Method for producing propylene by employing extracted C4
A technology for extracting C4 and propylene, which is applied in the direction of organic chemistry and metathesis reaction to produce hydrocarbons, can solve the problems of short catalyst life and low butene conversion rate, so as to improve the service life, reduce the influence of impurities on the catalyst, and improve active effect
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Embodiment 1
[0042] Using the extracted C42 in Table 1 as the raw material, the first C4 material is obtained after the C4 raw material is removed from heavy components such as the polymerization inhibitor in the raw material through the de-weight tower, and the dimethyl ether therein is removed through the de-light tower The second C4 material is obtained, and then the butadiene and isobutene in the raw material are removed through the deisobutanizer to obtain the third C4 material. The mixed material is formed after the stream and the circulating C4 are mixed, and the mixed material is removed after being treated by an impurity processor. Impurities in the raw materials, including water, alcohol, ether and other polar substances, the pretreated materials enter the disproportionation reactor for reaction, and the reaction products propylene, pentene and unreacted carbon tetraolefins are obtained, and the reaction products pass through the deethylene tower , to obtain ethylene from the top ...
Embodiment 2~6
[0046] React by each condition and step of embodiment 1, just change different operating parameters, its disproportionation catalyst and the component of sorbent are shown in Table 2, disproportionation reaction conditions and reaction result are listed in Table 3, light removal tower and weight removal tower The operating conditions of the isobutanizer are shown in Table 4, the operating conditions of the deisobutanizer are shown in Table 5, and the operating conditions of the deethylene tower and the depropylene tower are shown in Table 6.
[0047] Table 2
[0048]
[0049] table 3
[0050]
[0051] Table 4
[0052]
[0053] table 5
[0054]
[0055] Table 6
[0056]
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