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A kind of antistatic ABS composite material and preparation method thereof

A composite material and antistatic technology, which is applied in the field of composite materials, can solve the problems of limitations and inability to fully utilize antistatic agents, and achieve the effect of uniform distribution and good antistatic effect

Active Publication Date: 2017-11-03
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The method of use is mainly to realize the dispersion of the antistatic agent in the ABS matrix through the twin-screw extrusion granulation method, but the twin-screw extrusion granulation method is a physical blending method, so the dispersion of the antistatic agent in the ABS matrix The effect is limited to a certain extent, so that the effect of the antistatic agent cannot be fully exerted

Method used

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  • A kind of antistatic ABS composite material and preparation method thereof
  • A kind of antistatic ABS composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] (1) 150 parts of acrylonitrile, 400 parts of α-methylstyrene, 10 parts of hydroxybutyl vinyl ether and 10 parts of initiator azobisisobutyronitrile, 1000 parts of deionized water, 250 parts Parts of emulsifier nonylphenol polyoxyethylene ether was added to Reactor 1, and under continuous stirring and nitrogen gas flow, the temperature of the system was raised to 70°C and reacted for 4 hours to obtain Latex 1;

[0027] (2) 400 parts of butadiene, 30 parts of vinyl acetate and 10 parts of initiator benzoyl peroxide, 1000 parts of deionized water, 150 parts of emulsifier nonylphenol polyoxyethylene ether are added to In the reactor 2, under the condition of continuous stirring and continuous feeding of nitrogen gas, the temperature of the system was raised to 70° C., and the reaction was carried out for 4 hours to obtain the latex 2 .

[0028] (3) After latex 1 and latex 2 are mixed, they are added to reactor 3, and 10 parts of initiator diisopropyl azodicarboxylate is add...

Embodiment 2

[0030] (1) 200 parts of acrylonitrile, 500 parts of α-methylstyrene, 20 parts of hydroxybutyl vinyl ether and 5 parts of initiator azobisisobutyronitrile, 1500 parts of deionized water, 300 parts Parts of emulsifier sodium dodecylbenzene sulfonate was added to reactor 1, under the condition of continuous stirring and continuous feeding of nitrogen gas, the temperature of the system was raised to 80°C, reacted for 3 hours, and latex 1 was obtained;

[0031] (2) 200 parts of butadiene, 20 parts of vinyl acetate and 5 parts of initiator azobisisobutyronitrile, 1500 parts of deionized water, 250 parts of emulsifier sodium dodecylbenzenesulfonate Put it into the reactor 2, raise the temperature of the system to 80° C. under the condition of continuous stirring and continuous feeding of nitrogen, and react for 3 hours to obtain the latex 2.

[0032] (3) After mixing Latex 1 and Latex 2, add them to Reactor 3, add 5 parts of initiator azobisisobutyronitrile, and heat up to 80°C for p...

Embodiment 3

[0034] (1) 250 parts of acrylonitrile, 400 parts of α-methylstyrene, 30 parts of hydroxybutyl vinyl ether and 5 parts of initiator azobisisobutyronitrile, 2000 parts of deionized water, 350 parts Parts of emulsifier hexadecyltrimethylammonium chloride was added to reactor 1, under continuous stirring and continuous feeding of nitrogen gas, the temperature of the system was raised to 90°C, reacted for 2 hours, and latex 1 was obtained;

[0035] (2) With 300 parts of butadiene, 10 parts of vinyl acetate and 5 parts of initiator benzoyl peroxide, 1200 parts of deionized water, 200 parts of emulsifier hexadecyl trimethyl chloride Ammonium was added to reactor 2, and the temperature of the system was raised to 90° C. under continuous stirring and nitrogen gas flow, and reacted for 2 hours to obtain latex 2.

[0036](3) After latex 1 and latex 2 are mixed, join in the reactor 3, add the initiator benzoyl peroxide of 10 parts, under continuous agitation and continuously feed nitrogen...

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Abstract

A novel antistatic ABS composite material provided by the invention consists of 150 to 250 parts of acrylonitrile, 200 to 400 parts of butadiene, 400 to 600 parts of α-methylstyrene, and 10 to 30 parts of hydroxybutyrate It is prepared from base vinyl ether, 10-30 parts of vinyl acetate and 15-30 parts of initiator. The invention also discloses a method for preparing the composite material by adopting a novel monomer with an antistatic effect. The method mainly includes: firstly preparing two different latexes respectively, and then mixing the two latexes for copolymerization. After the polymerization reaction is completed, , purifying and drying the obtained antistatic ABS composite material to finally prepare the composite material, which has good antistatic performance.

Description

technical field [0001] The invention belongs to the technical field of composite materials, and in particular relates to an antistatic ABS composite material and a preparation method. Background technique [0002] Acrylonitrile-butadiene-styrene (ABS) material is an insulating material. In some specific use environments, it is easy to accumulate static electricity and cause danger. In order to reduce or eliminate the harm caused by the accumulated charge to the ABS material during use, antistatic agents are often added to the ABS material to divert or eliminate the accumulated harmful charge in a timely manner. The antistatic agent reduces the resistivity of the ABS material by forming an ordered arrangement on the surface of the ABS material, or forming a charge-conducting network structure in the polymer matrix. [0003] Chen Erfan and others used a twin-screw extruder to prepare antistatic ABS alloy materials by extruding and granulating dimethylaminoethyl methacrylate b...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F212/12C08F236/10C08F236/06C08F220/44C08F216/14C08F218/08C08F2/24
Inventor 杨桂生田恐虎
Owner HEFEI GENIUS NEW MATERIALS
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