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A cleaning process for the production of cellulose foam material

A cellulose foaming and crafting technology, applied in the coating and other directions, can solve the problems of fast corrosion of cutting machines, insoluble sodium sulfate, unsafety and other problems, and achieve the advantages of improving production efficiency, low concentration of cleaning solution and reducing production costs. Effect

Active Publication Date: 2018-07-31
潍坊欣龙生物材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] 3. In the prior art, large-scale industrial dehydrators are used to dehydrate cellulose foam materials, which is unsafe;
[0007] 4. In the prior art, a large industrial dehydrator is used to dehydrate the cleaned cellulose foam material, resulting in a substantial increase in equipment investment costs;
[0008] 5. In the prior art, the entire cleaning process for the production of cellulose foam materials needs to be soaked for 5-12 hours to dissolve the internal Glauber's salt, and the production efficiency is too low;
[0009] 6. When the pore size of the cellulose foam material product is <1mm, it is difficult for the cleaning solution to enter the product, resulting in difficulty in dissolving the internal sodium sulfate;
[0010] 7. In the prior art, during the elution process of the cellulose foam material, the amount of magnesium chloride used is too large, so that the prepared cellulose foam material has too high a salt content, resulting in high difficulty in downstream cleaning;
[0011] 8. In the existing technology, due to the high salt content in the cellulose foam material, during the processing of the foam material by downstream customers, salt dust is prone to occur in the production of dry products, and the cutting machine corrodes quickly, etc.;
[0012] 9. The process of cleaning the cellulose foam material in the prior art is not suitable for large-scale production

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] Embodiment 1 The cleaning of cellulose foam material production

[0054]Pickling: measure the initial specifications of the cellulose foam material after molding, the length, width, and height are 1010mm, 1015mm, and 423mm respectively, and the pore diameter of the cellulose foam material is about 0.7mm; put it into the extrusion cleaning tank, Squeeze to 75% of the height of the original specification, and squeeze out the waste liquid contained in the cellulose foam material itself; inject dilute sulfuric acid solution, the pH of the dilute sulfuric acid solution is 3.5, the temperature is 75°C, and the liquid level reaches the cellulose foam. The foam material is 1.35 times the height of the initial specification, and then the pressure is released so that the pressure relief plate no longer squeezes the foam material. The entire pickling time is 15 minutes.

[0055] Bleaching: Squeeze the pickled cellulose foam material to 65% of the original specification height, and...

Embodiment 2

[0058] Embodiment 2 The cleaning of cellulose foam material production

[0059] Pickling: After the cellulose foam material product is molded, the initial specifications are measured. The length, width and height dimensions are 1010mm, 1015mm, and 1005mm respectively, and the pore diameter of the cellulose foam material is about 0.5mm; To 70% of the height of the original specification, squeeze out the waste liquid contained in the cellulose foam material itself; inject hydrochloric acid solution, the pH of the hydrochloric acid solution is 3.0, the temperature is 100°C, and the liquid level reaches 1.5 times the height of the original specification, Then release the pressure until the pressure plate no longer squeezes the cellulose foam material, and the entire pickling time is 20 minutes.

[0060] Bleaching: the cellulose foam material after extrusion pickling is extruded to 60% of the initial specification height, and the acid solution is extruded out of the cleaning tank; ...

Embodiment 3

[0063] Embodiment 3 The cleaning of cellulose foam material production

[0064] Pickling: Measure the initial specifications of the cellulose foam material after molding. The length, width, and height are 501mm, 501mm, and 502mm respectively. The height of the product is 80%, and the extruded cellulose foam material has its own waste liquid discharged from the cleaning tank; inject acetic acid solution, the pH of the acetic acid solution is 4.0, the temperature is 40°C, and the liquid level reaches 1.2 times the height of the original initial specification, and then drains Press until the press plate no longer squeezes the cellulose foam material, and the entire absorption pickling time is 15 minutes.

[0065] Bleaching: Squeeze the pickled cellulose foam material to 70% of the original specification height, squeeze the pickling solution out of the tank; inject hydrogen peroxide bleaching solution, the concentration of the hydrogen peroxide bleaching solution is 0.2%, the temp...

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Abstract

The invention provides a cleaning process for production of a cellulose foam material. The cleaning process is characterized by comprising the steps of acid cleaning and bleaching, wherein the acid cleaning step comprises: extruding a prepared cellulose foam material until the height is 70-80% of the initial specification height, and injecting an acid solution, and the amount of the injected acid solution is 1.2-1.5 times that of the initial specification height; in the acid cleaning step, the acid solution is one or more of a sulfuric acid solution, a hydrochloric acid solution, and an acetic acid solution; and the pH value of the acid solution is 3-4, and the temperature of the acid solution is 40-100 DEG C. According to the cleaning process for cleaning the cellulose foam material, provided by the invention, the produced cellulose foam material does not have acicular crystals on the surface, and is good in appearance, and the whiteness is more than or equal to 80%; and by adopting the process for cleaning the cellulose foam material, adopted by the invention, the cleaning time is 90-150min, and the production efficiency is greatly improved.

Description

technical field [0001] The invention relates to a cleaning process for the production of foamed materials, in particular to a cleaning process suitable for the production of cellulose foamed materials. Background technique [0002] Cellulose foam material has biodegradability, oil absorption, strong water absorption and water expansion, so it can be used for civil cleaning, industrial cleaning and water engineering. As people's awareness of environmental protection continues to increase, the market demand for cellulose foam materials will continue to increase. Cellulose foaming material is mainly prepared from regenerated cellulose solution, reinforcing fiber and Glauber's salt (sodium sulfate decahydrate) through material mixing, injection molding, heat curing, neutralization, bleaching, cleaning and other process steps. Sodium sulfate aqueous solution is easy to produce a large number of needle-like crystals at room temperature, resulting in poor appearance of the cellulo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J9/36C08L1/02
CPCC08J9/36C08J2301/02
Inventor 万和军贾守江刘长军马君志岳本增马清涛
Owner 潍坊欣龙生物材料有限公司