27 results about "Hypobromous acid" patented technology

The invention discloses a copper-doped cerium oxide antifouling agent and a preparation method and application thereof.The antifouling agent takes cerium oxide as a main body material, copper is introduced for doping, Cu < 2 + > partially replaces Ce < 4 + > to enter crystal lattices, charge imbalance is caused, more oxygen vacancies are induced to be generated, meanwhile, reduction conversion from Ce < 4 + > to Ce < 3 + > is promoted, and formation of the oxygen vacancies is further stabilized. The oxygen vacancies obviously enhance the surface catalytic activity of the material, H2O2 and Br <-> in seawater can be efficiently catalyzed to generate hypobromous acid (HOBr) with a bactericidal effect, the function of natural halogenated peroxidase is simulated, and long-acting and environment-friendly biological antifouling is realized. The antifouling agent provided by the invention can be synthesized by adopting a hydrothermal method, is simple and convenient in process, is suitable for large-scale preparation, is suitable for various marine environment antifouling scenes such as hulls, marine engineering equipment and underwater sensors, and has a good application prospect.

To provide a stable water treatment composition containing an inorganic sterilizing agent having high sterilization power and an azole compound, and a water treatment method using the water treatment composition.SOLUTION: The present invention provides a water treatment composition containing hypobromous acid, a bromine stabilizer, and an azole compound, and having a pH of 13 or more. The bromine stabilizer comprises (A) a sulfonamide compound and (B) a sulfobenzimide compound.SELECTED DRAWING: None

The invention provides a compound, a kit and a method for detecting the alkalization degree of an ammonia death marker lysosome, and belongs to the technical field of biological detection.The compound is EKNOH and can specifically react with ammonia under the action of an auxiliary agent hypobromous acid to generate a fluorescent substance, and the fluorescent substance is used for detecting the alkalization degree of the lysosome. The kit comprises a sample extracting solution A, a sample extracting solution B, a sample buffer solution and a protein precipitant which can effectively extract lysosomal ammonia from cells, and a substrate stock solution and a color developing auxiliary reagent which are used for color developing detection. The scheme provided by the invention is particularly suitable for cell samples, has the advantages of simplicity and convenience in operation, higher detection sensitivity, small sample dosage and the like, and provides an effective detection means for related mechanism research of ammonia death, drug development and the like.

The present invention relates to the preparation and use of high-entropy nanozymes with multi-pathway synergistic antibacterial effects, belonging to the field of nanozyme catalytic materials. The present invention, for the first time, utilizes a hydrothermal method and high-temperature calcination method to synthesize oxygen-vacancy-rich high-entropy oxides with haloperoxidase-like, peroxidase-like, and glutathione oxidase-like activities. These oxides can catalyze bromide ions and hydrogen peroxide to generate hypobromous acid, which interferes with bacterial quorum sensing, and hydroxyl radicals, which disrupt structure and function. Furthermore, these oxides consume glutathione, which maintains the internal redox balance of bacteria. This allows for multi-pathway synergistic and efficient bacterial damage and inactivation, helping to address the problems of existing antifouling nanozyme materials, which suffer from a single catalytic pathway and poor component adjustability. This allows for the practical expansion of high-entropy nanozyme coatings, and has potential application prospects in the field of marine biofouling.

The utility model belongs to the technical field of water treatment, and provides a filter which comprises a valve body, a filter element shell is detachably connected into the valve body, the outer sides of the top and the bottom of the filter element shell are both in sealed connection with the valve body, a water inlet is formed in the top of the valve body, a water inlet pipe is connected to the water inlet, a water outlet is formed in the upper end of one side of the valve body, and a water outlet pipe is connected to the water outlet. A water permeable membrane is arranged at the top of the filter element shell, the filter element shell is filled with brominated hydantoin resin particles, and the water inlet and the water outlet are communicated with the interior of the filter element shell. Compared with the prior art, the water filter has the advantages that when water flows through the filter element shell, sterilization of the water is achieved by means of the slow release principle, the flowing-out water does not contain hypobromous acid with high concentration, the drinking taste is not affected, and after the filter does not need to be used for a long time, when the filter is reused, the water filter can be reused, and the service life of the water filter is prolonged. And only the water outlet needs to be opened to enable the water higher than the outlet water in the filter element shell to flow out, so that the water waste is reduced.

