Catalysis carbonization intumescent flame-retardant system and application thereof

An intumescent flame retardant system technology, applied in the direction of flame retardant fibers, textiles, papermaking, fiber treatment, etc., can solve the problems of secondary damage, failure to meet the requirements of flame retardant performance, etc., achieve good flame retardant performance, reduce heat Release rate, effect of reducing total heat release

Inactive Publication Date: 2016-08-10
DONGHUA UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Polyester is a flammable fiber, which cannot meet the requirements of flame retardant performance in some fields, so it needs to be treated with flame retardant
Most of the established methods of endowing polyester with flame retardancy achieve the flame retardancy effect by increasing the molten droplets while making the molten droplets drip quickly and self-extinguish, but the dripping of high-temperature molten matter is likely to cause secondary damage

Method used

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  • Catalysis carbonization intumescent flame-retardant system and application thereof
  • Catalysis carbonization intumescent flame-retardant system and application thereof
  • Catalysis carbonization intumescent flame-retardant system and application thereof

Examples

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Embodiment 1~12

[0024] According to the ratio shown in Table 1, the acid source, carbon source, gas source, charring catalyst and water that make up the catalytic carbonization intumescent flame retardant system were added to the colloid mill and ground for 4 hours to obtain a milky white viscous catalytic carbonization intumescent flame retardant system .

[0025] Table 1 Proportion of catalytic carbonization expansion flame retardant system

[0026]

[0027] In the table, APP—ammonium polyphosphate, PER—pentaerythritol, MEL—melamine, MPP—melamine pyrophosphate, Si-APP—silane-modified ammonium polyphosphate, the same below. (Example 12 test used melamine pyrophosphate—prepared by the reaction of sodium pyrophosphate and melamine, and the gas source has been included therein.)

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Abstract

The present invention relates to a catalytic carbonization expansion flame retardant system and its application. The system includes: an acid source, a carbon source, a gas source and a carbon forming catalyst; wherein, the mass percentage of the acid source in the flame retardant system is 15-30%; The mass ratio of acid source to gas source is 2-10:1; the mass ratio of acid source to carbon source is 2-10:1; the mass ratio of acid source to carbon-forming catalyst is 10-20:1. The catalytic carbonization expansion flame retardant system of the present invention is applied to the flame retardant post-finishing of polyester fabrics. The intumescent flame retardant system of the present invention does not contain halogen, and conforms to the development trend of less smoke and low toxicity of flame retardants, and is an environmentally friendly flame retardant system; the finished product has better flame retardant performance, and the finished polyester fabric has good flame retardant Anti-dripping.

Description

technical field [0001] The invention belongs to the field of functional finishing of textiles, in particular to a catalytic carbonization expansion flame retardant system and its application. Background technique [0002] Polyester is the most widely used synthetic fiber, widely used in national defense, industrial fabrics and all aspects of people's lives. Polyester is a flammable fiber, which cannot meet the requirements for flame retardant performance in some fields, so it needs to be treated with flame retardant. Most of the established methods of endowing polyester with flame retardancy achieve the flame retardancy effect by increasing the molten droplets while making the molten droplets drip quickly and self-extinguish, but the dripping of high-temperature melts is likely to cause secondary damage. It is a better way to endow polyester with flame retardancy if it can form a compact charcoal layer on the surface of the fiber when it is burned and reduce the dripping of...

Claims

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Application Information

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IPC IPC(8): D06M11/71D06M13/148D06M13/364D06M11/76D06M11/46D06M11/155D06M11/28D06M11/56D06M101/32
CPCD06M11/71D06M11/155D06M11/28D06M11/46D06M11/56D06M11/76D06M13/148D06M13/364D06M2101/32D06M2200/30
Inventor 吴亚容周翔马江涛邢志奇
Owner DONGHUA UNIV
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