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EPU one-component solvent-free environment-friendly adhesive and preparation method thereof

A solvent-free, environmentally friendly technology, applied in the direction of adhesive additives, polymer adhesive additives, non-polymer adhesive additives, etc., can solve the problems of operators and environmental pollution, increased storage period, short storage period, etc. , to achieve the effect of wide application field, strong stability and strong storage stability

Inactive Publication Date: 2017-02-08
苏州市丛岭胶粘剂有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, some high-strength adhesives on the market, such as epoxy resins, polyurethanes, etc., can only be cured when they are cured with a catalyst or moisture. Once the catalyst is added to the main agent, it will have a certain impact on storage. Currently on the market Most of the products are two-component, which are compounded together during use. In order to increase the storage period, some single-component adhesives are added with a certain amount of solvents that do not participate in the reaction to improve the storage stability of the product. It will cause harm and pollution to the operator and the environment
All-purpose glue, styrofoam, paint, anti-rust paint, foaming agent, soft and hard sponge, plastic runway glue, composite materials, etc. for decoration on the market today are two-component, which brings trouble to use, while single Due to the short storage period of the components, it is difficult to be used as a commodity, and some solvents that do not participate in the reaction are added to increase the storage period

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] This embodiment is a kind of EPU one-component solvent-free environment-friendly adhesive, and its formula is calculated by weight: 5 parts of epoxy resin, 40 parts of polyether polyol, 5 parts of dehydrated castor oil, 10 parts of anhydrous chlorinated paraffin, 5 parts of liquid rosin resin, 30 parts of alcohol ester twelve film-forming aids, 40 parts of diphenylmethane diisocyanate (polymeric MDI) 5005 type, 10 parts of modified MDI 9259 type, 10 parts of modified MDI 2023 type, silane diisocyanate 1 part of joint agent, 1 part of superfine talc powder, 1 part of nano-scale calcium oxide, 0.1 part of catalyst bismorpholino diethyl ether, and 5 parts of silicone oil.

[0018] Its preparation method process is specifically:

[0019] Dehydration process:

[0020] 5 parts of epoxy resin, 40 parts of polyether polyol, 5 parts of dehydrated castor oil, 10 parts of anhydrous chlorinated paraffin, 5 parts of liquid rosin resin, 30 parts of alcohol ester twelve film-forming ...

Embodiment 2

[0024] This embodiment is a kind of EPU one-component solvent-free environment-friendly adhesive, and its formula is by weight: 10 parts of epoxy resin, 30 parts of polyether polyol, 10 parts of dehydrated castor oil, 20 parts of anhydrous chlorinated paraffin, liquid 20 parts of rosin resin, 20 parts of alcohol ester twelve film-forming aids, 40 parts of diphenylmethane diisocyanate (polymeric MDI) 5005 type, 15 parts of modified MDI 9259 type, 15 parts of modified MDI2023 type, silane coupling agent 0.5 parts, 5 parts of superfine talc powder, 5 parts of nano-scale calcium oxide, 2 parts of catalyst bismorpholino diethyl ether, and 2 parts of silicone oil.

[0025] Its preparation method process is specifically:

[0026] Dehydration process:

[0027] 10 parts of epoxy resin, 30 parts of polyether polyol, 10 parts of dehydrated castor oil, 20 parts of anhydrous chlorinated paraffin, 20 parts of liquid rosin resin, 20 parts of alcohol ester twelve film-forming aids, 0.5 parts...

Embodiment 3

[0031] This embodiment is a kind of EPU one-component solvent-free environment-friendly adhesive, and its formula is by weight: 15 parts of epoxy resin, 30 parts of polyether polyol, 15 parts of dehydrated castor oil, 30 parts of anhydrous chlorinated paraffin, liquid 8 parts of rosin resin, 10 parts of alcohol ester twelve film-forming aids, 30 parts of diphenylmethane diisocyanate (polymeric MDI) 5005 type, 20 parts of modified MDI 9259 type, 30 parts of modified MDI 2023 type, silane coupling 0.8 parts of agent, 10 parts of superfine talc powder, 10 parts of nano-scale calcium oxide, 5 parts of catalyst bismorpholino diethyl ether, and 1 part of silicone oil.

[0032] Its preparation method process is specifically:

[0033] Dehydration process:

[0034] 15 parts of epoxy resin, 30 parts of polyether polyol, 15 parts of dehydrated castor oil, 30 parts of anhydrous chlorinated paraffin, 8 parts of liquid rosin resin, 10 parts of alcohol ester twelve film-forming aids, 0.8 pa...

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PUM

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Abstract

The invention relates to an EPU one-component solvent-free environment-friendly adhesive, the formula of which comprises the following ingredients (by weight): 5-20 parts of epoxy resin, 20-40 parts of polyether polyol, 5-15 parts of dehydrated castor oil, 5-40 parts of anhydrous chlorinated paraffin, 5-20 parts of liquid rosin resin, 10-30 parts of 2,2,4-trimethyl-1,3-pentanediol isobutyrate, 20-40 parts of polymetric MDI Type-5005, 10-30 parts of modified MDI Type-9259, 10-30 parts of modified MDI Type-2023, 0.5-1 part of a silane coupling agent, 1-10 parts of ultrafine talcum powder, 1-10 parts of nanoscale calcium oxide, 0.1-5 parts of a catalyst dimorpholinyl diethylether and 1-5 parts of silicone oil. The environment-friendly type adhesive is stable to store and environment-friendly and harmless. By properly adjusting ratio, products with different properties of quick-drying, slow-drying, bubble, bubble-free, softness and hardness, etc. can be produced to meet requirements of the market.

Description

technical field [0001] The invention relates to an adhesive, in particular to an EPU one-component solvent-free environment-friendly adhesive capable of increasing storage stability and a preparation method thereof. Background technique [0002] At present, some high-strength adhesives on the market, such as epoxy resins, polyurethanes, etc., can only be cured when they are cured with a catalyst or moisture. Once the catalyst is added to the main agent, it will have a certain impact on storage. Currently on the market Most of the products are two-component, which are compounded together during use. In order to increase the storage period, some single-component adhesives are added with a certain amount of solvents that do not participate in the reaction to improve the storage stability of the product. It may cause harm and pollution to the operator and the environment. All-purpose glue, styrofoam, paint, anti-rust paint, foaming agent, soft and hard sponge, plastic runway gl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J175/14C09J11/04C09J11/06C09J11/08
CPCC09J175/14C08K2201/011C09J11/04C09J11/06C09J11/08C08L91/06C08K13/02C08K3/34C08K2003/2206
Inventor 孙益成
Owner 苏州市丛岭胶粘剂有限公司
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