The invention provides a single-molecule fluorescent probe based on a BODIPY derivative BP-BNO2 as well as a synthesis method and application of the single-molecule fluorescent probe, and the specific Chinese name of the derivative is 5, 5-difluoro-1, 3, 7, 9-tetramethyl-10-(4-nitrophenyl)-5H-4 lambda 4, 5 lambda 4-dipyrrolo [1, 2-c: 2 ', 1'-f] [1, 3, 2] diazaborane. The invention also provides a synthesis method of the derivative and application of the derivative in detection of hypobromous acid in vitro, cells and nasal cavities of mice with allergic rhinitis. According to the method, on the basis of a derivative BP-BNO2 of BODIPY, the concentration change of hypobromous acid is detected through a fluorospectro photometer in a mixed solution of a phosphate buffer solution and acetonitrile (the volume ratio is 7: 3). The method also realizes noninvasive in-situ imaging at cell and mouse levels, and can be used for in-situ monitoring of hypobromous acid level in the nasal cavity of the mouse with allergic rhinitis and auxiliary diagnosis of allergic rhinitis.

To provide a stable hypobromous acid solution that can maintain a stable bactericidal effect over a long period of time, even amid annual temperature fluctuations.SOLUTION: The stable hypobromous acid solution is achieved even at elevated temperatures by using sulfonated benzimidazole compounds as bromine stabilizers.SELECTED DRAWING: None

Reaction of bleach with a soluble bromide salt to produce brightly colored hypobromite ion enables easy colorimetric measurement of active chlorine, or NaOCl content of bleach. Water of dilution and a suitable buffer are combined with bleach to provide a stable color over a wide range of bleach composition. This analytical method is well suited for use outside the laboratory at sites where bleach is stored or used; for example, but not limited to industrial sites that use bleach, places where bleach is used to destroy microbes and / or hazardous substances in water, and commercial laundries. In addition to analyzing bleach itself, process water streams containing some amount of bleach or another source of active chlorine can be analyzed over a wide range of NaOCl concentration.

Provided is a water treatment method and the like that enables stable management of water systems. [Solution] According to one aspect of the present invention, there is provided a water treatment method for an aqueous system, comprising a supplying step and a control step, in which the supplying step supplies hypochlorite ions to the aqueous system to be treated, the aqueous system containing a bromide salt and a chlorine stabilizer, and the control step controls the concentration of hypobromite ions in the aqueous system to be treated at one or more of the timings before, during, and after the supplying step.

The invention belongs to the technical field of electro-catalysis, and discloses a method and device for preparing ethylene oxide through cathode and anode coupling electro-catalysis, and the method comprises the following steps: obtaining an electrolyte containing hydrogen peroxide in a cathode electrolytic cell; feeding the electrolyte containing hydrogen peroxide into a cathode reaction tank; electrolyte containing potassium hypobromite is obtained in an anode electrolytic cell; feeding the electrolyte containing potassium hypobromite into an anode reaction tank; in a cathode reaction tank, obtaining a reaction solution containing ethylene oxide; feeding the reaction liquid containing ethylene oxide into a reaction liquid flow mixing tank; in an anode reaction tank, obtaining a reaction solution containing a bromoalcohol intermediate; feeding the reaction liquid containing the bromoalcohol intermediate into a reaction liquid flow mixing tank; carrying out saponification reaction on the bromo-alcohol intermediate in the mixed flow tank; and after the saponification reaction is finished, carrying out reduced pressure distillation on the mixed solution to separate out ethylene oxide gas, and respectively feeding the liquid into an external catholyte tank and an external anolyte tank. The method improves the energy utilization rate.

A treatment liquid for a semiconductor containing a group 6 metal, the treatment liquid containing hypobromite ions. Also provided is a treatment liquid for a semiconductor containing a group 6 metal, the treatment liquid characterized by being formed by adding and mixing at least a bromine-containing compound, an oxidizing agent, a base compound, and water, wherein relative to a total mass, an added amount of the bromine-containing compound is 0.008 mass % or more and less than 10 mass % as an amount of bromine element, and an added amount of the oxidizing agent is 0.1 mass ppm or more and 20 mass % or less; and pH at 25° C. is 8 or higher and 14 or lower. Further provided is a method for producing the treatment liquid for a semiconductor.

