Preparation method of polymethyl methacrylate with narrow molecular weight distribution
A technology of polymethyl methacrylate and methyl methacrylate, which is applied in the field of polymer material preparation, can solve the problems of complex preparation process, harsh polymerization conditions, and long polymerization cycle, and achieve high monomer conversion rate and high reaction rate Fast and simple preparation method
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[0013] The present invention provides a method for preparing polymethyl methacrylate with narrow molecular weight distribution, which adopts solution polymerization, and the steps and conditions are as follows:
[0014] Put methyl methacrylate, solvent and initiator into the reaction vessel, stir well until the mixture is uniform, evacuate the air in the reaction vessel with nitrogen, and react at 90-180°C for 60-180 minutes, preferably at 100- React at 130°C for 120-150 minutes, and separate the polymer by sedimentation, preferably at room temperature for 12-20 hours, and then dry under vacuum to obtain polymethyl methacrylate with narrow molecular weight distribution. The sedimentation method of the present invention is a commonly used technical method in the field, and there is no special limitation.
[0015] According to the present invention, dialkylimidazole ionic liquids are used as solvents. Because ionic liquids are a kind of special solvents with relatively high viscosity...
Example Embodiment
[0026] Example 1
[0027] Take 50 parts of the monomer methyl methacrylate, 50 parts of the solvent 1-methyl-3-butylimidazole hexafluorophosphate, and 0.05 parts of the initiator di-tert-butyl peroxide into the reactor, fully stir until the mixture is uniform, The air in the reactor was evacuated with nitrogen, sealed and reacted at 90°C for 150 minutes. After the reaction, the polymer was precipitated by sedimentation, placed at room temperature for 12 hours, and then dried at 60°C for 48 hours under vacuum to obtain Molecular weight distribution polymethyl methacrylate.
[0028] The number average molecular weight of the polymethyl methacrylate obtained in Example 1 is 907850, and the molecular weight distribution: PDI=1.3.
Example Embodiment
[0029] Example 2
[0030] Take 30 parts of the monomer methyl methacrylate, 70 parts of the solvent 1-methyl-3-ethylimidazole tetrafluoroborate, and 0.5 part of the initiator di-tert-butyl peroxide into the reactor, and fully stir until the mixture is uniform , The air in the reactor was evacuated with nitrogen, sealed and reacted at 100°C for 180 minutes, after the reaction, the polymer was precipitated by sedimentation, placed at room temperature for 12 hours, and then dried at 60°C under vacuum for 48 hours to obtain Narrow molecular weight distribution polymethyl methacrylate.
[0031] The number average molecular weight of the polymethyl methacrylate obtained in Example 2 was 709158, and the molecular weight distribution: PDI=1.27.
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