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A processing method for inferior heavy oil and/or inferior residual oil

A processing method and technology for low-quality heavy oil, which is applied in the petroleum industry, hydrotreating process, and hydrocarbon oil treatment. It can solve the problems of short operation period, excessive dry gas, and excessive coking, and achieve high yield of light oil, The effect of extending the operating cycle and wide application range

Active Publication Date: 2018-11-02
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are two deficiencies in the fixed bed process: one is poor adaptability to raw materials, when the Ni+V content of the raw materials is greater than or equal to 200 μg / g, trace carbon residue is greater than or equal to 15% by weight, or the content of asphaltene is greater than or equal to 7 It is more difficult to process at weight %; the second is that the operation cycle is short, and the catalyst is deactivated faster due to carbon deposition and metal deposition
This method pursues a higher conversion rate in the slurry bed reactor, so the yield of the light oil product obtained is relatively high, but it also produces a lot of coking and more dry gas at the same time, and the light oil product obtained requires Secondary treatment such as hydrofinishing, resulting in low conversion of residual oil and / or heavy oil in the overall process

Method used

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  • A processing method for inferior heavy oil and/or inferior residual oil
  • A processing method for inferior heavy oil and/or inferior residual oil
  • A processing method for inferior heavy oil and/or inferior residual oil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0071] With A as raw material (properties see Table 1), in the slurry bed reactor with C as catalyst (properties see Table 2), material flow chart as figure 1 shown.

[0072] Grind the catalyst and control the particle size to 100-150 mesh by sieving method, and feed it into the slurry bed reactor 1 from bottom to top along with the raw material and hydrogen at 3.0% by weight of the weight of the fresh raw material oil. The operating conditions for controlling the slurry bed reactor 1 are: temperature 420°C, pressure 10MPa, hydrogen-oil volume ratio 1000, space velocity 0.2h -1 . The conversion depth of the material at the outlet of slurry bed reactor 1 is shown in Table 3. The material enters the high-pressure separator 2 from the slurry bed reactor 1. The operating conditions of the high-pressure separator 2 include a temperature of 380°C and a pressure of 10MPa, and the discharge speed of the high-pressure separator is controlled so that the heavy matter obtained from the...

Embodiment 2

[0077] Taking B as raw material (see Table 1 for properties), and taking D as catalyst (see Table 2 for properties) in the slurry bed reactor, the material flow chart is as follows figure 1 shown.

[0078] Grind the catalyst and control the particle size to 120-180 mesh by sieving method, and feed it into the slurry bed reactor 1 from bottom to top along with the raw material and hydrogen at 5.0% by weight of the weight of the fresh raw material oil. The operating conditions for controlling the slurry bed reactor 1 are: temperature 380°C, pressure 12MPa, hydrogen-oil volume ratio 1500, space velocity 0.1h -1 . The conversion depth of the material at the outlet of slurry bed reactor 1 is shown in Table 3. The material enters the high-pressure separator 2 from the slurry bed reactor 1. The operating conditions of the high-pressure separator 2 include a temperature of 390°C and a pressure of 9MPa, and the discharge speed of the high-pressure separator is controlled so that the ...

Embodiment 3

[0089] With A as raw material (properties see Table 1), in the slurry bed reactor with C as catalyst (properties see Table 2), material flow chart as figure 2 shown.

[0090] Grind the catalyst and control the particle size to 200-240 mesh by sieving method, and feed it into the slurry bed reactor 1 from bottom to top along with the raw material and hydrogen at 6.0% by weight of the weight of the fresh raw material oil. Control the operating conditions of slurry bed reactor 1 as follows: temperature 400°C, pressure 10MPa, hydrogen-oil volume ratio 1000, space velocity 0.2h -1 . The conversion depth of the material at the outlet of slurry bed reactor 1 is shown in Table 3. The material enters the high-pressure separator 2 from the slurry bed reactor 1. The operating conditions of the high-pressure separator 2 include a temperature of 380°C and a pressure of 10MPa, and the discharge speed of the high-pressure separator is controlled so that the heavy matter obtained from the ...

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Abstract

The invention relates to an inferior heavy oil and / or inferior residual oil processing method. The method includes: feeding inferior heavy oil and / or inferior residual oil into a slurry bed reactor to realize first hydrogenation reaction, and adding obtained products into a high-pressure separator to realize separation, so that hydrogen-containing gas is obtained from the top of the high-pressure separator, liquid components are obtained from the middle of the high-pressure separator, and heavy materials are obtained from the bottom of the high-pressure separator; separating the heavy materials to obtain deasphalted oil and hydrogenation-catalyst-containing deasphalted oil, and sending the liquid components and the deasphalted oil into a fixed bed reactor to realize second hydrogenation reaction, wherein conversion level of the inferior heavy oil and / or the inferior residual oil is not higher than 50% according to conditions of the first hydrogenation reaction. By adoption of the method, poor-property inferior heavy oil and / or the inferior residual oil can be processed, freeness of coking or low coking quantity in the slurry bed reactor and pipelines can be basically guaranteed, and accordingly high lightweight oil product yield can be acquired, and operation cycle of the fixed bed reactor is prolonged.

Description

technical field [0001] The invention relates to a method for processing inferior heavy oil and / or inferior residual oil. Background technique [0002] Crude oil has become heavy and inferior worldwide, and the proportion of residual oil obtained after primary processing of crude oil has increased sharply. In addition, the processing volume of crude oil has increased year by year, and the output of residual oil has risen sharply. At the same time, crude oil reserves are gradually declining, the market demand for light oil products is increasing year by year, and the price difference between light crude oil and heavy crude oil is also increasing. These factors urgently require the development of residual oil / heavy oil light and efficient use of new technologies. [0003] At present, the technologies for lightening residual oil / heavy oil mainly include two processes: decarburization and hydrogenation. In the decarbonization process, the yield of light oil is low and the produc...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G67/02
Inventor 童凤丫杨清河李大东戴立顺邓中活
Owner CHINA PETROLEUM & CHEM CORP
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