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Rare-earth-doped iron-based amorphous thick strip and preparing method thereof

An iron-based amorphous and rare earth doped technology, applied in the field of magnetic functional materials, can solve the problems of limiting strip production efficiency, iron core preparation efficiency and performance improvement, and achieve the effect of ensuring standardization and accuracy

Active Publication Date: 2017-01-11
南京腾元软磁有限公司 +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing technology generally adopts the spout plane flow casting method to make strips, and the thickness of the sprayed amorphous alloy strips generally does not exceed 40 μm, which limits the production efficiency of strips, the efficiency of iron core preparation and the improvement of performance.

Method used

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  • Rare-earth-doped iron-based amorphous thick strip and preparing method thereof
  • Rare-earth-doped iron-based amorphous thick strip and preparing method thereof
  • Rare-earth-doped iron-based amorphous thick strip and preparing method thereof

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Embodiment 1

[0053] The present invention adopts the method of adding trace rare earth elements, so that the molten steel of the alloy of the present invention in the smelting process is reasonably purified, and the fluidity of the molten liquid is significantly improved; at the same time, because the rare earth Y element has a large atomic size, it is compatible with The atomic size of other elements in the system is very different, so a large mismatch ratio is formed, which improves the amorphous forming ability of the system; the strong amorphous forming ability and excellent melt fluidity make the preparation of thick amorphous ribbons The process is safer and more reliable, and the qualification rate of thick belt products is obviously improved. Within the chemical composition range of the iron-based amorphous alloy described in the present invention, 8 different iron-based amorphous alloy components are selected respectively, and the serial numbers are 1-8, and the iron-based amorphou...

Embodiment 2

[0059] Since the nozzle slit width is the main factor determining the thickness of the strip, the present invention sets up a group of comparative experiments to investigate the influence of the traditional single-slit nozzle and the double-slit nozzle used in the present invention on the thickness of the prepared amorphous alloy strip. The present invention adopts described double slit nozzle and prior art adopts traditional nozzle, carries out comparative experiment under the same process condition, and the process flow chart of tape making is as follows figure 1 As shown, the structure of the double-slit nozzle is as figure 2 The specific process parameters for the preparation of amorphous alloy strips are listed in Table 2. Table 2 is the ingredients according to the components of the present invention. Put the raw materials with good ratio into induction melting furnace or arc melting furnace, and vacuumize to 5×10 -3 Pa below, then filled with nitrogen atmosphere prote...

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Abstract

The invention relates to a rare-earth-doped iron-based amorphous thick strip and a preparing method thereof. The component expression of the iron-based amorphous thick strip is FexSiaBbPcYd, wherein x, a, b, c and d are atomic percents of corresponding elements, wherein a is larger than or equal to 0.5 and smaller than or equal to 10, b is larger than or equal to 0.5 and smaller than or equal to 12, c is larger than or equal to 0.5 and smaller than or equal to 8, d is larger than or equal to 0.001 and smaller than or equal to 0.5, and x+a+b+c+d is equal to 100. A plane flow casting method is adopted for manufacturing the strip, during strip manufacturing, a double-line nozzle is adopted, the thickness of the prepared amorphous thick strip ranges from 50 micrometers to 100 micrometers, the lamination coefficient is larger than 0.92, the saturated magnetic induction density is larger than 1.67T. Micro rare earth yttrium is contained in an alloy, the content of impurities of oxygen, sulphur and the like is greatly reduced, and the molten steel mobility is improved; meanwhile the rare earth yttrium improves the amorphous forming capacity of an alloy system, and the amorphous alloy strip with the thickness ranging from 50 micrometers to 100 micrometers can be prepared through the technology method.

Description

technical field [0001] The invention belongs to the technical field of magnetic functional materials, and in particular relates to a rare earth-doped iron-based amorphous thick ribbon and a preparation method thereof. Background technique [0002] Soft magnetic materials refer to materials that are easily magnetized by a magnetic field, that is, they are magnetized at a low external magnetic field, and demagnetize quickly after the magnetic field is removed. At present, the soft magnetic materials widely used in engineering can be divided into two categories: soft magnetic alloys and soft ferrites. From the perspective of magnetic properties, due to the different physical basis of magnetic formation, there are obvious differences between soft magnetic alloys and soft ferrites. Soft magnetic alloys are ferromagnetic, and the exchange between electrons is strong and direct, so the saturation magnetic induction is high and the Curie temperature is high. The soft ferrite mater...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C45/02C21D6/00C21D1/26B22D11/06
CPCB22D11/0611B22D11/0642C21D1/26C21D6/008C21D2201/03C22C33/003C22C45/02
Inventor 丁力栋
Owner 南京腾元软磁有限公司
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