A composite positive electrode sheet and preparation method thereof, and lithium ion battery
A composite positive electrode and composite layer technology, applied in battery electrodes, secondary batteries, non-aqueous electrolyte battery electrodes, etc., can solve the problem of uneven positive active material, difficult control of slurry uniformity, and influence on electrode and battery electrochemical performance. and other problems, to achieve the effect of not degrading the cycle performance, improving the overall electrochemical performance, and promoting the capacity to play.
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Embodiment 1
[0039] Such as Figure 1-Figure 2 As shown, the composite positive electrode sheet of this embodiment includes a positive electrode current collector 1 and a coating layer coated on both surfaces of the positive electrode current collector. The positive electrode current collector includes an aluminum foil of the positive electrode current collector body and a primer coated on both surfaces of the aluminum foil. layer, the undercoat layer is polyvinylidene fluoride and graphene that are uniformly mixed and bonded together, the mass ratio of polyvinylidene fluoride to graphene is 5:95, and the thickness of the undercoat layer is 1 μm;
[0040] The coating layer sequentially includes a positive electrode material layer 2 coated on the surface of the positive electrode current collector and a conductive composite layer 3 coated on the outer surface of the positive electrode material layer from the inside to the outside; the positive electrode material layer consists of the first p...
Embodiment 2
[0049] The composite positive electrode sheet of this embodiment includes a positive electrode current collector and a coating layer coated on both surfaces of the positive electrode current collector. The positive electrode current collector includes an aluminum foil of the positive electrode current collector body and an undercoat layer coated on both surfaces of the aluminum foil. The layer is a carbon nanotube composite layer, which is composed of carbon nanotubes with a mass ratio of 95:5 and polyvinylidene fluoride uniformly mixed and bonded together, and the thickness of the undercoat layer is 2 μm;
[0050] The coating layer sequentially includes a positive electrode material layer coated on the surface of the positive electrode current collector and a conductive composite layer coated on the outer surface of the positive electrode material layer from the inside to the outside; the positive electrode material layer is composed of the first positive electrode active mater...
Embodiment 3
[0059] The composite positive electrode sheet of this embodiment includes a positive electrode current collector and a coating layer coated on both surfaces of the positive electrode current collector. The positive electrode current collector includes an aluminum foil of the positive electrode current collector body and an undercoat layer coated on both surfaces of the aluminum foil. The layer is a graphene conductive composite layer. The graphene conductive composite layer is composed of carbon nanotubes with a mass ratio of 95:5 and polyvinylidene fluoride uniformly mixed and bonded together. The thickness of the undercoat layer is 1.5 μm;
[0060]The coating layer sequentially includes a positive electrode material layer coated on the surface of the positive electrode current collector and a conductive composite layer coated on the outer surface of the positive electrode material layer from the inside to the outside; the positive electrode material layer is composed of the fi...
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