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Biologically-synthesized resin capable of controlling interfacial compatibility and application thereof

A technology for synthetic resin and interface control, which is applied to biosynthetic resins with controllable interface compatibility and their application fields, can solve the problem that the resin is difficult to penetrate and wet the inside of the pores, increase the difficulty of forming a good bonding force, and is difficult to form Wetting and interfacial bonding, etc., to achieve the effect of reducing interfacial incompatibility, good wetting and interfacial bonding, and reducing internal defects

Inactive Publication Date: 2016-09-21
王育钦
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] In addition, in biosynthetic resins, the resin matrix can be general-purpose resins such as PE, PP, PET, PVC, PS, etc. These resins contain a small amount of polar groups and are hydrophobic, and the main component of biomass as a filler is Cellulose, lignin and hemi-lignin contain more polar groups on the surface, such as hydroxyl groups, which are hydrophilic, so the interfacial compatibility between the two is poor, and it is difficult to form a good wetting and interface binding
In addition, biomass micropowder is a porous solid with tiny pores on the surface and inside, and it is difficult for resins with poor compatibility with biomass to penetrate and wet the inside of the pores, which makes it easy to produce interface defects between biomass and resin , which further increases the difficulty of forming a good bond
[0010] In addition to the above two problems, the most commonly used resin matrix for biosynthetic resins is the most widely used PE and PP. The structures of these two resins do not contain polar groups and groups that are easy to polarize, so the combination of interfaces The force is very small, so it is not easy to form a strong interface
[0011] In addition, when biosynthetic resin products involve degradable plastics as raw materials, it is necessary to ensure their shaping and easy processing characteristics. Therefore, the thickness of the interface between the resin and biomass must be controlled, so as to fully ensure the biosynthetic resin. The processing performance and the flexibility and ductility of the product, but there is no corresponding report

Method used

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  • Biologically-synthesized resin capable of controlling interfacial compatibility and application thereof
  • Biologically-synthesized resin capable of controlling interfacial compatibility and application thereof
  • Biologically-synthesized resin capable of controlling interfacial compatibility and application thereof

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specific Embodiment approach 1

[0043] Specific embodiment 1: A biosynthetic resin with controllable interfacial compatibility of this embodiment, it is composed of resin with a mass percentage of 30-50%, and a compatibilizer with a mass percentage of 0.5-5% , a mass percentage composition of 0.5 to 3% lubricant, a mass percentage content of 0.5 to 3% oxidant and a balance of fillers; the filler is made of inorganic fillers and biomass fillers (wherein common inorganic fillers and The proportion of the biomass filler can be adjusted arbitrarily), the preparation method of the biomass filler is as follows: firstly, the biomass is dried to make its water content controlled at 2-3%, and the biomass is added into the high mixer The micropowder, coating agent and nanoparticles are blended under the condition of 80-110°C to obtain biomass filler; wherein, the mass ratio of biomass micropowder, coating agent and nanoparticle is 1:0.005~0.02:0.005~ 0.02.

specific Embodiment approach 2

[0044] Embodiment 2: This embodiment is different from Embodiment 1 in that: the resin is a hydrophobic resin. Others are the same as in the first embodiment.

specific Embodiment approach 3

[0045] Embodiment 3: This embodiment is different from Embodiment 1 in that: the resin is general-purpose resin such as PE, PP, PET, PVC, and PS. Others are the same as in the first embodiment.

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Abstract

The invention discloses biologically-synthesized resin capable of controlling interfacial compatibility and application thereof and relates to biologically-synthesized resin and application thereof. The biologically-synthesized resin is prepared by, by weight percentage, 30-50% of resin, 0.5-5% of compatilizer, 0.5-3% of lubricating agent, 0.5-3% of oxidant and the balance of filler. The biologically-synthesized resin can be used for preparing degradable materials. By the preparation method of the biologically-synthesized resin, the surface appearance of biomass micro-powder can be controlled, good interfacial compatibility between the biomass micro-powder and a nonpolar resin base can be achieved, good moistening and interfacial combination between the biomass micro-powder and the nonpolar resin base can be achieved, interface combination strength is increased, internal defects of biologically-synthesized resin products are reduced, interface thickness is controlled, occlusion of the resin base on the surface and inside biomass is reduced, and the mechanical strength, stability, machinability, flexibility and ductility of the biologically-synthesized resin products are guaranteed.

Description

technical field [0001] The present invention relates to a method for increasing the interfacial compatibility of biomass with general resins through the use of compatibilizers and self-assembly of nanoparticles. Background technique [0002] With the increasingly prominent problem of plastic pollution, degradable plastics are gradually favored by the market. According to statistics, the demand for degradable plastics in foreign markets will grow rapidly at a rate of 20% per year. Degradable plastics can be divided into photodegradable plastics, biodegradable plastics, chemically degradable plastics, combined degradable plastics, etc. according to the environmental conditions that cause degradation. [0003] At present, the degradable plastics in the world mainly include three categories: aliphatic polyester degradable plastics, plastic starch and starch-based degradable plastics, and highly filled plastics with degradable modifiers added. [0004] Aliphatic polyesters main...

Claims

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Application Information

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IPC IPC(8): C08L101/00C08L97/02
CPCC08K2201/011C08L97/02C08L101/00C08L2201/06C08L2205/03C08L2205/035C08L2205/08C08L2205/16
Inventor 王育钦冯钢范大鹏
Owner 王育钦
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