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Film prepared from air-permeable thermoplastic elastomer resin composition

A thermoplastic elastomer and composition technology, which is applied in the field of gas permeable films, can solve the problems of hard hand feeling, poor mechanical properties of products, research on the way of stretching thermoplastic elastomers into pores, etc., and achieves excellent hydrostatic pressure resistance. , the effect of excellent air permeability

Active Publication Date: 2015-05-06
FOSHAN KING WONDER HI TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the design of these pore-forming material formulations mainly focuses on the blending research of olefin materials, olefin materials and various thermoplastic elastomers, and various fillers, oils and various pore-forming agents. However, there is no in-depth study on the stretching and pore-forming methods of thermoplastic elastomers, which limits the application of thermoplastic elastomers. Industry application
The current olefin-based products are hard to the touch, have a sound, and cannot be used in daily life, especially personal products, such as clothing, disposable products, etc.; from the perspective of processing methods, the current hair The bubble-forming method is uneven, the electrospinning investment is very expensive and the mechanical properties of the product are poor, and the solvent is polluted; the solution film-forming method is very easy to produce large changes with the change of the environment and there is a huge environmental problem. Pollution; In the case of limited cost, the method of punching holes cannot be used to make films with micron-sized pores, especially those with a pore size below 10 μm. It needs to cooperate with various precision instruments or etching methods, which will have a great impact on efficiency and cost. universal
The non-porous thermoplastic elastomer can only selectively permeate gas, and cannot achieve real air permeation, which can easily cause the illusion of stuffiness for end customers
All of these make the stretching of thermoplastic elastomers from production to end use form various technical obstacles in post-processing into finished products, which cannot be produced on a large scale, and consumers cannot experience the comfort of returning to nature.

Method used

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  • Film prepared from air-permeable thermoplastic elastomer resin composition
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  • Film prepared from air-permeable thermoplastic elastomer resin composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1 10

[0045] As shown in table 1, the mixture after the formula metering of embodiment one to embodiment ten, adopts thermal analysis instrument DSC to measure the melting point of this mixture, directly drops into single-layer co-extruded melt-molded matte film (see figure 1 ), the processing temperature is 160°C-290°C, after the stretching process, edge trimming, and winding, the finished product of 15μm matte film is finally prepared. The specific performance test is shown in Table 4 under the condition that the ratio is 1:4 and the stretching temperature is 10°C higher than the softening point. Each example shows different melting points. Among them, the melting points of Examples 1 to 6 increase gradually with the addition of inorganic powder, the elastic modulus also gradually increases, the toughness decreases, and the porosity also increases. Air permeability and sound absorption The capacity is also gradually increased, but the water pressure gradually decreases in Example ...

Embodiment 11 13

[0047] As shown in Table 2, the mixture measured in the formulas of Examples 11 to 13 was measured by a thermal analysis instrument DSC to measure the melting point of the mixture, and the processing temperature was 160°C-290°C to granulate, and the film-making speed was 70m / min, using the softening point uniaxial stretching process, the stretching ratio is 1:4, and the stretching temperature is 10°C higher than the softening point. The specific performance tests are shown in Table 2. , the processing temperature is 190°C-230°C, after the stretching process, trimming, and winding, it is finally prepared into a finished 20μm matte film with a film-making speed of 70m / min. Then carry out the specific performance test as shown in Table 5, and compare with Example 1, the modulus of elasticity decreases, the melting point also decreases, and the porosity decreases, and the increase in the proportion of recycled materials decreases more, mainly because The molecular weight of recyc...

Embodiment 14 17

[0049] As shown in table 1, adopt the mixture after the formula metering of embodiment three, adopt thermal analysis instrument DSC to measure the melting point of this mixture, carry out granulation first, then embodiment 14 drops into double-layer co-extrusion melt forming film (such as figure 2 ), embodiment 15 to embodiment 17 drop into single-layer co-extruded melt forming film (such as figure 1 ), the processing temperature is 160°C-290°C, through the uniaxial stretching process, trimming, and winding, the final embodiment 14 is prepared into a 15 μm colorless matte film product, the stretching ratio is 1:4, and the stretching ratio is 1:4. Under the condition that the elongation temperature is 10°C higher than the softening point, colorless matte films of 5 μm, 10 μm, and 20 μm were produced in Example 15 and Example 17, and the film-making speed was 70 m / min. Then carry out the above specific performance test as shown in Table 5, by comparison, air permeability, poros...

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PUM

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Abstract

The invention provides an air-permeable thermoplastic elastomer resin composition and a film prepared from the composition. The air-permeable thermoplastic elastomer resin composition comprises the following components: 30%-85% of a polar thermoplastic elastomer resin material, 15-70% of an inorganic powder material having the particle diameter being less than 50mu m and 0-3% of a dispersant, wherein the dispersant is an organic molecule having groups which have affinity with the polar thermoplastic elastomer. The polar thermoplastic elastomer film, which is provided with micropores having pore diameter being less than 50mu m and the porosity being not greater than 95% and has the advantages of good air permeability, flexible and smooth hand feeling, sound absorption and hydrostatic pressure resistance, is prepared by carrying out melt extrusion on the composition disclosed by the invention and then stretching.

Description

technical field [0001] The present invention relates to a film prepared from a breathable thermoplastic elastomer composition; more specifically, the present invention relates to a gas-permeable film prepared from a thermoplastic elastomer resin composition by melting and plasticizing to form a film and stretching to form holes. permeable film. Background technique [0002] Because the pore forming of materials has a very wide range of applications in various fields, in recent years, the research focus at home and abroad has focused on the pore forming technology, the formula design of various raw material resins, and various molding modification processing methods to finally achieve the purpose of pore forming. At present, the design of these pore-forming material formulations mainly focuses on the blending research of olefin materials, olefin materials and various thermoplastic elastomers, and various fillers, oils and various pore-forming agents. However, there is no in-...

Claims

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Application Information

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IPC IPC(8): C08L67/02C08L63/00C08L61/20C08L83/04C08K3/26C08K3/22C08K5/10
Inventor 林裕卫吴耀根
Owner FOSHAN KING WONDER HI TECH CO LTD