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Preparation method of hydrolysis-resisting polyurethane synthetic leather for sofas, furniture and automobile seats

A car seat and hydrolysis-resistant technology, which is applied in the direction of textiles and papermaking, can solve the problems of strong leather feeling, short process flow, and poor air permeability of the product, so as to improve the bonding strength, strengthen the hydrolysis resistance, and improve the hydrolysis resistance. Effect

Active Publication Date: 2016-03-30
ANHUI ANLI MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the production process of polyurethane synthetic leather can be divided into wet-dry process and full-dry process. The specific production steps of the wet-dry process are to first make the cloth base into a bass through a wet process, and then pass a dry process on the base. Process veneer, after drying and molding to make finished products, the product has good air permeability and strong leather feel. The disadvantage is that the process is long and the product has poor hydrolysis resistance; the full dry process refers to coating the resin on the release paper directly. The finished product is dried and molded after lamination. The advantage is that the process is short, and the product has good touch, toughness, appearance and hydrolysis resistance, but the disadvantage is that it is difficult to reach the level of hydrolysis resistance for more than 10 years, and the product has poor air permeability

Method used

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Polycarbon resin ST-300PC is a product of Hefei Amway Polyurethane New Material Co., Ltd.; leveling agent BYK-9565 is a product of German BYK Chemical Company; calcium carbonate is a product of Junbo Industrial (Shanghai) Co., Ltd.; silicone polyurethane resin 200G, silicone Polyurethane resin 1000G, diluent and curing agent are products of Dongguan Liangzhan Silicone Technology Co., Ltd.; polycarbonate diol (PCDL) is a product of Jining Baiyi Chemical Co., Ltd.; diphenylmethane diisocyanate (MDI) is a product of Yantai The product of Wanhua Group; NX-128 tin methyl mercaptide is the product of Nantong Advan Chemical Co., Ltd.

[0044] The polyurethane synthetic leather for hydrolysis-resistant sofa furniture and automobile seats of the present invention is prepared according to the following steps:

[0045] 1. Preparation of silicone-modified polycarbonate polyurethane resin SI-300PC

[0046] The mass parts of raw materials are reacted in the polymerization kettle acc...

Embodiment 2

[0076] Polycarbon resin ST-130PC is a product of Hefei Amway Polyurethane New Material Co., Ltd.; leveling agent BYK-9565 is a product of German BYK Chemical Company; calcium carbonate is a product of Junbo Industrial (Shanghai) Co., Ltd.; silicone polyurethane resin 200G, silicone Polyurethane resin 1000G, vinyl-terminated polymethylvinylsiloxane and curing agent are products of Dongguan Liangzhan Silicone Technology Co., Ltd.; polycarbonate diol (PCDL) is a product of Jining Baiyi Chemical Co., Ltd.; diphenyl Methyl methane diisocyanate (MDI) is a product of Yantai Wanhua Group; NX-128 methyl mercaptide tin is a product of Nantong Advan Chemical Co., Ltd.

[0077] The polyurethane synthetic leather for hydrolysis-resistant sofa furniture and automobile seats of the present invention is prepared according to the following steps:

[0078] 1. Preparation of silicone-modified polycarbonate polyurethane resin SI-130PC

[0079] The mass parts of raw materials are reacted in the p...

Embodiment 3

[0109] Polycarbon resin LY-60PC is a product of Hefei Amway Polyurethane New Material Co., Ltd.; leveling agent BYK-9565 is a product of German BYK Chemical Company; calcium carbonate is a product of Junbo Industrial (Shanghai) Co., Ltd.; silicone polyurethane resin 200G, silicone Polyurethane resin 1000G, vinyl-terminated polymethylvinylsiloxane and curing agent are products of Dongguan Liangzhan Silicone Technology Co., Ltd.; polycarbonate diol (PCDL) is a product of Jining Baiyi Chemical Co., Ltd.; diphenyl Methyl methane diisocyanate (MDI) is a product of Yantai Wanhua Group; NX-128 methyl mercaptide tin is a product of Nantong Advan Chemical Co., Ltd.

[0110] The polyurethane synthetic leather for hydrolysis-resistant sofa furniture and automobile seats of the present invention is prepared according to the following steps:

[0111] 1. Preparation of silicone-modified polycarbonate polyurethane resin LI-60PC

[0112] The mass parts of raw materials are reacted in the pol...

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Abstract

The invention provides a preparation method of hydrolysis-resisting polyurethane synthetic leather for sofas, furniture and automobile seats. The preparation method comprises the steps of preparation of organic silicon modified poly-carbon type polyurethane resin, impregnation treatment of a cloth base, preparation of a transfer membrane and curing of a coating. According to QB / T 4671-2014 (determination of hydrolysis resistance of an artificial leather and synthetic leather testing method), the surface PU coating is not cracked or powdered after the synthetic leather is stored for more than 10 weeks under the environments that the temperature is 70 DEG C and the relative humidity is 95%, and the stripping strength basically keeps unchanged; and the hydrolysis-resisting polyurethane synthetic leather can be widely applied to fabrics of the sofas, the furniture and the automobile seats under high-temperature and high-humidity environments, and a jungle test result shows that the hydrolysis-resisting polyurethane synthetic leather can be used for 10 years.

Description

Technical field [0001] The present invention involves a decade of water -resistant sand -resistant furniture and automotive seat production method for synthesis of polyurethane synthetic leather, which especially involves the effect of organic silicon resin to improve the synthetic leather and hydrolysis. Background technique [0002] Polyurethane synthetic leather is the most ideal material in the world to replace natural leather products. It is mainly used in shoes, bags, balls, balls, furniture and cars.With the improvement of people's living standards, people have also put forward higher requirements for the durability of synthetic leather, especially in terms of car seats and sofa fabrics that require the hydrolysis resistance of synthetic leather for more than 10 years.The factors affecting PU leather aging are mainly air, sunlight and moisture. The hydrolysis resistance of synthetic leather depends on the hydrolysis resistance of Boji and PU layer. [0003] At present, t...

Claims

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Application Information

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IPC IPC(8): D06N3/14C08G18/66C08G18/44C08G18/32
CPCC08G18/32C08G18/44C08G18/66D06N3/14
Inventor 笪丽红胡兆阳苏星吴文刘志球胡俊范培宏罗运东
Owner ANHUI ANLI MATERIAL TECH