Method for treating wastewater containing ammonia
A treatment method and wastewater technology, applied in the direction of oxidized water/sewage treatment, etc., can solve inappropriate problems, achieve the effects of less harmful gases, easy decomposition, and low concentration of residual oxidants
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Embodiment 1~6
[0050] [Examples 1 to 6 (treatment with liquid containing sodium hypobromite)]
[0051] As test water, steel mill wastewater of the following water quality was used.
[0052] pH: 8.2
[0053] Ammonium ion concentration: 410mg / L (22.7mmol / L)
[0054] TOC: 21mg / L
[0055] ORP: 236mV
[0056] For a liquid containing sodium hypobromite as a chemical solution, a sodium bromide solution with a concentration of 40 wt% and a sodium hypochlorite solution with a concentration of 12 wt% are mixed to form a ratio of NaBr:NaOCl=1:1 (molar ratio) to generate hypobromide Sodium acid liquid.
[0057] 1000 mL of test water was stored in a glass container, the water temperature was kept at 50°C, and the pH was adjusted to 9.6 with NaOH, then the sodium hypobromite aqueous solution was added. The reaction time was set to 5 minutes.
[0058] Table 1 shows the amount of sodium hypobromite added, the residual chlorine concentration, ORP, ammonium ion concentration, and ammonium ion decomposit...
Embodiment 7~21
[0067] [Examples 7 to 21 (treatment with sodium hypobromite and sodium hypochlorite)]
[0068] As test water, steel mill wastewater of the following water quality was used.
[0069] pH: 8.3
[0070] Ammonium ion concentration: 532mg / L (29.5mmol / L)
[0071] TOC: 22mg / L
[0072] ORP: 90mV
[0073] As the liquid containing sodium hypobromite and sodium hypochlorite, the liquid which produced sodium hypobromite by mixing the sodium bromide solution of 40 wt% concentration and the sodium hypochlorite aqueous solution of 12 wt% concentration by the weight ratio of Table 2 was used.
[0074] 1000 mL of test water was stored in a glass container, and the water temperature was kept at 50° C., and after pH was adjusted to 9.6 with NaOH, an aqueous solution of sodium hypobromite was added. The reaction time was set to 5 minutes.
[0075] Table 2 shows the amount of chemical reagents added (converted to the ratio of NaBr and NaOCl added to the test water), the residual chlorine conce...
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