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Inverted green light quantum dot thin film electroluminescence device and preparation method thereof

A technology for electroluminescent devices and quantum dots to emit light, which can be applied in the fields of electric solid-state devices, semiconductor/solid-state device manufacturing, electrical components, etc. Effect

Inactive Publication Date: 2018-05-29
SHANGHAI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Based on this, it is necessary to provide an inverted green light quantum dot thin film electroluminescent device and its preparation method that can solve the problem of high hole injection barrier

Method used

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  • Inverted green light quantum dot thin film electroluminescence device and preparation method thereof
  • Inverted green light quantum dot thin film electroluminescence device and preparation method thereof
  • Inverted green light quantum dot thin film electroluminescence device and preparation method thereof

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preparation example Construction

[0044] Such as figure 2 The method for preparing the above-mentioned inverted green light quantum dot thin film electroluminescent device includes the following steps:

[0045] S10. Provide the substrate 10 and clean the substrate 10.

[0046] The substrate 10 usually selects glass with a higher transmittance.

[0047] The operation of cleaning the substrate 10 is: the substrate 10 is ultrasonically treated with detergent, acetone, ethanol and isopropanol each for 15 minutes in sequence.

[0048] S20, forming a cathode 20 on the cleaned substrate obtained in S10.

[0049] The material of the cathode 20 is indium tin oxide (ITO), fluorine-doped tin oxide (FTO), aluminum-doped zinc oxide (AZO), or indium-doped zinc oxide (IZO).

[0050] The thickness of the cathode 20 is 80 nm to 200 nm.

[0051] In the operation of forming the cathode 20 on the cleaned substrate obtained in S10, the method for forming the cathode 20 includes evaporation, spraying, sputtering, electrochemical evaporation, ...

Embodiment 1

[0071] First, the glass substrate was ultrasonically treated with detergent, acetone, ethanol, and isopropanol for 15 minutes. Then, a layer of ITO conductive film with a thickness of 150nm was sputtered on the glass substrate, and then UV-ozone was performed for 15min.

[0072] Then, the electron transport layer was prepared with a 20mg / mL ZnO nanoparticle ethanol solution in a glove box filled with nitrogen and very low water and oxygen content by solution spin coating method, rotating speed was 1500rpm, annealing at 150℃ for 30min, thickness 40nm. Then, the quantum dot light-emitting layer was prepared, using a 10 mg / mL green CdSe@ZnS quantum dot toluene solution, rotating at 2000 rpm, annealing at 150° C. for 30 min, and having a thickness of 20 nm to obtain a semi-finished product.

[0073] Then transfer the semi-finished product to a pressure of 10 -4 In the high vacuum chamber under Pa, 0.6nm Alq is sequentially vacuum evaporated 3 As the green light energy transfer layer, 5...

Embodiment 2

[0075] First, the glass substrate was ultrasonically treated with detergent, acetone, ethanol, and isopropanol for 15 minutes. Then, a layer of ITO conductive film with a thickness of 150nm was sputtered on the glass substrate, and then UV-ozone was performed for 15min.

[0076] Then, the electron transport layer was prepared with a solution spin coating method in a glove box filled with nitrogen and extremely low water and oxygen content, using a 20 mg / mL ZnO nanoparticle ethanol solution, at a rotation speed of 3000 rpm, annealed at 150° C. for 30 min, and a thickness of 30 nm. Then, the quantum dot light-emitting layer was prepared, using a 10 mg / mL green CdSe@ZnS quantum dot toluene solution, rotating at 2000 rpm, annealing at 150° C. for 30 min, and having a thickness of 20 nm to obtain a semi-finished product.

[0077] Then transfer the semi-finished product to a pressure of 10 -4 In the high-vacuum chamber under Pa, 1.5nm C545 is successively vacuum deposited as the green li...

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Abstract

The invention discloses an inverted green light quantum dot thin film electroluminescent device and a preparation method thereof, comprising a substrate, a cathode, an electron transport layer, a green light quantum dot luminescent layer, a green light energy transport layer, a hole transport layer, and a hole transport layer stacked in sequence. A hole injection layer and an anode; the thickness of the green light quantum dot light-emitting layer is 20nm-30nm; the thickness of the green light energy transfer layer is 0.1nm-2.2nm. This inverted green light quantum dot thin film electroluminescence device uses a green light energy transfer layer as an auxiliary layer for the formation of light-emitting excitons, so that the green light light-emitting excitons can be formed not only by direct injection, but also by energy transfer. The green light-emitting excitons reach the green quantum dot light-emitting layer through energy transfer after the green light energy transfer layer is formed to make them emit light, thereby solving the problem of the high hole injection barrier of the inverted green quantum dot thin film electroluminescent device The problem.

Description

Technical field [0001] The invention relates to the field of thin film electroluminescent devices, in particular to an inverted green light quantum dot thin film electroluminescent device and a preparation method thereof. Background technique [0002] Quantum dots (QDs) are composed of a finite number of atoms, with three dimensions on the order of nanometers. Quantum dots are generally spherical or quasi-spherical, and are made of semiconductor materials (usually composed of IIB-VIA or IIIA-VA elements) and have a stable diameter of 2-20nm nanoparticles. Quantum dots are aggregates of atoms and molecules on the nanometer scale, which can be composed of a semiconductor material, such as IIB.VIA elements (such as CdS, CdSe, CdTe, ZnSe, etc.) or IIIA.VA elements (such as InP). , InAs, etc.), can also be composed of two or more semiconductor materials. As a novel semiconductor nanomaterial, quantum dots have many unique nano properties and can be used as the light-emitting layer o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L51/50H01L51/56H01L51/52H01L51/54
CPCH10K85/00H10K50/00H10K50/115H10K50/11H10K71/00
Inventor 曹进周洁谢婧薇魏翔俞浩健
Owner SHANGHAI UNIV