Disclosed herein is a method of extracting
metal from a
metal sulfide containing material comprising the steps of: a) providing an aqueous acidic oxidant mixture comprising water, an acid, an oxidising means, and a
halide ion source, wherein the aqueous acidic oxidant mixture has a pH of less than 7; wherein the oxidising means comprises
hydrogen peroxide,
ozone,
oxygen,
chlorine,
bromine,
iodine,
hypochlorous acid,
hypobromous acid, hypoiodous acid, a
hypochlorite salt, a
hypobromite salt, a hypoiodite salt, a percarbonate salt, a
persulfate salt, a
permanganate salt, an
anode connected to a power source, or combinations thereof; b) contacting the aqueous acidic oxidant mixture with the
metal sulfide containing material to extract the metal from the metal
sulfide containing material and form a metal
halide solution; wherein the metal comprises
copper,
nickel, lead,
zinc, or combinations thereof.