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A kind of mine reinforcement material

A technology for mines and hydrochloric acid, applied in the direction of organic chemistry, etc., can solve the problems of small diffusion radius and poisoning of slurry

Inactive Publication Date: 2017-01-04
NORTH CHINA UNIVERSITY OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Polyurethane grout swells and reacts with water, but it is easy to block channels in micro-cracked rock mass, resulting in a smaller diffusion radius of the grout
Urea-formaldehyde resin + acrylamide slurry is actually a mixture of urea-formaldehyde resin slurry and acrylamide. A 2-N methylene acrylamide material is used as an auxiliary material in the slurry. The monomer of this material has a large High toxicity. Although there is no report of water poisoning in China, there are reports of Japanese people being poisoned by grouting in relevant literature. This kind of grouting material has been banned by the government in Japan

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Embodiment 1: the preparation of formula I compound:

[0015] 5-Amino-2,4,6-tribromo-N,N'-bis(2,3-dihydroxypropyl)isophthalamide (15mmol) and aminotoluenesulfonic acid (TsOH) (0.6mmol) were added into 2,2-dimethoxypropane (30ml). The suspension mixture was stirred at ambient temperature for 48 hours and the ethanol formed was distilled off. The reaction mixture was evaporated in vacuo to give the compound of formula I as a white solid, 6.96 g, (R F =0.45 ethyl acetate), melting point 231-232°C.

[0016] 1 H-NMR (DMSO): 8.68-8.60 (m, 2H), 4.21-4.20 (m, 2H), 4.05 (t, 2H), 3.83-3.77 (m, 2H), 3.43-3.16 (m, 4H), 1.34(s, 6H), 1.26(s, 6H).

Embodiment 2

[0017] Embodiment 2: the preparation of composition:

[0018] Get ordinary Portland 425 cement 100g, tap water 100ml, p-toluenesulfonic acid 0.6g, mass percent is 98% phosphoric acid 0.8g, mass percent is 37% hydrochloric acid 1g, ethylene glycol 0.1g, and 2.5g formula I Compound, premix cement and additives to ensure uniform mixing. Add the compound of formula I into water for stirring and add it to the slurry mixer. Add the mixed powder (cement and additives) into the mixer, start stirring, stir slowly for 2 minutes, and stir rapidly for 2 minutes to obtain the composition.

Embodiment 3

[0019] Embodiment 3: the preparation of composition:

[0020] Get 100g of ordinary Portland 425 cement, 100ml of tap water, 0.8g of p-toluenesulfonic acid, 1.2g of phosphoric acid with a mass percentage of 98%, 0.8g of hydrochloric acid with a mass percentage of 37%, 0.1g of ethylene glycol, and 2.9g of the formula I compound, premix cement and additives to ensure uniform mixing. Add the compound of formula I into water for stirring and add it to the slurry mixer. Add the mixed powder (cement and additives) into the mixer, start stirring, stir slowly for 5 minutes, and stir rapidly for 2 minutes to obtain the composition.

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PUM

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Abstract

The invention relates to a material for reinforcing a mine. The material comprises a component A, a component B and a composition of cement, wherein the component A is a compound in a formula I; the component B is an assistant; cement is ordinary portland cement; the assistant is prepared from the following raw materials in parts by weight: 0.6-1.0 part of p-toluenesulfonic acid, 0.8-1.3 parts of phosphoric acid, 0.5-1.0 part of hydrochloric acid and 0.1 part of ethylene glycol; the mass percentage of the hydrochloric acid is 37%; the mass percentage of the phosphoric acid is 98%; the component A and the component B are mixed at the mass ratio of 1 to 1 when the material is used; and the portland cement is 100 parts by weight. The composition disclosed by the invention has good effects in seepage rate, shrinkage rate and hardness.

Description

technical field [0001] The invention relates to an engineering material, in particular to a material for mine reinforcement. Background technique [0002] Coal always accounts for about 70% of my country's primary energy production and consumption structure. With the increase of coal mining depth, the coal is broken and softened. In the process of mine mining, the accidents of sidewalls and roof fall continue to increase, which has seriously affected the mining of the working face. Therefore, it is one of the problems that must be solved in the coal mining process to ensure the stability of the coal rock mass, prevent the roof caving of the working face, and realize stable and high yield and safe production. Coal rock mass grouting reinforcement material is an effective means to solve this problem. It can consolidate the broken coal rock mass with developed cracks into a coal rock mass with better integrity, and can effectively prevent the occurrence of roof caving acciden...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07C237/46C04B28/04C04B24/12
Inventor 宋志飞赵法亮田波孙世国冯少杰
Owner NORTH CHINA UNIVERSITY OF TECHNOLOGY