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A kind of transparent medical PVC material suitable for broad-wave light-shielding and preparation method thereof

The technology of PVC material and PVC resin is applied in the field of transparent medical PVC material and its preparation, which can solve the problems of narrow light-proof range and low light transmittance, and achieve the effects of reducing particle diameter, improving dispersibility and good light transmittance.

Active Publication Date: 2017-09-22
深圳恒方大高分子材料科技有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The object of the present invention is to provide a kind of PVC material suitable for wide-wave transparent medical use and preparation method thereof, it can increase the light-proof wavelength range to 220-550nm, and the light transmittance can reach more than 0%, so as to solve the problem of the existing light-proof medical PVC material. The problem of narrow light-shielding range (220-450nm) and low light transmittance (less than 30%) meets the higher clinical application requirements of light-shielding infusion sets

Method used

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  • A kind of transparent medical PVC material suitable for broad-wave light-shielding and preparation method thereof
  • A kind of transparent medical PVC material suitable for broad-wave light-shielding and preparation method thereof
  • A kind of transparent medical PVC material suitable for broad-wave light-shielding and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0015] Example 1 Formula composition: 100 parts by weight of PVC resin, 50 parts by weight of plasticizer, 2.0 parts by weight of calcium / zinc stabilizer, 8.0 parts by weight of auxiliary heat stabilizer, 1.0 part by weight of lubricant, and 0.01 part by weight of light-shielding agent. Wherein said PVC resin is polyvinyl chloride resin by suspension method, and the degree of polymerization is 800-2500; said calcium / zinc heat stabilizer is 40-50% calcium ricinoleate, 15-20% zinc octylate, 10-20% zinc stearate, 15-25% polyvinyl alcohol composition compound; Described auxiliary thermal stabilizer is epoxy soybean oil (ESBO); Described lubricant is polyethylene wax; Described The light shielding agent consists of 40-60% iron oxide red (Fe 2 o 3 ), 20-30% iron oxide yellow (Fe 2 o 3 ·H 2 O) and 20-30% carbon black compound.

[0016] The specific production steps are:

[0017] (1) Add iron oxide red, iron oxide yellow, and carbon black into the quantitative epoxy soybean oil ...

Embodiment 2

[0022] Embodiment 2 Formula composition: 100 parts by weight of PVC resin, 65 parts by weight of plasticizer, 1.5 parts by weight of calcium / zinc stabilizer, 10 parts by weight of auxiliary heat stabilizer, 0.7 parts by weight of lubricant, and 0.02 parts by weight of light-shielding agent, wherein The PVC resin is a suspension polyvinyl chloride resin with a degree of polymerization of 800-2500; the calcium / zinc heat stabilizer is 40-50% calcium ricinoleate, 15-20% zinc octylate, 10 -20% zinc stearate, 15-25% polyvinyl alcohol composition compound; Described auxiliary heat stabilizer is epoxy soybean oil (ESBO); Described lubricant is polyethylene wax; Described The light shielding agent consists of 40-60% iron oxide red (Fe 2 o 3 ), 20-30% iron oxide yellow (Fe 2 o 3 ·H 2 O) and 20-30% carbon black compound.

[0023] The preparation method is the same as in Example 1.

Embodiment 3

[0025] Embodiment 3 Formula composition: 100 parts by weight of PVC resin, 75 parts by weight of plasticizer, 1.0 part by weight of calcium / zinc stabilizer, 12 parts by weight of auxiliary heat stabilizer, 0.5 part by weight of lubricant, and 0.05 part by weight of light-shielding agent, wherein The PVC resin is a suspension polyvinyl chloride resin with a degree of polymerization of 800-2500; the calcium / zinc heat stabilizer is 40-50% calcium ricinoleate, 15-20% zinc octylate, 10 -20% zinc stearate, 15-25% polyvinyl alcohol composition compound; Described auxiliary heat stabilizer is epoxy soybean oil (ESBO); Described lubricant is polyethylene wax; Described The light shielding agent consists of 40-60% iron oxide red (Fe 2 o 3 ), 20-30% iron oxide yellow (Fe 2 o 3 ·H 2 O) and 20-30% carbon black compound.

[0026] The preparation method is the same as in Example 1.

[0027] Select 3 examples with the basic formula of the present invention to carry out implementation ve...

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Abstract

The invention relates to a transparent medical PVC material suitable for wide-wave shading and a preparation method thereof. The PVC material is composed of, by weight, 100 parts of suspension-method PVC resin, 50-75 parts of plasticizers DEHP and TOTM, 1.0-2.0 parts of a Ca / Zn thermal stabilizer, 8-12 parts of an auxiliary thermal stabilizer, 0.5-1.0 part of a lubricant and 0.01-0.05 parts of a shading agent. The shading wave length range of the PVC material is increased to 220-550 nm and the light transmittance reaches not less than 0%. The PVC material solves the problems of narrow shading range (220-450 nm) and low light transmittance (less than 30%) which exist in the shading medical PVC materials in the prior art, thereby satisfying the higher clinical application demands in a shading transfusion device.

Description

technical field [0001] The invention relates to a modification technology of a medical PVC material, in particular to a transparent medical PVC material suitable for wide-wave light protection and a preparation method thereof. Background technique [0002] Medical PVC material is the most widely used raw material for disposable medical device consumables at home and abroad. Due to the advantages of good comprehensive performance and high cost performance, PVC materials are more and more widely used in disposable medical devices, among which the application of infusion sets is the most important. However, it has been clinically found that many drugs have special molecular structures that absorb light energy when they are used in ordinary non-light-proof infusion sets. Especially because the light energy in the ultraviolet region is large, reactions such as decomposition and oxidation occur, resulting in the occurrence of drug components. change, reduce or lose the due curati...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L27/06C08L29/04C08L91/00C08L23/06C08K13/06C08K5/098C08K3/22C08K3/04B29C47/92B29C48/92
Inventor 徐龙平陆锋韩梁
Owner 深圳恒方大高分子材料科技有限公司
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