All-biological-based resin composition

A technology of base resin and composition, applied in the field of full bio-based resin composition, can solve the problems that are not involved in hydrolysis resistance, destructive biodegradability, overall performance defects, etc., and achieve superior biodegradation performance, high toughness and Effects of hydrolysis resistance and high hydrolysis resistance

Inactive Publication Date: 2016-06-22
宁波高新区优合塑料制品有限公司
View PDF8 Cites 14 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

According to the content disclosed in the above prior art, it can be seen that in order to improve the hydrolysis resistance of polylactic acid materials, petroleum-based carbodiimide anti-hydrolysis agents are mostly used, which destroys the biodegradability and renewable advantages of polylactic acid. It has a certain impact on the environmental load; although the patent of Chinese application number 201180028896.9 discloses the preparation method and use of bio-based carbodiimide, no further research has been done on the application of polylactic acid ma

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • All-biological-based resin composition
  • All-biological-based resin composition

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0025] A preparation method of bio-based carbodiimide (biopolyols ratio is 54%), the specific steps are as follows:

[0026] Add 200 grams of Stabaxol P220 polycarbodiimide (a tetramethylxylylene diisocyanate produced by Rhein Chemie, with an NCN content of about 14%) in a nitrogen atmosphere, and add 238 grams of Agrol2 when heated to 140°C .0 Bio-based polyol (a kind of bio-based polyol with an OH number of 74.5 produced by Cargrill Company), start to stir the mixture, monitor the NCO content in the mixture, until the NCO content drops to zero, the reaction ends to obtain bio-polyols The ratio is 54% bio-based carbodiimide.

Example Embodiment

[0027] Example 1

[0028] A fully bio-based resin composition, proportioned by weight of the following components: 100 parts of polylactic acid (Hisun Biomaterials REVODE190), 2 parts of bio-based carbodiimide (54% of biopolyols) , Talcum powder (3000 mesh) 5 parts, polycaprolactone 2 parts; put the mixture in a twin-screw extruder for blending and granulation. The temperature of each section of the screw is set to 190℃, 200℃, 210℃, 220℃, 205℃, rotation speed: 50rpm, after granulation, put into injection molding machine for injection molding, injection temperature is 205℃, injection pressure is 100mpa, cooling time of melt in the mold is 38 seconds, mold temperature Set to 100°C to obtain a fully bio-based resin composition. The mechanical properties and hydrolysis resistance of the composition were tested, and the results are shown in Table 1 and Table 2.

Example Embodiment

[0029] Example 2

[0030] The total bio-based resin composition is proportioned according to the following components by weight: 100 parts of polylactic acid (Hisun Biomaterials REVODE190), 2 parts of bio-based carbodiimide (the proportion of biopolyols is 54%), and talc (3000 mesh) 5 parts, 10 parts polybutylene succinate; put the well-proportioned mixture in a twin-screw extruder for blending and granulation. The temperature of each section of the screw is set to: 190℃, 200℃ , 210℃, 220℃, 205℃, rotation speed: 50rpm, after granulation, put into injection molding machine for injection molding, injection temperature is 205℃, injection pressure is 100mpa, cooling time of melt in mold is 38 seconds, mold The temperature was set to 100°C to obtain a fully bio-based resin composition. The mechanical properties and hydrolysis resistance of the composition were tested, and the results are shown in Table 1 and Table 2.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses an all-biological-based resin composition and belongs to the field of environment-friendly materials. The all-biological-based resin composition comprises all-biological degradable material polylactic acid, biological-based carbonized diimine anti-hydrolysis agent, inorganic talcum powder nucleating agent and biological-based polyester material toughener with flexible molecular chains. The all-biological-based resin composition has high toughness, high hydrolysis resistance and excellent biodegradability, organic polymer parts contained in materials can be degraded completely, and the characteristic of renewability of raw materials of the resin composition is maintained.

Description

technical field [0001] The invention belongs to the field of environment-friendly materials, and in particular relates to an all-bio-based resin composition, which has good hydrolysis resistance and toughness. Background technique [0002] Most of the plastic products used in daily life come from petroleum-based. Due to concerns about the depletion of petroleum resources and the global warming effect caused by the increase of carbon dioxide in the air in recent years, it is more and more necessary to reduce the use of petroleum-based plastics; However, bio-based plastics carry the advantages of renewable and biodegradable raw materials. If they can be applied and used on a large scale to replace some petroleum-based plastics, it will be a very good choice to reduce the environmental load while reducing the consumption of petroleum resources. ; In the field of bioplastics, the application of polylactic acid materials in the fields of daily necessities, spinning, and other pla...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08L67/04C08L67/02C08K3/34C08K5/29B29C47/92B29C45/76B29C45/77B29C45/78B29C48/92
CPCC08L67/04B29C45/76B29C45/77B29C45/78B29C48/92B29C2948/9259B29C2948/92704C08K2201/014C08L2201/06C08L2205/02C08L2205/025C08L2205/24C08K3/34C08K5/29C08L67/02
Inventor 姜笑君
Owner 宁波高新区优合塑料制品有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap