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Method for coating epoxy resin layer on surface of microsphere with critical carbon dioxide

A technology coated with epoxy resin and carbon dioxide, which is applied in the field of material science, can solve the problems of glass plate spacing deviation, blurry image, easy sliding, etc., and achieve the effect of reducing spacing deviation, improving quality, and simple method

Active Publication Date: 2018-03-27
GUIZHOU MATERIAL IND TECH INSTITUE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The surface of the currently used PS balls has not been treated. A layer of PS microspheres has a smooth surface. When the microspheres are applied between the glass plates, they are easy to slide under the action of external force. After the microspheres slide and accumulate, the deviation of the distance between the glass plates will be caused.
Once there is a deviation in the distance between the two plates, the direction of the liquid crystal molecules is not reversed according to the original electrical performance, which will cause a series of image distortions such as blurred screens.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Embodiment 1 of the present invention: the method that supercritical carbon dioxide wraps epoxy resin layer on PS microsphere surface,

[0016] (1) Surface treatment: Weigh 10 g of 10 μm PS microspheres and 50 ml of sulfuric acid solution with a mass percentage of 50%, add sulfuric acid and PS microspheres into a three-necked flask at the same time and stir with a stirrer for 30 minutes. Repeatedly wash 5 times with distilled water in ultrasonic until the sulfuric acid is completely washed, and finally filter and dry to obtain PS microspheres with surface sulfonation treatment;

[0017] (2) Preparation of epoxy resin: take 25g of E20 epoxy resin and dissolve it completely in butanone, then add 1g of dicyandiamide and 0.1g of dimethylimidazole and stir evenly;

[0018] (3) Surface coated with resin: add the surface sulfonated PS microspheres into the prepared solid epoxy resin solution, in a three-necked bottle, under the condition of 200r / min, ultrasonic treatment while...

Embodiment 2

[0021] Embodiment 2 of the present invention: the method that supercritical carbon dioxide coats epoxy resin layer on the surface of silica microspheres,

[0022] (1) Surface treatment: weigh 10 g of 8 μm silica microspheres and 50 ml of 50% sulfuric acid solution by mass percentage, add sulfuric acid and silica microspheres into a three-necked flask at the same time and stir with a stirrer for 30 minutes , after the stirring is completed, use distilled water to wash repeatedly in ultrasonic waves for 5 times until the sulfuric acid is completely washed, and finally filter and dry to obtain surface sulfonated silica microspheres;

[0023] (2) Configure epoxy resin: take 12.5g E44 epoxy resin and completely dissolve it in methyl ethyl ketone, then add cationic hexafluoroantimonate and stir evenly;

[0024] (3) Surface coating resin: add the surface sulfonated silica microspheres to the prepared solid epoxy resin solution, in a three-necked bottle, under the condition of 200r / mi...

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Abstract

The invention provides a method for coating the surfaces of microspheres with an epoxy resin layer by virtue of supercritical carbon dioxide. According to the method, based on the characteristics of supercritical carbon dioxide which is an all-purpose solvent, the surfaces of PS microspheres are coated with an epoxy resin layer; the, a solvent in epoxy resin is extracted out by using supercritical carbon dioxide so as to form an adhesive layer on the surfaces of the PS microspheres; moreover, when gas is released, the microspheres are suspended and roll continuously in a gas flow so that the epoxy resin uniformly coats the surfaces of the microspheres; after gas is completely released, the microspheres are collected to obtain microspheres well coated with the epoxy resin; after being treated, the PS microspheres have smooth surfaces and fixed particle diameter just like original spheres; when an edge sealing adhesive is cured, the microspheres are synchronously cured and adhered to a glass plate or PET, thus achieving the aim of fixing the microspheres; the phenomenon of image instability because of spacing deviation caused when an external force acts between two plates of an LCD can be reduced and the quality of the LCD can be improved. The method is simple, easy to implement, low in cost and good in use effect.

Description

technical field [0001] The invention relates to the technical field of material science, in particular to a method for coating an epoxy resin layer on the surface of microspheres with critical carbon dioxide. Background technique [0002] When making existing liquid crystal displays, liquid crystal is injected between two glass plates or PET plates coated with ITO (indium tin oxide), and its surroundings are coated with PET glue. The two plates are bonded and sprayed with PS microspheres of a certain particle size in the middle as a spacer. Materials, especially PET for flexible liquid crystal displays, are also made by the same method, and the microspheres between them are easy to slide and accumulate. The distance between the two plates must be consistent during injection. Usually PS microspheres with the same particle size are used to control the distance between the two plates when preparing liquid crystal displays. The surface of the currently used PS balls has not be...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J7/04C08J7/14C08L25/06C08L63/00
CPCY02P20/54
Inventor 罗恒田井速何文涛姚勇张敏敏张凯
Owner GUIZHOU MATERIAL IND TECH INSTITUE
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