Working liquid for producing hydrogen peroxide by anthraquinone method
A technology of working fluid and hydrogen peroxide, applied in peroxide/peroxy hydrate/peroxyacid/superoxide/ozonide, chemical instruments and methods, inorganic chemistry, etc., can solve the problem of heavy workload, high solubility, Reduce the degradation rate of anthraquinone and other problems to achieve the effect of increasing production capacity, reducing production cost and improving solubility
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Embodiment 1
[0017] Using No. 200 mineral spirits and trioctyl phosphate = 70:30 (volume ratio) as the working fluid medium, the solubility of 2-ethylanthraquinone is 165 g / L. The hydrogenation temperature is 55°C, the hydrogenation pressure is 0.25 MPa, and the space velocity is 4h -1 , The ratio of hydrogen to liquid is 60:1. The oxidation temperature is 50°C, and the oxidation pressure is 0.15MPa. Hydrogen efficiency is 10.89 g / L
Embodiment 2
[0019] Using No. 200 mineral spirits and trioctyl phosphate = 50:50 (volume ratio) as the working fluid medium, the solubility of 2-ethylanthraquinone is 146 g / L. The hydrogenation temperature is 55°C, the hydrogenation pressure is 0.30 MPa, and the space velocity is 5h -1 , The ratio of hydrogen to liquid is 50:1. The oxidation temperature is 55°C, and the oxidation pressure is 0.20MPa. The hydrogen efficiency is 8.64 g / L.
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