Novel dyeing method of reactive dyes

A technology of reactive dyes and dyeing methods, applied in dyeing methods, textiles and papermaking, etc., can solve the problems of loss of covalent bonding, excessive sewage discharge, high water consumption and energy consumption, etc., reduce hydrolysis side reactions and improve dyeing effect , Improve the effect of color fixing rate

Active Publication Date: 2015-12-09
GUANGDONG ESQUEL TEXTILES CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the traditional cotton fabric dyeing system using water as the medium, reactive dyes will undergo hydrolysis side reactions during alkaline fixation, thus losing the ability to covalently bond with cellulose fibers, greatly reducing the utilization of reactive dyes; At the same time, in order to obtain the required dyeing fastness to wet treatment after dyeing, the hydrolyzed dye distributed in the fiber interior, fiber surface and inter-fiber capillary network channels must be removed by sufficient washing. Therefore, in the traditional dyeing process, reactive The color fixation rate of the dye is not high (about 40-85%)
[0003] In addition, the traditional dyeing process consumes a lot of water and energy, and discharges a lot of sewage during the dyeing process; although it is recorded in the prior art that dyeing with a small liquor ratio is used, it has not been widely used in this field, mainly because of the small liquor ratio dyeing. It is easily affected by the solubility of dyes, equipment specificity, dyeing levelness and easy abrasion of the fabric surface, and cannot obtain satisfactory results
[0004] Although the prior art utilizes pure organic solvents for dyeing to improve the utilization rate of reactive dyes, this method is limited by the variety of dyes, the safety of solvents and the feasibility of dyeing processes, and has not been popularized.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] The present embodiment provides a kind of novel dyeing method of reactive dye, and this method comprises the following steps:

[0037] Step 1: Pretreatment of pure cotton woven fabrics including desizing, scouring and bleaching;

[0038]Step 2: the above-mentioned pretreated woven cloth is pad-padped to comprise the mixed solution (the volume of the mixed solution) of 30g / L reactive dye (reactive red, containing three active groups) and 20g / L soda ash, in Stack at room temperature for 20 hours, then dry at 100°C for 30s;

[0039] Step 3: pad the above-mentioned dried fabric with a mixed solution containing 5g / L acetic acid and 20g / L fixing agent (fixing agent 2518, provided by Guangdong Demei Fine Chemical Co., Ltd.), and then bake at 150°C Bake for 30s; obtain a red pure cotton woven fabric with uniform color and in compliance with the national color fastness standard (18401).

[0040] The red pure cotton woven fabric provided by this embodiment has a simple processi...

Embodiment 2

[0042] The present embodiment provides a kind of novel dyeing method of reactive dye, and this method comprises the following steps:

[0043] Step 1: Pretreatment of cotton / linen woven fabrics including desizing, scouring and bleaching;

[0044] Step 2: the above-mentioned pretreated woven fabric is pad-pad comprising the mixed solution of 20g / L reactive dye (reactive blue, containing three active groups) and 20g / L soda ash (content is based on the volume of the mixed solution), in Stack at room temperature for 20 hours, then dry at 90°C for 30s;

[0045] Step 3: pad the above-mentioned dried fabric with a mixed solution containing 5g / L acetic acid and 20g / L fixing agent (fixing agent 2518, provided by Guangdong Demei Fine Chemical Co., Ltd.), and then bake at 150°C Bake for 30s; obtain a blue cotton / linen woven fabric with uniform color and in line with the national color fastness standard (18401).

[0046] The blue cotton / linen woven fabric provided by this embodiment has ...

Embodiment 3

[0048] The present embodiment provides a kind of novel dyeing method of reactive dye, and this method comprises the following steps:

[0049] Step 1: After padding the pure cotton woven fabric through desizing, scouring and bleaching containing 50g / L cationic modifier CR-2000 (provided by Dow Chemical) and 12g / L caustic soda, control the liquid The rate is 90%, stacked at room temperature for 24 hours, washed with warm water at 40°C three times, then washed with 0.5g / L acetic acid solution, dried and coiled to obtain a pretreated woven fabric;

[0050] Step 2: After the above-mentioned pretreated woven cloth is pad-pad comprising a mixed solution of 25g / L reactive dye (reactive blue, containing three active groups) and 15g / L soda ash (content is based on the volume of the mixed solution), Stack at room temperature for 20 hours, then dry at 90°C for 30s;

[0051] Step 3: pad the above-mentioned dried fabric with a solution containing 5g / L acetic acid and 20g / L fixing agent (fi...

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PUM

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Abstract

The invention provides a novel dyeing method of reactive dyes. The method includes the steps of conducting preprocessing, wherein loose fiber or yarn or fabric is preprocessed; conducting dyeing, wherein the preprocessed loose fiber or yarn or fabric is dyed in the reactive dyes through a water-saving dyeing method; conducting color fixing, wherein the dyed loose fiber or yarn or fabric is directly soaked in color fixing liquid to be subjected to color fixing and is then baked so that the dyeing process of the reactive dyes can be completed. In the dyeing step, the structure of the reactive dyes at least contains three active groups. According to the technical scheme, operation is easy, no salt is used in the dyeing process, and the good dyeing and color fixing effects can be achieved with a smaller volume of water; in addition, water used in the dyeing process can be directly evaporated in the subsequent operation process, no washing operation is needed after color dyeing and fixing, and therefore no dyeing wastewater can be produced after operation is ended, and clean production is achieved.

Description

technical field [0001] The invention relates to a novel dyeing method of reactive dyes, which belongs to the field of textile dyeing and finishing. Background technique [0002] In the traditional cotton fabric dyeing system using water as the medium, reactive dyes will undergo hydrolysis side reactions during alkaline fixation, thus losing the ability to covalently bond with cellulose fibers, greatly reducing the utilization of reactive dyes; At the same time, in order to obtain the required dyeing fastness to wet treatment after dyeing, it is necessary to remove the hydrolyzed dye distributed in the fiber interior, fiber surface and inter-fiber capillary network channels through sufficient washing. Therefore, in the traditional dyeing process, reactive The dye fixation rate is not high (about 40-85%). [0003] In addition, the traditional dyeing process consumes a lot of water and energy, and discharges a lot of sewage during the dyeing process; although it is recorded in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06P1/38D06P3/66D06P3/85D06P1/673D06P5/02D06P5/04
Inventor 徐伟杰周立明张玉高陈可兵
Owner GUANGDONG ESQUEL TEXTILES CO LTD
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