The invention belongs to the technical field of green electrochemistry, and particularly relates to a synchronous electrooxidation reduction bromine extraction method which is carried out in an electrolysis device composed of an anode electrolytic tank and a cathode electrolytic tank, and the anode electrolytic tank and the cathode electrolytic tank are separated through a diaphragm; the method comprises the following steps: S1, introducing a bromine-containing raw material solution into an anode electrolytic tank; s2, adding an electrolyte into the cathode electrolytic tank; s3, applying oxidation potential to the working electrode, and carrying out electrochemical oxidation reaction to generate bromine molecules; s4, blowing out bromine molecules and carrying the bromine molecules into a cathode electrolytic tank; s5, the bromine molecules are subjected to a disproportionation reaction in the cathode electrolytic tank, and bromine ions and hypobromite ions are generated; the hypobromite ions are subjected to an electrochemical reduction reaction to generate bromide ions and hydroxyl ions; s6, continuously carrying out reactions in the steps S3 to S5; and S7, obtaining a concentrated bromine salt solution from the cathode electrolytic tank. The method provided by the invention realizes greenization and high efficiency of the bromine extraction process.

Disclosed herein is a method of extracting metal from a metal sulfide containing material comprising the steps of: a) providing an aqueous acidic oxidant mixture comprising water, an acid, an oxidising means, and a halide ion source, wherein the aqueous acidic oxidant mixture has a pH of less than 7; wherein the oxidising means comprises hydrogen peroxide, ozone, oxygen, chlorine, bromine, iodine, hypochlorous acid, hypobromous acid, hypoiodous acid, a hypochlorite salt, a hypobromite salt, a hypoiodite salt, a percarbonate salt, a persulfate salt, a permanganate salt, an anode connected to a power source, or combinations thereof; b) contacting the aqueous acidic oxidant mixture with the metal sulfide containing material to extract the metal from the metal sulfide containing material and form a metal halide solution; wherein the metal comprises copper, nickel, lead, zinc, or combinations thereof.

The invention provides a BCDMH (bromochlorohydantoin) treatment agent for black and odorous water treatment, and relates to the technical field of water ecological environmental protection, BCDMH is prepared into a granular preparation, the specific gravity of particles is larger than that of water, the BCDMH is prepared into the granular preparation, and the granular preparation is uniformly thrown into the black and odorous water. After entering water, the bromochlorohydantoin granular preparation is quickly dispersed to form wettable powder, the bottom is aerated at the same time, oxidation of bromochlorohydantoin is promoted, and generated hypobromous acid and hypochlorous acid are used for killing sludge microorganisms; the bromochlorohydantoin treatment agent has extremely high pollution removal capacity, black and odorous bottom mud is converted into brown yellow after treatment, and the method is an in-situ and in-situ treatment method and is suitable for treatment of rural black and odorous water bodies. According to the present invention, the raw materials are respectively crushed, such that the adsorption capacity of the crushed bentonite and the crushed attapulgite is significantly improved according to the solid adsorption theory, and the specific surface area of the bromochlorohydantoin powder and the 5, 5-dimethylhydantoin is increased so as to improve the sterilization and disinfection effect.

The invention provides a dithiothreitol preparation method, which comprises: carrying out an addition reaction on butadiene and hypobromous acid, and refining to obtain 1, 4-dibromo-2, 3-butanediol; and adding hydrosulfide to carry out substitution reaction to obtain the dithiothreitol. According to the method, the synthesis route is greatly shortened, byproducts are few, the yield is improved, the product purity can reach 99% or above, and the cost is low; meanwhile, the intermediate is high in stability, high in purity and easy to store, the generation of intermediates which are extremely high in corrosivity and susceptibility to allergy is avoided, and the preparation method has great advantages on industrial enlarged production and environmental protection.

Disclosed herein is a method of extracting metal from a metal sulfide containing material comprising the steps of: a) providing an aqueous acidic oxidant mixture comprising water, an acid, an oxidising means, and a halide ion source, wherein the aqueous acidic oxidant mixture has a pH of less than 7; wherein the oxidising means comprises hydrogen peroxide, ozone, oxygen, chlorine, bromine, iodine, hypochlorous acid, hypobromous acid, hypoiodous acid, a hypochlorite salt, a hypobromite salt, a hypoiodite salt, a percarbonate salt, a persulfate salt, a permanganate salt, an anode connected to a power source, or combinations thereof; b) contacting the aqueous acidic oxidant mixture with the metal sulfide containing material to extract the metal from the metal sulfide containing material and form a metal halide solution; wherein the metal comprises copper, nickel, lead, zinc, or combinations thereof.

Methods for treating water in a water system to reduce the amount of trihalomethanes (“THM”) in the water. The methods include combining with the water a stabilized halogen biocide that is stabilized with at least one of sulfamic acid and a hydantoin in sufficient amounts so that the water has a residual total halogen amount that is from 0.1 ppm to 50 ppm, for example. The THM in the treated water can be significantly reduced as compared to treatments in which hypochlorous acid and / or hypobromous acid are the only antimicrobial agents.

