A low-carbon high-chromium wear-resistant ball and its preparation process

A low-carbon, high-chromium, wear-resistant ball technology, applied in the field of wear-resistant balls, can solve the problems of reduced content of solid solution alloying elements, poor comprehensive mechanical properties, unfavorable grinding ball toughness, etc., to improve hardenability and enhance ductility. , the effect of enhancing wear resistance

Active Publication Date: 2018-01-19
安徽中建材开源新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In CN105112768A disclosed in China, the wear resistance of grinding balls has been improved, and a vanadium-titanium alloy wear-resistant cast ball is proposed, which promotes the formation of carbides by adding vanadium content to improve hardness, but the carbide content is too high. High content will lead to a decrease in the content of solid solution alloy elements, low matrix strengthening, and poor hardenability, and vanadium is also an element that reduces hardenability. A large amount of vanadium is not conducive to the toughness of the grinding ball, and the comprehensive mechanical properties are poor.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A low-carbon high-chromium wear-resistant ball is composed of the following parts by mass: carbon 2.45%, silicon 0.88%, manganese 0.52%, chromium 18%, aluminum 0.22%, titanium 0.16%, tantalum 0.05%, boron 0.11%, niobium 0.03% %, zirconium 0.03%, sulfur 0.018%, phosphorus 0.022%, nitrogen 0.21%, and the balance is iron and unavoidable impurities.

[0023] A preparation process of a low-carbon high-chromium wear-resistant ball, the preparation steps are as follows:

[0024] 1) Put scrap steel, pig iron, aluminum-iron alloy into induction electric furnace, and feed nitrogen into the electric furnace, heat up to 1260°C, then add niobium-tantalum alloy, ferrosilicon nitride, titanium-iron alloy, manganese-ferroalloy, and continue to heat up to 1550°C ;

[0025] 2) Add ferroboron alloy and ferrosilicon alloy in turn for inoculation treatment, then conduct component analysis, and keep warm for 30 minutes;

[0026] 3) Spray slag removal agent on the molten liquid surface, rem...

Embodiment 2

[0031] A low-carbon high-chromium wear-resistant ball is composed of the following parts by mass: carbon 2.46%, silicon 0.96%, manganese 0.6%, chromium 20%, aluminum 0.25%, titanium 0.18%, tantalum 0.1%, boron 0.12%, niobium 0.02% %, zirconium 0.02%, sulfur 0.016%, phosphorus 0.025%, nitrogen 0.24%, the balance is iron and unavoidable impurities.

[0032] A preparation process of a low-carbon high-chromium wear-resistant ball, the preparation steps are as follows:

[0033] 1) Put scrap steel, pig iron, aluminum-iron alloy into the induction electric furnace, and pass nitrogen gas into the electric furnace, raise the temperature to 1290°C, then add niobium-tantalum alloy, ferrosilicon nitride, titanium-iron alloy, and manganese-ferroalloy, and continue to heat up to 1560°C ;

[0034] 2) Add ferroboron alloy and ferrosilicon alloy in turn for inoculation treatment, then conduct component analysis, and keep warm for 30 minutes;

[0035] 3) Spray slag removal agent on the molten...

Embodiment 3

[0040] A low-carbon high-chromium wear-resistant ball is composed of the following parts by mass: carbon 2.35%, silicon 1%, manganese 0.5%, chromium 19%, aluminum 0.23%, titanium 0.14%, tantalum 0.07%, boron 0.11%, niobium 0.02% %, zirconium 0.03%, sulfur 0.02%, phosphorus 0.017%, nitrogen 0.2%, and the balance is iron and unavoidable impurities.

[0041] A preparation process of a low-carbon high-chromium wear-resistant ball, the preparation steps are as follows:

[0042] 1) Put steel scrap, pig iron, and aluminum-iron alloy into the induction furnace, and feed nitrogen into the furnace, raise the temperature to 1280°C, then add niobium-tantalum alloy, ferrosilicon nitride, ferro-titanium alloy, and ferromanganese alloy, and continue to raise the temperature to 1580°C ;

[0043] 2) Add ferroboron alloy and ferrosilicon alloy in turn for inoculation treatment, then conduct component analysis, and keep warm for 30 minutes;

[0044] 3) Spray slag removal agent on the molten li...

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Abstract

The invention provides a low-carbon high-chromium abrasion-resistant ball and a preparation technique thereof. The low-carbon high-chromium abrasion-resistant ball is prepared from, by mass, 2.35%-2.46% of carbon, 0.85%-1.12% of silicon, 0.45%-0.6% of manganese, 18%-22% of chromium, 0.2%-0.25% of aluminum, 0.1%-0.18% of titanium, 0.05%-0.1% of tantalum, 0.1%-0.12% of boron, 0.02%-0.04% of niobium, 0.01%-0.03% of zirconium, 0.01%-0.025% of sulfur, 0.01%-0.025% of phosphorus, 0.2%-0.24% of nitrogen, and the balance ferrum and inevitable impurities. The low-carbon high-chromium abrasion-resistant ball is prepared through the steps of smelting, pouring, quenching, tempering and the like, the content of the carbon element is decreased, and nitrogen is introduced in the smelting process, so that the abrasion resistance of the ball is improved through formed metal nitride; and meanwhile, the situation that the hardenability is reduced due to excessive carbide is avoided. The quenched HRC of the low-carbon high-chromium abrasion-resistant ball is equal to or higher than 65, the impact fatigue life of the low-carbon high-chromium abrasion-resistant ball is equal to or longer than 19600 times, and the breakage rate of the low-carbon high-chromium abrasion-resistant ball is equal to or lower than 2.5%.

Description

technical field [0001] The invention relates to the technical field of wear-resistant balls, in particular to a low-carbon, high-chromium wear-resistant ball and a preparation process thereof. Background technique [0002] The ball mill is the key equipment for crushing the material after it is crushed. It is widely used in cement, silicate products, new building materials, refractory materials, chemical fertilizers, black and non-ferrous metal beneficiation, glass ceramics and other production industries, for dry or wet grinding of various ores and other grindable materials. The steel ball is an important part in the ball mill. Its main function is to impact and crush the material, and it also plays a certain grinding role. The quality of the steel ball will have a direct impact on the crushing effect and grinding efficiency, and ultimately Affect the output of the ball mill, therefore, the steel ball should have high enough strength and impact resistance. [0003] In CN1...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C37/10C22C37/06C22C33/08C21D1/18C21D9/36C21D5/00
CPCC21D1/18C21D5/00C21D9/36C22C33/08C22C37/06C22C37/10
Inventor 汪德发徐光清李英虎孙成芳刘四新龙国琴
Owner 安徽中建材开源新材料科技有限公司
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