Spray-free thermoplastic resin composition with special aesthetic effect and its preparation method and application

Abstract

The invention discloses a spraying-free thermoplastic resin composition with special aesthetic effect and a preparation method and application thereof. The composition comprises the following components: 70-98 wt% of thermoplastic resin, 1-25 wt% of polymer coated powder microspheres with special effect, 0-10 wt% of a compatibilizer, 0.1-1 wt% of an antioxidant and 0.1-0.5 wt% of a processing aid. The powder with special effect coats by an aqueous polymer dispersion liquid to form microspheres which are then dispersed into thermoplastic resin, so as to significantly improve the compatibility of the powder with special effect and thermoplastic resin, and eliminate the flow mark formed on the surface of products in the extrusion or injection molding process and reduce the weld line. The prepared spraying-free thermoplastic resin composition has aesthetic effects of obvious metal texture and pearly flashing, and greatly improves the scope of market application of spraying-free materials.

Description

technical field [0001] The invention belongs to the field of polymer materials, and in particular relates to a spray-free thermoplastic resin composition with special aesthetic effects and its preparation method and application. Background technique [0002] As people pay more and more attention to environmental issues, spray-free special effect material products are gradually showing their competitiveness. Spray-free aesthetic resins can replicate the bright and colorful hues produced by spray paint, as well as pearlescent, flashing effects, metallic luster and Texture and other special effects, so as to meet diversified and differentiated customer needs, and can truly achieve energy saving and emission reduction in the production process, and can be widely used in handicrafts, toys, home appliances, automobiles, electronic products, sporting goods and office supplies and other fields . [0003] At present, the more common preparation method of spray-free resin is to add m...

AI Technical Summary

Problems solved by technology

By dispersing the special effect powder into the matrix resin, the special effect powder is connected to each other to form a continuous special effect film, which covers the base material and presents a special effect texture, although the special effect powder is directly added to the resin base. , can achieve a special glossy effect, but the compatibility between the matrix resin and the special effect powder is poor. Under the strong pressure and strong shear conditions of extrusion or injection molding, it is difficult for the special effect powder and the matrix resin material to achieve the same fluidity, especially It is a product with a complex structure. The special effect powder oriented along the flow direction occurs and the melt flow turns, the flow velocity is unstable, and the melt merges, etc., causing the special effect powder to be unevenly distributed in the melt and easy to form on the surface of the product. Defects such as flow marks and weld lines seriously prevent and limit the market promotion and application of this type of spray-free material

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