The present invention relates to a highly selective fluorescent probe for identifying hypobromous acid. Specifically, the probe of the present invention can be used to measure, detect or screen hypobromous acid, can realize selective recognition of hypobromous acid, can realize rapid and highly sensitive analysis of hypobromous acid, and can also realize detection of hypobromous acid in real water samples, and has the advantages of simple synthesis, stable properties, and is conducive to commercial application.

The invention discloses a method for improving Faraday efficiency of bromine ion mediated styrene epoxidation. According to the method, a bromine ion mediated styrene photoelectrocatalysis epoxidation reaction is carried out by utilizing a three-electrode system taking alpha-Fe2O3 as a working electrode, bromine ions are oxidized in a photo-anode local acid environment to generate hypobromous acid under the condition of no stirring, and then styrene is oxidized by the hypobromous acid to generate epoxy with high selectivity and high Faraday efficiency. The method is simple, easy to operate and low in cost, and has certain universality for styrene substrates.

A semiconductor treatment liquid for removing ruthenium silicide from a substrate containing ruthenium silicide, the semiconductor treatment liquid for ruthenium silicide removal containing (i) at least one selected from the group consisting of hypochlorous acid, hypobromous acid, periodic acid, and ions thereof, (ii) at least one selected from the group consisting of hydrogen fluoride and a fluoride ion, and (iii) an onium ion.

Methods for treating water in a water system to reduce the amount of trihalomethanes ("THM") in the water. The methods include combining with the water a stabilized halogen biocide that is stabilized with at least one of sulfamic acid and a hydantoin in sufficient amounts so that the water has a residual total halogen amount that is from 0.1 ppm to 50 ppm, for example. The THM in the treated water can be significantly reduced as compared to treatments in which hypochlorous acid and / or hypobromous acid are the only antimicrobial agents.

The present invention provides compounds, kits and methods for detecting the lysosomal alkalinity as an ammonia death marker, belonging to the field of biological detection technologies. The compound is EKNOH, which can specifically react with ammonia under the action of an auxiliary agent hypobromous acid to generate a fluorescent substance. The kit includes a sample extraction solution A, a sample extraction solution B, a sample buffer solution, a protein precipitant for effectively extracting lysosomal ammonia from cells, a substrate stock solution for colorimetric detection, and a color development auxiliary reagent. The solution of the present invention is particularly applicable to cell samples, and has the advantages of simple operation, higher detection sensitivity, less sample consumption, etc., providing an effective detection means for the research on the mechanism related to ammonia death and drug development, etc.

A semiconductor processing liquid comprising a carboxylic acid and a hypohalite ion, wherein the concentration of the carboxylic acid is 0.0001-1.0 mol / L, the hypohalite ion is at least one selected from the group consisting of hypochlorite and hypobromite ions, the concentration of the hypohalite ion is 0.0001-3.0 mol / L, and the pH of the semiconductor processing liquid at 25°C is 7.0-14.0.

The invention relates to a ruthenium semiconductor processing liquid and a manufacturing method thereof. A treatment liquid for a ruthenium semiconductor, the treatment liquid containing hypobromous acid ions, the amount of the hypobromous acid ions being 0.001 mol / L to 0.20 mol / L (inclusive).

A method for producing a quaternary alkylammonium hypobromite solution comprising: a preparation step in which a quaternary alkylammonium hydroxide solution is prepared in a reaction vessel; and a reaction step in which the quaternary alkylammonium hydroxide solution is brought into contact with liquid bromine and / or bromine gas in the reaction vessel.

The invention relates to a preparation method and application of a hypobromous acid ratiometric fluorescent probe capable of targeting mitochondria. The probe can selectively and quickly react with HOBr through a specifically designed molecular structure, and generates ratio type fluorescence signal change, so that high-sensitivity detection of endogenous / exogenous HOBr of mitochondria in cells is realized. The long emission wavelength (gt; 600nm), low cytotoxicity and excellent co-localization performance (the mitochondrial localization coefficient is greater than or equal to 0.97), and is suitable for dynamic imaging analysis of living cells. The invention also provides a simple synthesis method of the probe.

Provided is a treatment liquid for treating a semiconductor wafer in a semiconductor forming process, the treatment liquid containing (A) a hypobromite ion, (B) a pH buffer, and (C) an onium ion represented by formula (1):(wherein R1, R2, R3, and R4 each independently denote an alkyl group having carbon number from 1 to 25,)