Photothermally responsive smart energy saving composite film
A composite film, responsive technology, applied in the direction of luminescent materials, synthetic resin layered products, layered products, etc., can solve the problem of not meeting the needs of consumers
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[0053] The technical solutions of the present invention will be further described in detail below through examples. The scope of the present invention is not limited by the specific embodiments but by the scope of the claims.
[0054] The spiropyrans according to the present invention can be prepared according to the following steps, with R 1 for hydrogen, R 2 for nitro, R 3 for -CH 2 CH 2 COOH as an example. Add 3.2g of trimethylindole and 4.0g of ioformic acid into a 50mL round bottom flask, protect with nitrogen, heat at 95°C and stir for 4h. After the reaction is complete, the resulting solution is dissolved in 100mL of distilled water, extracted with chloroform, and the organic phases are combined. After rotary evaporation, the residue was recrystallized from acetone-ether to obtain a light yellow solid.
[0055] Weigh 3.6g of the above-mentioned light yellow solid and 1.7g of 5-nitrosalicylaldehyde, 30mL of butanone, and 1mL of piperidine, and reflux for 5h under a...
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