[0042] c. Add solution A to the mixed solution prepared in step b, and stir at a constant temperature of 35°C for 1 hour;

[0043] d. Cool the mixed solution prepared in step c to 25°C, add 3 parts of sodium...

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Abstract

The high temperature and high pressure resistant organic compound oil layer protection fluid and the preparation method thereof of the present invention relate to the technical field of oil field chemical industry, and are composed of 3 to 6 parts of polyacrylamide, 2 to 5 parts of oxidative crosslinking agent, and 2 parts of inorganic coagulant accelerator. ~8 parts, 63~88 parts of water and 5~18 parts of 98% ethanol. The preparation method is to dissolve polyacrylamide in water, then add ethanol solution of oxidative crosslinking agent, and stir at 35~60℃ for 1~ After 5 hours, finally cool the mixture to 20-30°C, add 2-8 parts of inorganic coagulant, and stir for 30 minutes to obtain the finished product. The high temperature and high pressure resistant organic composite oil layer protection fluid of the present invention has a density range of 1.05g / cm3 to 1.35g / cm3, a long action period of the inorganic anti-swelling component, a chloride ion content of less than 300mg / L, no heavy metal ions, With low viscosity and low fluid loss, good thermal stability.

Description

technical field [0001] The invention relates to the field of oilfield chemical technology, in particular to a high temperature and high pressure resistant organic composite oil layer protection fluid and a preparation method thereof. Background technique [0002] In the process of oil and water well construction, the correct selection of oil layer protection fluid can not only protect the formation, tubing, casing and downhole equipment from secondary damage or damage, but also prevent formation voids from being blocked, avoid downhole equipment from being corroded, and effectively prolong Formation and well life. In recent years, during the construction and operation of ordinary oil-water wells and gas wells, a large number of protective fluids with chlorides as weighting agents have been used in large quantities. Reduce the permeability of the bottom layer; second, it is easy to interact with formation water to form precipitated insoluble matter and reduce porosity; third...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/52C09K8/512C09K8/12C09K8/68
CPCC09K8/12C09K8/512C09K8/52C09K8/665C09K8/685C09K8/882C09K8/887C09K2208/12
Inventor 陈国伟
Owner 陈国伟