Secondary lithium-ion battery with aluminum, nickel, copper and graphite cloth as current collector

A graphite cloth and current collector technology, applied in the field of secondary lithium ion batteries, can solve the problems of huge differences in the electron conduction rate, electron density and uniformity of active materials, and huge differences in electron conduction rate, electron density and uniformity, etc. High-value, capacity-enhancing effects

Inactive Publication Date: 2018-04-06
CHINA FIRST AUTOMOBILE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the traditional positive and negative current collector materials of secondary lithium ion batteries are aluminum foil and copper foil. The main disadvantage is that the positive and negative active materials can only be distributed on the surface of the current collector. The electron conduction rate and electron density and uniformity of the active material vary greatly
In order to improve this situation, the new current collector materials currently proposed mainly include foam metal, burr metal belt, metal mesh and other materials from the perspective of increasing the contact area with the active material; the problems existing in the traditional current collector materials: that is, positive and negative active materials It can only be distributed on the surface of the current collector, and the electron conduction rate, electron density and uniformity of the active material close to the current collector and the active material on the electrode surface are greatly different

Method used

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  • Secondary lithium-ion battery with aluminum, nickel, copper and graphite cloth as current collector
  • Secondary lithium-ion battery with aluminum, nickel, copper and graphite cloth as current collector
  • Secondary lithium-ion battery with aluminum, nickel, copper and graphite cloth as current collector

Examples

Experimental program
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Effect test

Embodiment 1

[0016] Lithium cobaltate and artificial graphite are used as positive and negative electrode active materials, and aluminum-coated graphite cloth (graphite cloth thickness 140µm aluminum coating thickness 1µm) and nickel-plated graphite cloth (graphite cloth thickness 180µm nickel coating thickness 3µm) are used as positive and negative electrode current collectors ; The battery structure is laminated. Add the positive electrode active material, 5% binder PVDF, and 5% conductive agent VGCF into NMP (nitrogen methyl pyrrolidone) in proportion; add the negative electrode active material, 5% binder PVDF, and 3% conductive agent VGCF by Add NMP (Nitromethylpyrrolidone) in proportion, stir it into a homogeneous mixture, apply it to aluminum-plated and nickel-plated graphite cloth positive and negative current collectors on both sides, soak for a period of time, vacuum dry and electrode press, and then cut into pieces for later use. Alternately overlap and arrange the positive and n...

Embodiment 2

[0020] Lithium manganate and lithium titanate are used as positive and negative electrode active materials, and aluminum-coated graphite cloth (graphite cloth thickness 200µm, aluminum coating thickness 4µm) and nickel-plated graphite cloth (graphite cloth thickness 250µm, nickel coating thickness 7µm) are used as positive and negative electrode collectors. Fluid; the battery structure is laminated. The preparation method of the pole piece and the battery and the preparation of the comparative battery are the same as those described in Example 1.

[0021] The comparative lithium ion battery prepared in the above manner has a design capacity of 2000mAh. The voltage of the battery using aluminum-plated and nickel-plated graphite cloth as the positive and negative current collectors is 2.5V, the first discharge capacity is 1960mAh, and the capacity retention rate after 50 cycles is 92%. The first discharge capacity of the battery using traditional metal foil as the positive and ...

Embodiment 3

[0023] Use ternary materials and silicon-carbon composite materials as positive and negative electrode active materials, and use aluminum-coated graphite cloth (graphite cloth thickness 270µm aluminum coating thickness 5µm) and nickel-plated graphite cloth (graphite cloth thickness 300µm nickel coating thickness 10µm) as positive and negative electrodes Current collector; battery structure is laminated. The preparation method of the pole piece and the battery and the preparation of the comparative battery are the same as those described in Example 1.

[0024] The comparative lithium ion battery prepared in the above manner has a design capacity of 2000mAh. The voltage of the battery using aluminum-plated and nickel-plated graphite cloth as the positive and negative electrode collectors is 3.5V, the first discharge capacity is 1954mAh, and the capacity retention rate after 50 cycles is 95%, that is, 1885mAh, while the traditional metal foil is used as the positive and negative ...

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Abstract

The present invention relates to a secondary lithium ion battery adopting an aluminum-plated, nickel-plated and copper-plated graphite cloth as a current collector. The secondary lithium ion battery is characterized in that the graphite cloth substrate thickness is 140-300 [mu]m, the aluminum plating layer thickness is 1-8 [mu]m, the nickel plating layer thickness is 2-10 [mu]m, the copper plating layer thickness is 2-10 [mu]m, and the plating sequence is that a carbon layer is coated on a substrate, then a transition carbonization metal layer is coated, and finally a metal layer is coated. The concrete preparation method comprises: uniformly mixing a positive electrode active material, a negative electrode active material, an electric conduction agent and a binder in a suitable solvent, carrying out double-surface coating on an aluminum-plated, nickel-plated, and copper-plated graphite cloth by using a curtain coating manner, completely infiltrating, and finally carrying out vacuum drying and electrode plate pressing. According to the present invention, the utilization efficiencies of the positive electrode active substance and the negative electrode active substance are improved, and the capacity and the rate discharge performance of the lithium ion battery are substantially improved.

Description

technical field [0001] The invention relates to a secondary lithium-ion battery with aluminum, nickel and copper-plated graphite cloth as a current collector. In a single secondary lithium-ion battery, the material of the positive electrode current collector is aluminum-plated graphite cloth, and the material of the negative electrode current collector is nickel-plated Or copper-coated graphite cloth, which can be applied to energy storage, new energy vehicles and portable electronic products, and belongs to the technical field of lithium-ion batteries. Background technique [0002] At present, people's requirements for the energy density of secondary lithium-ion batteries are gradually increasing, and various scientific research institutes and battery manufacturers are constantly seeking new materials to promote the continuous improvement of battery performance. In addition to the continuous development of new cathode materials with higher energy density, the innovative dev...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/0525H01M4/66H01M4/70
CPCY02E60/10
Inventor 米新艳曹婷婷崔新然安宇鹏姜涛常潇然陈慧明张克金
Owner CHINA FIRST AUTOMOBILE
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