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A kind of polyolefin-based conductive and dielectric composite material and preparation method thereof

A polyolefin and conductive filler technology, which is applied in the field of polyolefin-based conductive and dielectric composite materials and their preparation, can solve the problems of poor mechanical properties of conductive materials, complex processing technology, low percolation, etc., and achieve high strength and toughness , good overall performance, high conductivity effect

Active Publication Date: 2018-04-24
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to factors such as weak interfacial adhesion and defects between the conductive particles and the polymer matrix, the mechanical properties of the conductive materials obtained by these methods are generally very poor, especially for materials with isolated structures, which have rigidity, toughness, etc. The mechanical properties are generally extremely poor; at the same time, the construction of a special structure will inevitably bring about a complex process, these problems greatly limit the industrial production and application of conductive polymer materials, so how to easily prepare a low Conductive polymer composites with percolation, high conductivity and good mechanical properties are very necessary

Method used

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  • A kind of polyolefin-based conductive and dielectric composite material and preparation method thereof
  • A kind of polyolefin-based conductive and dielectric composite material and preparation method thereof
  • A kind of polyolefin-based conductive and dielectric composite material and preparation method thereof

Examples

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Effect test

Embodiment 1

[0032] Polypropylene / ethylene-octene block copolymer (PP / OBC) blend with a mass ratio of 80:20 is used as the polymer matrix, and multi-walled carbon nanotubes (MWCNT) are used as conductive filler particles; at 190°C, 80rpm Under conditions, in the torque rheometer (XSS-300 type, produced by Shanghai Qingji Mold Factory), OBC and different contents (1,3,5,7,9,11,13,15wt%), conductive filler The content refers to the mass percentage of MWCNT in the total amount of PP / OBC) MWCNT was blended for 3 minutes, and then PP was added to continue blending under the same conditions for 8 minutes to obtain a PP / OBC / MWCNT composite material with uniformly dispersed MWCNT. The obtained composite material was pressed at 190°C and 10 MPa for 5 minutes, and then cooled to obtain a PP / OBC / MWCNT sheet, and its electrical and mechanical properties were tested.

Embodiment 2

[0034] A high-density polyethylene / ethylene-octene block copolymer (HDPE / OBC) blend with a mass ratio of 80:20 is used as the polymer matrix, and multi-walled carbon nanotubes (MWCNT) are used as conductive filler particles; at 190°C , under the condition of 80rpm, in the torque rheometer (XSS-300 type, produced by Shanghai Qingji Mold Factory), firstly mix OBC with different contents (the contents are respectively 1,3,5,7,9,11,13, 15 wt%) of MWCNT was blended for 3 minutes, and then HDPE was added to continue blending under the same conditions for 8 minutes to obtain a HDPE / OBC / MWCNT composite material with uniformly dispersed carbon tubes. The obtained composite material was pressed at 190°C and 10 MPa for 5 minutes, and after cooling, HDPE / OBC / MWCNT sheets were obtained, and their electrical and mechanical properties were tested.

Embodiment 3

[0036]The low-density polyethylene / ethylene-octene block copolymer (LDPE / OBC) blend with a mass ratio of 80:20 is used as the polymer matrix, and the multi-walled carbon nanotube (MWCNT) is used as the conductive filler particle; at 190°C , under the condition of 80rpm, in the torque rheometer (XSS-300 type, produced by Shanghai Qingji Mold Factory), first mix OBC with different contents (1,3,5,7,9,11,13,15wt%) The MWCNTs were blended for 3 minutes, and then LDPE was added to continue blending for 8 minutes under the same conditions to obtain LDPE / OBC / MWCNT composites with uniformly dispersed carbon tubes. The obtained composite material was pressed at 190°C and 10MPa for 5 minutes, and after cooling, LDPE / OBC / MWCNT sheets were obtained, and their electrical and mechanical properties were tested.

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Abstract

The invention relates to the novel field of polyolefin-based conductive and dielectric composite materials, and particularly relates to a polyolefin-based conductive and dielectric composite material and a preparation method thereof. The polyolefin-based conductive and dielectric composite material is prepared from the following raw materials in parts by weight: 70 to 95 parts of polyolefin matrix, 5 to 30 parts of ethylene-octene block copolymer, and 0. 1 to 15 parts of electrically conductive filler. The polyolefin-based conductive composite material provided by the invention has the advantages of relatively low conductivity percolation threshold, relatively high conductivity and dielectric constant when the content of the conductive filler is very low, relatively high strength and toughness, and good overall performance.

Description

technical field [0001] The invention relates to a new field of polyolefin-based conductive and dielectric composite materials, in particular to a polyolefin-based conductive and dielectric composite material and a preparation method thereof. Background technique [0002] In recent years, conductive polymer composites have been widely used in static dissipation, electromagnetic shielding, electronic sensors, and capacitors because of their advantages such as low density, easy processing, solvent resistance, and adjustable conductivity. However, in order to obtain conductive polymer composites with high conductivity, it is usually necessary to add a large amount of conductive fillers, and a large amount of conductive fillers will increase the cost of the molding process and greatly reduce the mechanical properties of the material. Therefore, there are currently two main problems in the design of conductive polymer composites: how to reduce the conductive percolation threshold ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/12C08L23/06C08L23/08C08K7/24
CPCC08K2201/001C08K2201/011C08L23/06C08L23/0815C08L23/12C08L2205/025C08L2207/062C08L2207/066C08K7/24
Inventor 杨伟查湘军包睿莹李亭谢邦互刘正英杨鸣波
Owner SICHUAN UNIV
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