Low energy consumption hydrocracking method for producing high-quality chemical industry raw material

A technology of hydrocracking and chemical raw materials, which is applied in the fields of hydrotreating process, hydrocarbon oil cracking, petroleum industry, etc. It can solve the problems of unreasonable use of hydrocracking reaction heat, complicated process flow, and API degree drop, and achieve reduction Project investment and operating energy consumption, improving product quality, and maintaining selectivity

Active Publication Date: 2015-05-13
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] Since the 1990s, the crude oil processed by the world's oil refining enterprises has become significantly heavier, the sulfur and heavy metal content in crude oil has increased year by year, and the API degree has decreased; the environmental protection regulations promulgated by governments of various countries have become increasingly stringent, and the requirements for clean production processes and clean fuel production have become increasingly stringent. It is becoming more and more urgent; the growth rate of diesel demand in the refined oil market is much higher than that of gasoline, and the demand growth of aromatics and ethylene raw materials can no longer be met only by the increase of crude oil processing volume.

Method used

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  • Low energy consumption hydrocracking method for producing high-quality chemical industry raw material

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Embodiment 1~3

[0031] use figure 1 process shown. Using VGO as the raw material oil, the catalyst system of FF-46 hydrocracking pretreatment catalyst and hydrocracking catalyst Ⅰ / hydrocracking catalyst Ⅱ in different volume ratios was selected. Catalyst Ⅰ and catalyst Ⅱ are both supported by amorphous silica-alumina and modified Y molecular sieve. The volume ratios of hydrocracking catalyst I / hydrocracking catalyst II in Examples 1-3 are 2:1, 1:1 and 1:2, respectively.

[0032] At a total reaction pressure of 15.7MPa, the volume ratio of hydrogen to oil in the refining section and the cracking section is 900:1 and 1200:1 respectively, and the volume space velocity of the refining section and the cracking section are 1.0h -1 and 1.5h -1 , control the nitrogen content of refined oil to 5-8 μg×g -1 , a process test with a conversion rate of about 75wt% at >350°C was carried out, in which the temperature difference between the beds of hydrocracking catalyst I and hydrocracking catalyst II wa...

Embodiment 4

[0046] According to the complete set of hydrogenation technology of the present invention, newly build a set of 2 million tons / year hydrocracking unit, carry out economic calculation and can obtain following conclusion:

[0047] (1) Specific comparison results with conventional hydrocracking unit project investment:

[0048] 1. The investment of high-pressure heat exchanger was reduced by 4.9 million yuan;

[0049] 2. The investment in reaction feed heating furnace was reduced by 9.24 million yuan;

[0050] 3. The investment of thermal high-separation air-air cooler was reduced by 8.2 million yuan;

[0051] 4. The investment in circulating hydrogen compressor is reduced by 500,000 yuan;

[0052] The total investment in installation projects decreased by 22.84 million yuan, a decrease of 4.56%.

[0053] (2) Compared with the fuel consumption of conventional hydrocracking units, the results are as follows:

[0054] 1. The fuel consumption of the reaction feed heating furnace...

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Abstract

The present invention discloses a low energy consumption hydrocracking method for producing a high-quality chemical industry raw material. According to the method, a raw material oil and hydrogen gas are subjected to heat exchange two times, and then sequentially pass through a hydrorefining reaction zone and a hydrocracking reaction zone, wherein the hydrocracking reaction zone comprises at least two hydrocracking catalysts, the upstream is filled with a catalyst I, the downstream is filled with a catalyst II, the catalyst I contains 30-70 wt% of a modified Y molecular sieve, the catalyst II contains 15-50 wt% of the modified Y molecular sieve, and the modified Y molecular sieve content in the catalyst I is 10-30% higher than the modified Y molecular sieve content in the catalyst II. According to the method of the present invention, the high temperature high pressure countercurrent heat transfer technology and the hydrocracking catalyst grading technology are organically combined, and the hydrocracking reaction heat is comprehensively utilized, such that the characteristics of the two different types of the hydrocracking catalysts are completely provided, and the catalyst selectivity is maintained while the target product quality is improved, and the project investment and the operating energy consumption are reduced.

Description

technical field [0001] The invention relates to a hydrocracking method, in particular to a hydrocracking method which simultaneously uses different types of hydrocracking catalysts to improve the quality of some products and integrates a normal operation non-open flame reaction heating furnace. Background technique [0002] Since the 1990s, the crude oil processed by the world's oil refining enterprises has become significantly heavier, the sulfur and heavy metal content in crude oil has increased year by year, and the API degree has decreased; the environmental protection regulations promulgated by governments of various countries have become increasingly stringent, and the requirements for clean production processes and clean fuel production have become increasingly stringent. It is becoming more and more urgent; the growth rate of diesel demand in the refined oil market is much higher than that of gasoline, and the demand growth of aromatics and ethylene raw materials can ...

Claims

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Application Information

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IPC IPC(8): C10G65/12C10G47/16
CPCC10G47/20C10G67/02
Inventor 彭冲曾榕辉王仲义崔哲黄新露孙士可
Owner CHINA PETROLEUM & CHEM CORP
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