Method for coating epoxy resin layer on surface of microsphere with critical carbon dioxide
A technology coated with epoxy resin and carbon dioxide, which is applied in the field of material science, can solve the problems of glass plate spacing deviation, blurry image, easy sliding, etc., and achieve the effect of reducing spacing deviation, improving quality, and simple method
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Embodiment 1
[0015] Embodiment 1 of the present invention: the method that supercritical carbon dioxide wraps epoxy resin layer on PS microsphere surface,
[0016] (1) Surface treatment: Weigh 10 g of 10 μm PS microspheres and 50 ml of sulfuric acid solution with a mass percentage of 50%, add sulfuric acid and PS microspheres into a three-necked flask at the same time and stir with a stirrer for 30 minutes. Repeatedly wash 5 times with distilled water in ultrasonic until the sulfuric acid is completely washed, and finally filter and dry to obtain PS microspheres with surface sulfonation treatment;
[0017] (2) Preparation of epoxy resin: take 25g of E20 epoxy resin and dissolve it completely in butanone, then add 1g of dicyandiamide and 0.1g of dimethylimidazole and stir evenly;
[0018] (3) Surface coated with resin: add the surface sulfonated PS microspheres into the prepared solid epoxy resin solution, in a three-necked bottle, under the condition of 200r / min, ultrasonic treatment while...
Embodiment 2
[0021] Embodiment 2 of the present invention: the method that supercritical carbon dioxide coats epoxy resin layer on the surface of silica microspheres,
[0022] (1) Surface treatment: weigh 10 g of 8 μm silica microspheres and 50 ml of 50% sulfuric acid solution by mass percentage, add sulfuric acid and silica microspheres into a three-necked flask at the same time and stir with a stirrer for 30 minutes , after the stirring is completed, use distilled water to wash repeatedly in ultrasonic waves for 5 times until the sulfuric acid is completely washed, and finally filter and dry to obtain surface sulfonated silica microspheres;
[0023] (2) Configure epoxy resin: take 12.5g E44 epoxy resin and completely dissolve it in methyl ethyl ketone, then add cationic hexafluoroantimonate and stir evenly;
[0024] (3) Surface coating resin: add the surface sulfonated silica microspheres to the prepared solid epoxy resin solution, in a three-necked bottle, under the condition of 200r / mi...
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